{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:22:01Z","timestamp":1760145721322,"version":"build-2065373602"},"reference-count":51,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2024,8,21]],"date-time":"2024-08-21T00:00:00Z","timestamp":1724198400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"General Program of Natural Science Foundation of Xinjiang Uygur Autonomous Region","award":["2022D01A76","KF202206","2022B02033-3","2022B02049-3-3","21561030","2021061"],"award-info":[{"award-number":["2022D01A76","KF202206","2022B02033-3","2022B02049-3-3","21561030","2021061"]}]},{"name":"Open Research Fund of Xinjiang Key Laboratory of Agricultural Chemistry and Biomaterials","award":["2022D01A76","KF202206","2022B02033-3","2022B02049-3-3","21561030","2021061"],"award-info":[{"award-number":["2022D01A76","KF202206","2022B02033-3","2022B02049-3-3","21561030","2021061"]}]},{"name":"Key Research and Development Projects of Xinjiang Uygur Autonomous Region","award":["2022D01A76","KF202206","2022B02033-3","2022B02049-3-3","21561030","2021061"],"award-info":[{"award-number":["2022D01A76","KF202206","2022B02033-3","2022B02049-3-3","21561030","2021061"]}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["2022D01A76","KF202206","2022B02033-3","2022B02049-3-3","21561030","2021061"],"award-info":[{"award-number":["2022D01A76","KF202206","2022B02033-3","2022B02049-3-3","21561030","2021061"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Xinjiang \u201cTianshan talent plan\u201d project","award":["2022D01A76","KF202206","2022B02033-3","2022B02049-3-3","21561030","2021061"],"award-info":[{"award-number":["2022D01A76","KF202206","2022B02033-3","2022B02049-3-3","21561030","2021061"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>By introducing disordered molecules into a crystal structure, the motion of the disordered molecules easily induces the formation of multidimensional frameworks in functional crystal materials, allowing for structural phase transitions and the realization of various dielectric properties within a certain temperature range. Here, we prepared a novel ionic complex [C7H8N3]3[Fe(NCS)6]\u00b7H2O (1) between 2-aminobenzimidazole and ferric isothiocyanate from ferric chloride hexahydrate, ammonium thiocyanate, and 2-aminobenzimidazole using the evaporation of the solvent method. The main components, the single-crystal structure, and the thermal and dielectric properties of the complex were characterized using infrared spectroscopy, elemental analysis, single-crystal X-ray diffraction, powder XRD, thermogravimetric analysis, differential scanning calorimetry, variable-temperature and variable-frequency dielectric constant tests, etc. The analysis results indicated that compound 1 belongs to the P21\/n space group. Within the crystal structure, the [Fe(NCS)6]3\u2212 anion formed a two-dimensional hydrogen-bonded network with the organic cation through S\u00b7\u00b7\u00b7S interactions and hydrogen bonding. The disorder\u2013order motion of the anions and cations within the crystal and the deformation of the crystal frameworks lead to a significant reversible isostructural phase transition and multiaxial dielectric anomalies of compound 1 at approximately 240 K.<\/jats:p>","DOI":"10.3390\/ijms25169064","type":"journal-article","created":{"date-parts":[[2024,8,26]],"date-time":"2024-08-26T05:16:24Z","timestamp":1724649384000},"page":"9064","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, the Reversible Isostructural Phase Transition, and the Dielectric Properties of a Functional Material Based on an Aminobenzimidazole\u2013Iron Thiocyanate Complex"],"prefix":"10.3390","volume":"25","author":[{"given":"Yang","family":"Liu","sequence":"first","affiliation":[{"name":"Chemistry and Chemical Engineering College, Xinjiang Agricultural University, Urumqi 830052, China"},{"name":"Xinjiang Sub-Center National Engineering Research Center of Novel Equipment for Polymer Processing, Urumqi 830052, China"},{"name":"Xinjiang Key Laboratory of Agricultural Chemistry and Biomaterials, Urumqi 830052, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Adila","family":"Abuduheni","sequence":"additional","affiliation":[{"name":"Chemistry and Chemical Engineering College, Xinjiang Agricultural University, Urumqi 830052, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fang","family":"Yang","sequence":"additional","affiliation":[{"name":"Chemistry and Chemical Engineering College, Xinjiang Agricultural University, Urumqi 830052, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hongzhi","family":"Hu","sequence":"additional","affiliation":[{"name":"Chemistry and Chemical Engineering College, Xinjiang Agricultural University, Urumqi 830052, China"},{"name":"Xinjiang Sub-Center National Engineering Research Center of Novel Equipment for Polymer Processing, Urumqi 830052, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zunqi","family":"Liu","sequence":"additional","affiliation":[{"name":"Chemistry and Chemical Engineering College, Xinjiang Agricultural University, Urumqi 830052, China"},{"name":"Xinjiang Sub-Center National Engineering Research Center of Novel Equipment for Polymer Processing, Urumqi 830052, China"},{"name":"Xinjiang Key Laboratory of Agricultural Chemistry and Biomaterials, Urumqi 830052, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2024,8,21]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"20989","DOI":"10.1021\/acs.jpcc.8b06538","article-title":"Semiconducting Organic\u2014Inorganic Hybrid Material with Distinct Switchable Dielectric Phase Transition","volume":"122","author":"Zhang","year":"2018","journal-title":"J. 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