{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T01:31:47Z","timestamp":1792805507690,"version":"4.5.0"},"reference-count":57,"publisher":"MDPI AG","issue":"18","license":[{"start":{"date-parts":[[2023,9,19]],"date-time":"2023-09-19T00:00:00Z","timestamp":1695081600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Tokyo Metropolitan Government Advanced Research","award":["H29-1"],"award-info":[{"award-number":["H29-1"]}],"id":[{"id":"https:\/\/ror.org\/01v42ys47","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>The present study investigates the relationship between the local structure, photocatalytic ability, and cathode performances in sodium-ion batteries (SIBs) and lithium-ion batteries (LIBs) using Ni-substituted goethite nanoparticles (NixFe1\u2212xOOH NPs) with a range of \u2018x\u2019 values from 0 to 0.5. The structural characterization was performed applying various techniques, including X-ray diffractometry (XRD); thermogravimetry differential thermal analysis (TG-DTA); Fourier transform infrared spectroscopy (FT-IR); X-ray absorption spectroscopy (XANES\/EXAFS), both measured at room temperature (RT); 57Fe M\u00f6ssbauer spectroscopy recorded at RT and low temperatures (LT) from 20 K to 300 K; Brunauer\u2013Emmett\u2013Teller surface area measurement (BET), and diffuse reflectance spectroscopy (DRS). In addition, the electrical properties of NixFe1\u2212xOOH NPs were evaluated by solid-state impedance spectroscopy (SS-IS). XRD showed the presence of goethite as the only crystalline phase in prepared samples with x \u2264 0.20, and goethite and \u03b1-Ni(OH)2 in the samples with x &gt; 0.20. The sample with x = 0.10 (Ni10) showed the highest photo-Fenton ability with a first-order rate constant value (k) of 15.8 \u00d7 10\u22123 min\u22121. The 57Fe M\u00f6ssbauer spectrum of Ni0, measured at RT, displayed a sextet corresponding to goethite, with an isomer shift (\u03b4) of 0.36 mm s\u22121 and a hyperfine magnetic distribution (Bhf) of 32.95 T. Moreover, the DC conductivity decreased from 5.52 \u00d7 10\u221210 to 5.30 \u00d7 10\u221212 (\u03a9 cm)\u20131 with \u2018x\u2019 increasing from 0.10 to 0.50. Ni20 showed the highest initial discharge capacity of 223 mAh g\u22121, attributed to its largest specific surface area of 174.0 m2 g\u22121. In conclusion, NixFe1\u2212xOOH NPs can be effectively utilized as visible-light-activated catalysts and active cathode materials in secondary batteries.<\/jats:p>","DOI":"10.3390\/ijms241814300","type":"journal-article","created":{"date-parts":[[2023,9,19]],"date-time":"2023-09-19T23:11:52Z","timestamp":1695165112000},"page":"14300","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Photocatalytic and Cathode Active Abilities of Ni-Substituted \u03b1-FeOOH Nanoparticles"],"prefix":"10.3390","volume":"24","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5300-0376","authenticated-orcid":false,"given":"Ahmed","family":"Ibrahim","sequence":"first","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Tokyo 192-0397, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mikan","family":"Shiraishi","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Tokyo 192-0397, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zolt\u00e1n","family":"Homonnay","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, E\u00f6tvos Lor\u00e1nd University, 1117 Budapest, Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stjepko","family":"Krehula","sequence":"additional","affiliation":[{"name":"Division of Materials Chemistry, Ru\u0111er Bo\u0161kovi\u0107 Institute, 10000 Zagreb, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4747-5981","authenticated-orcid":false,"given":"Marijan","family":"Marciu\u0161","sequence":"additional","affiliation":[{"name":"Division of Materials Chemistry, Ru\u0111er Bo\u0161kovi\u0107 Institute, 10000 Zagreb, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7343-1299","authenticated-orcid":false,"given":"Arijeta","family":"Bafti","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering and Technology, University of Zagreb, Maruli\u0107ev trg 20, 10000 Zagreb, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2232-6602","authenticated-orcid":false,"given":"Luka","family":"Pavi\u0107","sequence":"additional","affiliation":[{"name":"Division of Materials Chemistry, Ru\u0111er Bo\u0161kovi\u0107 Institute, 10000 Zagreb, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8255-7811","authenticated-orcid":false,"given":"Shiro","family":"Kubuki","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Tokyo 192-0397, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,9,19]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1562051","DOI":"10.1155\/2022\/1562051","article-title":"Iron oxide nanoparticles: Preparation, characterization, and assessment of antimicrobial and anticancer activity","volume":"9","author":"Alangari","year":"2022","journal-title":"Adsorp. Sci. Technol."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"287","DOI":"10.1016\/j.pisc.2016.04.054","article-title":"Iron oxide nanoparticles synthesis through a benign approach and its catalytic application","volume":"8","author":"Devi","year":"2016","journal-title":"Perspect. Sci."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"138524","DOI":"10.1016\/j.cplett.2021.138524","article-title":"Photocatalytic and antibacterial performance of iron oxide nanoparticles formed by the combustion method","volume":"771","author":"Tharani","year":"2021","journal-title":"Chem. Phys. Lett."},{"key":"ref_4","first-page":"1","article-title":"Facile method to synthesize magnetic iron oxides\/TiO2 hybrid nanoparticles and their photodegradation application of methylene blue","volume":"533","author":"Wu","year":"2011","journal-title":"Nanoscale Res. Lett."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"108064","DOI":"10.1016\/j.jece.2022.108064","article-title":"Preparation of FeOOH supported by melamine sponge and its application for efficient phosphate removal","volume":"10","author":"Tao","year":"2022","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1016\/j.apcatb.2019.118135","article-title":"One-dimensional nanocrystals of cobalt perylene diimide polymer with in situ generated FeOOH for efficient photocatalytic water oxidation","volume":"260","author":"Zhong","year":"2020","journal-title":"Appl. Catal. B Environ."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"2720","DOI":"10.1002\/cssc.201700522","article-title":"Enhanced solar water splitting by swift charge separation in Au\/FeOOH sandwiched single-crystalline Fe2O3 nanoflake photoelectrodes","volume":"10","author":"Wang","year":"2017","journal-title":"Chem. Sus. Chem."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"294","DOI":"10.1016\/j.nanoen.2019.03.058","article-title":"All-iron sodium-ion full-cells assembled via stable porous goethite nanorods with low strain and fast kinetics","volume":"60","author":"Huang","year":"2019","journal-title":"Nano Energy"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"657","DOI":"10.1007\/s10800-019-01315-0","article-title":"Novel \u03b1-FeOOH corner-truncated tetragonal prisms: Crystal structure, growth mechanism and lithium storage properties","volume":"49","author":"Liu","year":"2019","journal-title":"J. Appl. Electrochem."},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Pascariu, P., Gherasim, C., and Airinei, A. (2023). Metal oxide nanostructures (MONs) as photocatalysts for ciprofloxacin degradation. Int. J. Mol. Sci., 24.","DOI":"10.3390\/ijms24119564"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"290","DOI":"10.1016\/j.jallcom.2019.06.133","article-title":"Effects of Cu doping on the microstructural, thermal, optical and photocatalytic properties of \u03b1-FeOOH and \u03b1-Fe2O3 1D nanoparticles","volume":"802","author":"Krehula","year":"2019","journal-title":"J. Alloys Compd."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"109699","DOI":"10.1016\/j.jpcs.2020.109699","article-title":"Influence of Cr doping on the structural, magnetic, optical and photocatalytic properties of \u03b1-Fe2O3 nanorods","volume":"148","author":"Popov","year":"2021","journal-title":"J. Phys. Chem. Solids"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"94","DOI":"10.1016\/j.jallcom.2017.06.083","article-title":"57Fe-M\u00f6ssbauer study and methylene blue decomposing effect of nanoparticle mixtures composed of metallic iron and maghemite","volume":"722","author":"Kobzi","year":"2017","journal-title":"J. Alloys Compd."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"126247","DOI":"10.1016\/j.matchemphys.2022.126247","article-title":"Highly covalent FeIII-O bonding in photo-Fenton active Sn-doped goethite nanoparticles","volume":"287","author":"Zhang","year":"2022","journal-title":"Mater. Chem. Phys."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1021\/acs.langmuir.0c02466","article-title":"Size tuned synthesis of FeOOH nanorods toward self-assembled nanoarchitectonics","volume":"37","author":"Darehnaranji","year":"2021","journal-title":"Langmuir"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"751","DOI":"10.1107\/S0567739476001551","article-title":"Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides","volume":"32","author":"Shannon","year":"1976","journal-title":"Acta Cryst. A"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"363","DOI":"10.1016\/0016-7037(90)90325-F","article-title":"Unit-cell dimensions of pure and trace metal-associated goethites","volume":"54","author":"Gerth","year":"1990","journal-title":"Geochim. Cosmochim. Acta"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"6231","DOI":"10.1007\/BF01113909","article-title":"Structure of nickel-doped \u03b1-FeOOH","volume":"26","author":"Ishikawa","year":"1991","journal-title":"J. Mater. Sci."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1002\/jctb.280530111","article-title":"The effect of nickel on the conversion of amorphous iron (III) hydroxide into more crystalline iron oxides in alkaline media","volume":"53","author":"Cornell","year":"1992","journal-title":"J. Chem. Technol. Biot."},{"key":"ref_20","doi-asserted-by":"crossref","unstructured":"Val\u00e1\u0161kov\u00e1, M., Le\u0161tinsk\u00fd, P., Mat\u011bjov\u00e1, L., Klemencov\u00e1, K., Ritz, M., Schimpf, C., Motylenko, M., Rafaja, D., and B\u011bl\u00edk, J. (2022). Hematites Precipitated in Alkaline Precursors: Comparison of Structural and Textural Properties for Methane Oxidation. Int. J. Mol. Sci., 23.","DOI":"10.3390\/ijms23158163"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"666","DOI":"10.1021\/acs.langmuir.0c02592","article-title":"Nanoscale Hydration in Layered Manganese Oxides","volume":"37","author":"Cheng","year":"2021","journal-title":"Langmuir"},{"key":"ref_22","first-page":"389","article-title":"Synthesis and Properties of Ni-doped Goethite and Ni-doped Hematite Nanorods","volume":"91","author":"Krehula","year":"2018","journal-title":"Croat. Chem. Acta"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"075937","DOI":"10.1088\/1402-4896\/acdc5d","article-title":"Influence NiO on the structure, elastic properties and buildup factor of BaO-CdO-borosilicate glasses","volume":"98","author":"Sayyed","year":"2023","journal-title":"Phys. Scr."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"6642","DOI":"10.1038\/s41598-021-85672-x","article-title":"Ultra-small and highly dispersive iron oxide hydroxide as an efficient catalyst for oxidation reactions: A Swiss-army-knife catalyst","volume":"11","author":"Amini","year":"2021","journal-title":"Sci. Rep."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1016\/j.jnoncrysol.2016.09.016","article-title":"Electrochemical properties and in-situ XAFS observation of Li2O-V2O5-P2O5-Fe2O3 quaternary-glass and crystallized-glass cathodes","volume":"453","author":"Aoyagi","year":"2016","journal-title":"J. Non-Cryst. Solids"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"167366","DOI":"10.1016\/j.jallcom.2022.167366","article-title":"Enhancement of electrical conductivity and thermal stability of Iron- or Tin- substituted vanadate glass and glass-ceramics nanocomposite to be applied as a high-performance cathode active material in sodium-ion batteries","volume":"930","author":"Ibrahim","year":"2023","journal-title":"J. Alloys Compd."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"12021","DOI":"10.1088\/1742-6596\/985\/1\/012021","article-title":"Fe K-Edge X-ray absorption near-edge spectroscopy (XANES) and X-ray diffraction (XRD) analyses of LiFePO4 and its base materials","volume":"985","author":"Latif","year":"2018","journal-title":"J. Phys. Conf. Ser."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"5074","DOI":"10.1038\/s41467-019-13052-1","article-title":"A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering","volume":"10","author":"Li","year":"2019","journal-title":"Nat. Commun."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"111391","DOI":"10.1016\/j.jpcs.2023.111391","article-title":"Impact of adding Fe ions on the local structure and electrochemical performance of P2O5-V2O5 glass and glass ceramics used as a cathode in LIBs","volume":"179","author":"Ibrahim","year":"2023","journal-title":"J. Phys. Chem. Solids"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"12324","DOI":"10.1021\/acscatal.1c02566","article-title":"Detection of spontaneous FeOOH formation at the hematite\/Ni (Fe)OOH interface during photoelectrochemical water splitting by operando X-ray absorption spectroscopy","volume":"19","author":"Ismail","year":"2021","journal-title":"ACS Catal."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"2206768","DOI":"10.1002\/smll.202206768","article-title":"Dynamic reconstructed RuO2\/NiFeOOH with coherent interface for efficient seawater oxidation","volume":"19","author":"Chang","year":"2023","journal-title":"Small"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"2963","DOI":"10.1038\/s41467-022-30702-z","article-title":"Iron atom-cluster interactions increase activity and improve durability in Fe-N-C fuel cells","volume":"13","author":"Wan","year":"2022","journal-title":"Nat. Commun."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"163309","DOI":"10.1016\/j.jallcom.2021.163309","article-title":"Development of electrically conductive ZrO2-CaO-Fe2O3-V2O5 glass and glass-ceramics as a new cathode active material for Na-ion batteries with high performance","volume":"899","author":"Khan","year":"2022","journal-title":"J. Alloys Compd."},{"key":"ref_34","first-page":"16184","article-title":"Ultrathin metal-organic framework nanosheets for electrocatalytic oxygen evolution","volume":"1","author":"Zhao","year":"2016","journal-title":"Energy"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"108044","DOI":"10.1016\/j.nanoen.2022.108044","article-title":"Topologic transition-induced abundant undercoordinated Fe active sites in NiFeOOH for superior oxygen evolution","volume":"106","author":"Jia","year":"2023","journal-title":"Nano Energy"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"1006820","DOI":"10.1016\/j.mser.2022.100682","article-title":"A comprehensive review of template-assisted porous carbons: Modern preparation methods and advanced applications","volume":"149","author":"Pavlenko","year":"2022","journal-title":"Mater. Sci. Eng. R Rep."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"2874","DOI":"10.3390\/ma5122874","article-title":"A Review: Fundamental aspects of silicate mesoporous materials","volume":"5","author":"Alothman","year":"2012","journal-title":"Materials"},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"116441","DOI":"10.1016\/j.fuel.2019.116441","article-title":"Capillary-condensation hysteresis in naturally-occurring nanoporous media","volume":"263","author":"Barsotti","year":"2020","journal-title":"Fuel"},{"key":"ref_39","first-page":"119","article-title":"Characterization of activated carbon adsorbents -state of the art and novel approaches","volume":"6","author":"Blaker","year":"2019","journal-title":"A Chem. Bio. Eng. Rev."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"114573","DOI":"10.1016\/j.ssc.2021.114573","article-title":"Use and misuse of the Kubelka-Munk function to obtain the band gap energy from diffuse reflectance measurements","volume":"341","author":"Landi","year":"2022","journal-title":"Solid State Commun."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"627","DOI":"10.1002\/pssb.19660150224","article-title":"Optical properties and electronic structure of amorphous germanium","volume":"15","author":"Tauc","year":"1966","journal-title":"Phys. Status Solidi"},{"key":"ref_42","first-page":"1262","article-title":"Electronic spectra of Fe3+ oxides and oxide hydroxide in the near IR to near UV","volume":"70","author":"Sherman","year":"1985","journal-title":"Am. Miner."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"40920","DOI":"10.1016\/j.ijhydene.2022.08.292","article-title":"Surface engineering of Ba-doped TiO2 nanorods by Bi2O3 passivation and (NiFe)OOH Co-catalyst layers for efficient and stable solar water oxidation","volume":"47","author":"Arunachalam","year":"2022","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"1083","DOI":"10.1007\/s42452-019-1113-0","article-title":"Synthesis and characterization of NiO nanoparticles by chemical as well as green routes and their comparisons with respect to cytotoxic effect and toxicity studies in microbial and MCF-7 cancer cell models","volume":"1","author":"Vijaya","year":"2019","journal-title":"SN Appl. Sci."},{"key":"ref_45","unstructured":"Schumacher, B., Bach, H., Spitzer, P., and Obrzut, J. (2011). Springer Handbook of Materials Measurement Methods, Springer."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"141457","DOI":"10.1016\/j.cej.2023.141457","article-title":"Bimetallic substrate induction synthesis of binder-free electrocatalysts for stable seawater oxidation at industrial current densities","volume":"458","author":"Zhou","year":"2023","journal-title":"Chem. Eng. J."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"122273","DOI":"10.1016\/j.apcatb.2022.122273","article-title":"Photocatalytic ozonation inactivation of bioaerosols by NiFeOOH nanosheets in situ grown on nickel foam","volume":"324","author":"Wang","year":"2023","journal-title":"Appl. Catal. B Environ."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"1051","DOI":"10.1016\/S0025-5408(02)00742-0","article-title":"Photoacoustic, EPR and electrical conductivity investigations of three synthetic mineral pigments: Hematite, goethite and magnetite","volume":"37","author":"Guskos","year":"2002","journal-title":"Mater. Res. Bull."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1016\/j.jnoncrysol.2018.02.012","article-title":"Electrical transport in iron phosphate glass-ceramics","volume":"502","author":"Skoko","year":"2018","journal-title":"J. Non-Cryst. Solids"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"3999","DOI":"10.1039\/C6CP04226K","article-title":"Polaronic transport in iron phosphate glasses containing HfO2 and CeO2","volume":"19","author":"Banhatti","year":"2017","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"2007","DOI":"10.1111\/j.1551-2916.2012.05149.x","article-title":"Polaronic mobility in boron doped iron phosphate glasses: Influence of structural disorder on summerfield scaling","volume":"95","author":"Ertap","year":"2012","journal-title":"J. Am. Ceram. Soc."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"23312","DOI":"10.1021\/acs.jpcc.9b03666","article-title":"Ionic conductivity of lithium germanium phosphate glass-ceramics","volume":"123","author":"Skoko","year":"2019","journal-title":"J. Phys. Chem. C"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"234701","DOI":"10.1063\/1.4882065","article-title":"Electron transport in pure and substituted iron oxyhydroxides by small-polaron migration","volume":"140","author":"Alexandrov","year":"2014","journal-title":"J. Chem. Phys."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"4120","DOI":"10.1021\/acs.jpclett.8b01525","article-title":"Photoexcited small polaron formation in goethite (\u03b1-FeOOH) nanorods probed by transient extreme ultraviolet spectroscopy","volume":"9","author":"Porter","year":"2018","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"2713","DOI":"10.1021\/acs.jpcc.0c10067","article-title":"Pressure-induced mixed protonic-electronic to pure electronic conduction transition in goethite","volume":"125","author":"Su","year":"2021","journal-title":"J. Phys. Chem. C"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1039\/D2YA00004K","article-title":"The role of specific and active surface areas in optimizing hard carbon irreversible capacity loss in sodium ion batteries","volume":"1","author":"Beda","year":"2022","journal-title":"Energy Adv."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"e202200045","DOI":"10.1002\/batt.202200045","article-title":"Impact of degree of graphitization, surface properties and particle size distribution on electrochemical performance of carbon anodes for potassium-ion batteries","volume":"5","author":"Wrogemann","year":"2022","journal-title":"Batter. Supercaps."}],"container-title":["International Journal of Molecular Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1422-0067\/24\/18\/14300\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T20:53:55Z","timestamp":1760129635000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1422-0067\/24\/18\/14300"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,9,19]]},"references-count":57,"journal-issue":{"issue":"18","published-online":{"date-parts":[[2023,9]]}},"alternative-id":["ijms241814300"],"URL":"https:\/\/doi.org\/10.3390\/ijms241814300","relation":{},"ISSN":["1422-0067"],"issn-type":[{"value":"1422-0067","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,9,19]]}}}