{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,30]],"date-time":"2026-10-30T05:26:37Z","timestamp":1793337997826,"version":"4.5.0"},"reference-count":57,"publisher":"MDPI AG","issue":"18","license":[{"start":{"date-parts":[[2024,9,12]],"date-time":"2024-09-12T00:00:00Z","timestamp":1726099200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Major Program Natural Science Foundation of Hunan Province of China","award":["2021JC0001"],"award-info":[{"award-number":["2021JC0001"]}]},{"name":"Major Program Natural Science Foundation of Hunan Province of China","award":["2023JJ31010"],"award-info":[{"award-number":["2023JJ31010"]}]},{"name":"Major Program Natural Science Foundation of Hunan Province of China","award":["2024JJ7647"],"award-info":[{"award-number":["2024JJ7647"]}]},{"name":"Major Program Natural Science Foundation of Hunan Province of China","award":["2024JJ7094"],"award-info":[{"award-number":["2024JJ7094"]}]},{"name":"Major Program Natural Science Foundation of Hunan Province of China","award":["23A0225"],"award-info":[{"award-number":["23A0225"]}]},{"name":"Major Program Natural Science Foundation of Hunan Province of China","award":["HBKYXM-2023038"],"award-info":[{"award-number":["HBKYXM-2023038"]}]},{"name":"Major Program Natural Science Foundation of Hunan Province of China","award":["22B0883"],"award-info":[{"award-number":["22B0883"]}]},{"name":"Major Program Natural Science Foundation of Hunan Province of China","award":["ES202380056"],"award-info":[{"award-number":["ES202380056"]}]},{"name":"Major Program Natural Science Foundation of Hunan Province of China","award":["2020YJ010"],"award-info":[{"award-number":["2020YJ010"]}]},{"name":"Hunan Provincial Natural Science Foundation of China","award":["2021JC0001"],"award-info":[{"award-number":["2021JC0001"]}]},{"name":"Hunan Provincial Natural Science Foundation of China","award":["2023JJ31010"],"award-info":[{"award-number":["2023JJ31010"]}]},{"name":"Hunan Provincial Natural Science Foundation of China","award":["2024JJ7647"],"award-info":[{"award-number":["2024JJ7647"]}]},{"name":"Hunan Provincial Natural Science Foundation of China","award":["2024JJ7094"],"award-info":[{"award-number":["2024JJ7094"]}]},{"name":"Hunan Provincial Natural Science Foundation of China","award":["23A0225"],"award-info":[{"award-number":["23A0225"]}]},{"name":"Hunan Provincial Natural Science Foundation of China","award":["HBKYXM-2023038"],"award-info":[{"award-number":["HBKYXM-2023038"]}]},{"name":"Hunan Provincial Natural Science Foundation of China","award":["22B0883"],"award-info":[{"award-number":["22B0883"]}]},{"name":"Hunan Provincial Natural Science Foundation of China","award":["ES202380056"],"award-info":[{"award-number":["ES202380056"]}]},{"name":"Hunan Provincial Natural Science Foundation of China","award":["2020YJ010"],"award-info":[{"award-number":["2020YJ010"]}]},{"name":"Key Project of Scientific Research Project of Hunan Provincial Department of Education","award":["2021JC0001"],"award-info":[{"award-number":["2021JC0001"]}]},{"name":"Key Project of Scientific Research Project of Hunan Provincial Department of Education","award":["2023JJ31010"],"award-info":[{"award-number":["2023JJ31010"]}]},{"name":"Key Project of Scientific Research Project of Hunan Provincial Department of Education","award":["2024JJ7647"],"award-info":[{"award-number":["2024JJ7647"]}]},{"name":"Key Project of Scientific Research Project of Hunan Provincial Department of Education","award":["2024JJ7094"],"award-info":[{"award-number":["2024JJ7094"]}]},{"name":"Key Project of Scientific Research Project of Hunan Provincial Department of Education","award":["23A0225"],"award-info":[{"award-number":["23A0225"]}]},{"name":"Key Project of Scientific Research Project of Hunan Provincial Department of Education","award":["HBKYXM-2023038"],"award-info":[{"award-number":["HBKYXM-2023038"]}]},{"name":"Key Project of Scientific Research Project of Hunan Provincial Department of Education","award":["22B0883"],"award-info":[{"award-number":["22B0883"]}]},{"name":"Key Project of Scientific Research Project of Hunan Provincial Department of Education","award":["ES202380056"],"award-info":[{"award-number":["ES202380056"]}]},{"name":"Key Project of Scientific Research Project of Hunan Provincial Department of Education","award":["2020YJ010"],"award-info":[{"award-number":["2020YJ010"]}]},{"name":"Hunan Province Environmental Protection Research Project","award":["2021JC0001"],"award-info":[{"award-number":["2021JC0001"]}]},{"name":"Hunan Province Environmental Protection Research Project","award":["2023JJ31010"],"award-info":[{"award-number":["2023JJ31010"]}]},{"name":"Hunan Province Environmental Protection Research Project","award":["2024JJ7647"],"award-info":[{"award-number":["2024JJ7647"]}]},{"name":"Hunan Province Environmental Protection Research Project","award":["2024JJ7094"],"award-info":[{"award-number":["2024JJ7094"]}]},{"name":"Hunan Province Environmental Protection Research Project","award":["23A0225"],"award-info":[{"award-number":["23A0225"]}]},{"name":"Hunan Province Environmental Protection Research Project","award":["HBKYXM-2023038"],"award-info":[{"award-number":["HBKYXM-2023038"]}]},{"name":"Hunan Province Environmental Protection Research Project","award":["22B0883"],"award-info":[{"award-number":["22B0883"]}]},{"name":"Hunan Province Environmental Protection Research Project","award":["ES202380056"],"award-info":[{"award-number":["ES202380056"]}]},{"name":"Hunan Province Environmental Protection Research Project","award":["2020YJ010"],"award-info":[{"award-number":["2020YJ010"]}]},{"name":"Education Department of Hunan Province","award":["2021JC0001"],"award-info":[{"award-number":["2021JC0001"]}]},{"name":"Education Department of Hunan Province","award":["2023JJ31010"],"award-info":[{"award-number":["2023JJ31010"]}]},{"name":"Education Department of Hunan Province","award":["2024JJ7647"],"award-info":[{"award-number":["2024JJ7647"]}]},{"name":"Education Department of Hunan Province","award":["2024JJ7094"],"award-info":[{"award-number":["2024JJ7094"]}]},{"name":"Education Department of Hunan Province","award":["23A0225"],"award-info":[{"award-number":["23A0225"]}]},{"name":"Education Department of Hunan Province","award":["HBKYXM-2023038"],"award-info":[{"award-number":["HBKYXM-2023038"]}]},{"name":"Education Department of Hunan Province","award":["22B0883"],"award-info":[{"award-number":["22B0883"]}]},{"name":"Education Department of Hunan Province","award":["ES202380056"],"award-info":[{"award-number":["ES202380056"]}]},{"name":"Education Department of Hunan Province","award":["2020YJ010"],"award-info":[{"award-number":["2020YJ010"]}]},{"name":"National Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Open Fund","award":["2021JC0001"],"award-info":[{"award-number":["2021JC0001"]}]},{"name":"National Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Open Fund","award":["2023JJ31010"],"award-info":[{"award-number":["2023JJ31010"]}]},{"name":"National Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Open Fund","award":["2024JJ7647"],"award-info":[{"award-number":["2024JJ7647"]}]},{"name":"National Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Open Fund","award":["2024JJ7094"],"award-info":[{"award-number":["2024JJ7094"]}]},{"name":"National Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Open Fund","award":["23A0225"],"award-info":[{"award-number":["23A0225"]}]},{"name":"National Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Open Fund","award":["HBKYXM-2023038"],"award-info":[{"award-number":["HBKYXM-2023038"]}]},{"name":"National Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Open Fund","award":["22B0883"],"award-info":[{"award-number":["22B0883"]}]},{"name":"National Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Open Fund","award":["ES202380056"],"award-info":[{"award-number":["ES202380056"]}]},{"name":"National Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Open Fund","award":["2020YJ010"],"award-info":[{"award-number":["2020YJ010"]}]},{"name":"Scientific Research Foundation for Talented Scholars of CSUFT","award":["2021JC0001"],"award-info":[{"award-number":["2021JC0001"]}]},{"name":"Scientific Research Foundation for Talented Scholars of CSUFT","award":["2023JJ31010"],"award-info":[{"award-number":["2023JJ31010"]}]},{"name":"Scientific Research Foundation for Talented Scholars of CSUFT","award":["2024JJ7647"],"award-info":[{"award-number":["2024JJ7647"]}]},{"name":"Scientific Research Foundation for Talented Scholars of CSUFT","award":["2024JJ7094"],"award-info":[{"award-number":["2024JJ7094"]}]},{"name":"Scientific Research Foundation for Talented Scholars of CSUFT","award":["23A0225"],"award-info":[{"award-number":["23A0225"]}]},{"name":"Scientific Research Foundation for Talented Scholars of CSUFT","award":["HBKYXM-2023038"],"award-info":[{"award-number":["HBKYXM-2023038"]}]},{"name":"Scientific Research Foundation for Talented Scholars of CSUFT","award":["22B0883"],"award-info":[{"award-number":["22B0883"]}]},{"name":"Scientific Research Foundation for Talented Scholars of CSUFT","award":["ES202380056"],"award-info":[{"award-number":["ES202380056"]}]},{"name":"Scientific Research Foundation for Talented Scholars of CSUFT","award":["2020YJ010"],"award-info":[{"award-number":["2020YJ010"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>Tetracycline\u2019s accumulation in the environment poses threats to human health and the ecological balance, necessitating efficient and rapid removal methods. Novel porous metal\u2013organic framework (MOF) materials have garnered significant attention in academia due to their distinctive characteristics. This paper focuses on studying the adsorption and removal performance of amino-modified MIL-101(Fe) materials towards tetracycline, along with their adsorption mechanisms. The main research objectives and conclusions are as follows: (1) NH2-MIL-101(Fe) MOF materials were successfully synthesized via the solvothermal method, confirmed through various characterization techniques including XRD, FT-IR, SEM, EDS, XPS, BET, and TGA. (2) NH2-MIL-101(Fe) exhibited a 40% enhancement in tetracycline adsorption performance compared to MIL-101(Fe), primarily through chemical adsorption following pseudo-second-order kinetics. The adsorption process conformed well to Freundlich isotherm models, indicating multilayer and heterogeneous adsorption characteristics. Thermodynamic analysis revealed the adsorption process as a spontaneous endothermic reaction. (3) An increased adsorbent dosage and temperature correspondingly improved NH2-MIL-101(Fe)\u2019s adsorption efficiency, with optimal performance observed under neutral pH conditions. These findings provide new strategies for the effective removal of tetracycline from the environment, thus holding significant implications for environmental protection.<\/jats:p>","DOI":"10.3390\/ijms25189855","type":"journal-article","created":{"date-parts":[[2024,9,12]],"date-time":"2024-09-12T06:31:40Z","timestamp":1726122700000},"page":"9855","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":92,"title":["Preparation of NH2-MIL-101(Fe) Metal Organic Framework and Its Performance in Adsorbing and Removing Tetracycline"],"prefix":"10.3390","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9642-9973","authenticated-orcid":false,"given":"Yiting","family":"Luo","sequence":"first","affiliation":[{"name":"School of Business, Hunan First Normal University, Changsha 410114, China"},{"name":"National Engineering Laboratory of Southern Forestry Ecological Application Technology, Changsha 410004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9830-6176","authenticated-orcid":false,"given":"Rongkui","family":"Su","sequence":"additional","affiliation":[{"name":"College of Life and Environmental Sciences, Central South University of Forestry and Technology, Changsha 410004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,9,12]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"450","DOI":"10.1016\/j.apcatb.2019.02.046","article-title":"Quantification of the local magnetized nanotube domains accelerating the photocatalytic removal of the emerging pollutant tetracycline","volume":"248","author":"Yu","year":"2019","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"141975","DOI":"10.1016\/j.scitotenv.2020.141975","article-title":"Occurrence, fate, and risk assessment of typical tetracycline antibiotics in the aquatic environment: A review","volume":"753","author":"Xu","year":"2021","journal-title":"Sci. Total Environ."},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Amangelsin, Y., Semenova, Y., Dadar, M., Aljofan, M., and Bjorklund, G. (2023). The impact of tetracycline pollution on the aquatic environment and removal strategies. Antibiotics, 12.","DOI":"10.3390\/antibiotics12030440"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"134681","DOI":"10.1016\/j.jhazmat.2024.134681","article-title":"Integrated assessment of the spatial distribution, sources, degradation, and human risk of tetracyclines in honey in China","volume":"473","author":"Wang","year":"2024","journal-title":"J. Hazard. Mater."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"9474","DOI":"10.1021\/acs.est.2c09854","article-title":"Antimicrobial transformation products in the aquatic environment: Global occurrence, ecotoxicological risks, and potential of antibiotic resistance","volume":"57","author":"Loffler","year":"2023","journal-title":"Environ. Sci. Technol."},{"key":"ref_6","doi-asserted-by":"crossref","unstructured":"Cyco\u0144, M., Mrozik, A., and Piotrowska-Seget, Z. (2019). Antibiotics in the soil environment\u2014Degradation and their impact on microbial activity and diversity. Front. Microbiol., 10.","DOI":"10.3389\/fmicb.2019.00338"},{"key":"ref_7","doi-asserted-by":"crossref","unstructured":"Luo, Y., and Su, R. (2024). Environmental impact of waste treatment and synchronous hydrogen production: Based on life cycle assessment method. Toxics, 12.","DOI":"10.3390\/toxics12090652"},{"key":"ref_8","doi-asserted-by":"crossref","unstructured":"Su, R., Xie, C., Alhassan, S.I., Huang, S., Chen, R., Xiang, S., Wang, Z., and Huang, L. (2020). Oxygen reduction reaction in the field of water environment for application of nanomaterials. Nanomaterials, 10.","DOI":"10.3390\/nano10091719"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"754","DOI":"10.1007\/s11270-023-06770-2","article-title":"Advances in the degradation of emerging contaminants by persulfate oxidation technology","volume":"234","author":"Su","year":"2023","journal-title":"Water Air Soil. Poll."},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Luo, Y., and Su, R. (2024). Cobalt-based mof material activates persulfate to degrade residual ciprofloxacin. Water, 16.","DOI":"10.3390\/w16162299"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"202","DOI":"10.1038\/s41570-023-00463-4","article-title":"Metals to combat antimicrobial resistance","volume":"7","author":"Frei","year":"2023","journal-title":"Nat. Rev. Chem."},{"key":"ref_12","doi-asserted-by":"crossref","unstructured":"Hu, P., Shao, J.Y., Qian, G.S., Adeleye, S.A., and Hao, T.W. (2022). Removal of tetracycline by aerobic granular sludge from marine aquaculture wastewater: A molecular dynamics investigation. Bioresour. Technol., 355.","DOI":"10.1016\/j.biortech.2022.127286"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"136321","DOI":"10.1016\/j.jclepro.2023.136321","article-title":"Insights into biodegradation of antibiotics during the biofilm-based wastewater treatment processes","volume":"393","author":"Wang","year":"2023","journal-title":"J. Clean. Prod."},{"key":"ref_14","doi-asserted-by":"crossref","unstructured":"Cheng, D.L., Ngo, H.H., Guo, W.S., Chang, S.W., Nguyen, D.D., Liu, Y.W., Shan, X., Nghiem, L.D., and Nguyen, L.N. (2020). Removal process of antibiotics during anaerobic treatment of swine wastewater. Bioresour. Technol., 300.","DOI":"10.1016\/j.biortech.2019.122707"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"107366","DOI":"10.1016\/j.jece.2022.107366","article-title":"Activation of peroxydisulfate by bimetal modified peanut hull-derived porous biochar for the degradation of tetracycline in aqueous solution","volume":"10","author":"Pan","year":"2022","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"2174","DOI":"10.2166\/wst.2018.129","article-title":"Comparison of the degradation of molecular and ionic ibuprofen in a UV\/H2O2 system","volume":"77","author":"Su","year":"2018","journal-title":"Water Sci. Technol."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"62572","DOI":"10.1007\/s11356-021-15146-0","article-title":"Degradation of trimethoprim by sulfate radical-based advanced oxidation processes: Kinetics, mechanisms, and effects of natural water matrices","volume":"28","author":"Luo","year":"2021","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"2578","DOI":"10.1080\/01496395.2023.2259079","article-title":"A review on current pollution and removal methods of tetracycline in soil","volume":"58","author":"Ren","year":"2023","journal-title":"Sep. Sci. Technol."},{"key":"ref_19","doi-asserted-by":"crossref","unstructured":"Su, R., Dai, X., Wang, H., Wang, Z., Li, Z., Chen, Y., Luo, Y., and Ouyang, D. (2022). Metronidazole degradation by UV and UV\/H2O2 advanced oxidation processes: Kinetics, mechanisms, and effects of natural water matrices. Int. J. Environ. Res. Public Health, 19.","DOI":"10.3390\/ijerph191912354"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"159815","DOI":"10.1016\/j.scitotenv.2022.159815","article-title":"A review of antibiotics and antibiotic resistance genes (ARGs) adsorption by biochar and modified biochar in water","volume":"858","author":"Du","year":"2023","journal-title":"Sci. Total Environ."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"907","DOI":"10.1289\/ehp.99107s6907","article-title":"Pharmaceuticals and personal care products in the environment: Agents of subtle change?","volume":"107","author":"Daughton","year":"1999","journal-title":"Environ. Health Perspect."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"770","DOI":"10.1016\/j.jcis.2024.05.165","article-title":"Targeted improvement of narrow micropores in porous carbon for enhancing trace benzene vapor removal: Revealing the adsorption mechanism via experimental and molecular simulation","volume":"671","author":"Su","year":"2024","journal-title":"J. Colloid. Interf. Sci."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"112425","DOI":"10.1016\/j.envres.2021.112425","article-title":"HKUST-1 derived carbon adsorbents for tetracycline removal with excellent adsorption performance","volume":"205","author":"Pan","year":"2022","journal-title":"Environ. Res."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"115676","DOI":"10.1016\/j.envres.2023.115676","article-title":"Adsorptive decontamination of antibiotics from livestock wastewater by using alkaline-modified biochar","volume":"226","author":"Zhao","year":"2023","journal-title":"Environ. Res."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"939","DOI":"10.1126\/science.1152516","article-title":"High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture","volume":"319","author":"Banerjee","year":"2008","journal-title":"Science"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"2610","DOI":"10.1021\/jacs.7b12420","article-title":"Core-Shell ZIF-8@ZIF-67-Derived CoP Nanoparticle-Embedded N-Doped Carbon Nanotube Hollow Polyhedron for Efficient Overall Water Splitting","volume":"140","author":"Pan","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"2111","DOI":"10.1080\/00958972.2021.1965130","article-title":"A review on state of art and perspectives of Metal-Organic frameworks (MOFs) in the fight against coronavirus SARS-CoV-2","volume":"74","year":"2021","journal-title":"J. Coord. Chem."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/j.colsurfa.2012.11.067","article-title":"Synthesis, characterization and sorption properties of zinc(II) metal\u2013organic framework containing methanetetrabenzoate ligand","volume":"437","author":"Gyepes","year":"2013","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1016\/j.apcatb.2013.10.056","article-title":"Iron terephthalate metal-organic framework: Revealing the effective activation of hydrogen peroxide for the degradation of organic dye under visible light irradiation","volume":"148","author":"Ai","year":"2014","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"8775","DOI":"10.1021\/ja901587t","article-title":"Comparative study of hydrogen sulfide adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) metal\u2212organic frameworks at room temperature","volume":"131","author":"Hamon","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"23794","DOI":"10.1039\/C7TA07934F","article-title":"Bifunctional NH2-MIL-88(Fe) metal\u2013organic framework nanooctahedra for highly sensitive detection and efficient removal of arsenate in aqueous media","volume":"5","author":"Xie","year":"2017","journal-title":"J. Mater. Chem. A"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"7533","DOI":"10.1021\/acs.cgd.8b01340","article-title":"Effect of the synergetic interplay between the electrostatic interactions, size of the dye molecules, and adsorption sites of MIL-101(Cr) on the adsorption of organic dyes from aqueous solutions","volume":"18","author":"Zhang","year":"2018","journal-title":"Cryst. Growth Des."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"310","DOI":"10.1038\/nchem.1272","article-title":"Imparting functionality to a metal-organic framework material by controlled nanoparticle encapsulation","volume":"4","author":"Lu","year":"2012","journal-title":"Nature Chem."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"278","DOI":"10.1039\/D2RE00365A","article-title":"Current trends in the synthesis, characterization and application of metal-organic frameworks","volume":"8","author":"Udourioh","year":"2023","journal-title":"React. Chem. Eng."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"11894","DOI":"10.1007\/s10853-023-08747-2","article-title":"Solvothermal synthesis of nanostructured nickel-based metal\u2013organic frameworks (Ni-MOFs) with enhanced electrochemical performance for symmetric supercapacitors","volume":"58","author":"Zheng","year":"2023","journal-title":"J. Mater. Sci."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"109954","DOI":"10.1016\/j.jece.2023.109954","article-title":"Synthesis and modification methods of metal-organic frameworks and their application in modification of polymeric ultrafiltration membranes: A review","volume":"11","author":"Dehghankar","year":"2023","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"2838","DOI":"10.1039\/c0cc04526h","article-title":"Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid","volume":"47","author":"Bernt","year":"2011","journal-title":"Chem. Commun."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"3294","DOI":"10.1002\/adma.201101356","article-title":"Cellulose hydrolysis by a new porous coordination polymer decorated with sulfonic acid functional groups","volume":"23","author":"Akiyama","year":"2011","journal-title":"Adv. Mater."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"6151","DOI":"10.1039\/c2cc32384b","article-title":"A strategy toward constructing a bifunctionalized MOF catalyst: Post-synthetic modification of MOFs on organic ligands and coordinatively unsaturated metal sites","volume":"48","author":"Li","year":"2012","journal-title":"Chem. Commun."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"215259","DOI":"10.1016\/j.ccr.2023.215259","article-title":"Post-synthetic modification of metal-organic framework-based membranes for enhanced molecular separations","volume":"491","author":"Chen","year":"2023","journal-title":"Coord. Chem. Rev."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"907","DOI":"10.1016\/j.chemosphere.2018.07.085","article-title":"ZrO2 nanoparticles confined in metal organic frameworks for highly effective adsorption of phosphate","volume":"210","author":"Liu","year":"2018","journal-title":"Chemosphere"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1007\/s11696-017-0276-7","article-title":"A novel catalyst of MIL-101(Fe) doped with Co and Cu as persulfate activator: Synthesis, characterization, and catalytic performance","volume":"72","author":"Duan","year":"2018","journal-title":"Chem. Pap."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"122111","DOI":"10.1016\/j.cej.2019.122111","article-title":"A novel and universal metal-organic frameworks sensing platform for selective detection and efficient removal of heavy metal ions","volume":"375","author":"Lv","year":"2019","journal-title":"Chem. Eng. J."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.molcata.2013.03.020","article-title":"Nano-rod catalysts: Building MOF bottles (MIL-101 family as heterogeneous single-site catalysts) around vanadium oxide ships","volume":"374","author":"Fazaeli","year":"2013","journal-title":"J. Mol. Catal. A Chem."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"1406","DOI":"10.1016\/j.cej.2015.08.087","article-title":"Adsorptive removal of diclofenac sodium from water with Zr-based metal\u2013organic frameworks","volume":"284","author":"Hasan","year":"2016","journal-title":"Chem. Eng. J."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"128991","DOI":"10.1016\/j.fuel.2023.128991","article-title":"Synthesis, characterization, and selective gas adsorption performance of hybrid NH2-MIL-101(Fe)\/ZIF-8 metal organic framework (MOF)","volume":"351","author":"Hosseini","year":"2023","journal-title":"Fuel"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"101004","DOI":"10.1016\/j.jwpe.2019.101004","article-title":"MOF [NH2-MIL-101(Fe)] as a powerful and reusable Fenton-like catalyst","volume":"33","author":"Taha","year":"2019","journal-title":"J. Water Process Eng."},{"key":"ref_48","doi-asserted-by":"crossref","unstructured":"Mo, L.J., Chen, G.Z., and Wang, H. (2024). Degradation of orange g using pms triggered by NH2-MIL-101(Fe): An amino-functionalized metal-organic framework. Molecules, 29.","DOI":"10.3390\/molecules29071488"},{"key":"ref_49","unstructured":"Zhang, H. (2022). Fabrication of NH2-MIL-101(Fe) Metal-Organic Framework and Its Photocatalytic Performance for Degrading Antibiotics. [Master\u2019s Thesis, Donghua University]."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"1735","DOI":"10.1007\/s13738-019-01647-w","article-title":"Comparison of MIL-101 (Fe) and amine-functionalized MIL-101 (Fe) as photocatalysts for the removal of imidacloprid in aqueous solution","volume":"16","author":"Gecgel","year":"2019","journal-title":"J. Iran. Chem. Soc."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"31171","DOI":"10.1109\/JSEN.2023.3328257","article-title":"Synthesis and dielectric characterization of Iron-Doped forsterite coated titanium-based medical implants","volume":"23","author":"Pandey","year":"2023","journal-title":"IEEE Sens. J."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"123060","DOI":"10.1016\/j.matchemphys.2020.123060","article-title":"Influence of microwave-assisted synthesis on the structural and textural properties of mesoporous MIL-101 (Fe) and NH2-MIL-101 (Fe) for enhanced tetracycline adsorption","volume":"251","author":"Dong","year":"2020","journal-title":"Mater. Chem. Phys."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"197","DOI":"10.1016\/j.biortech.2019.03.096","article-title":"Influence of pyrolysis temperature on polycyclic aromatic hydrocarbons production and tetracycline adsorption behavior of biochar derived from spent coffee ground","volume":"284","author":"Nguyen","year":"2019","journal-title":"Bioresour. Technol."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"194","DOI":"10.1016\/j.jhazmat.2018.12.080","article-title":"Facile fabrication of hierarchical porous ZIF-8 for enhanced adsorption of antibiotics","volume":"367","author":"Chen","year":"2019","journal-title":"J. Hazard. Mater."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"398","DOI":"10.1016\/j.envpol.2019.03.049","article-title":"A spectroscopic and theoretical investigation of interaction mechanisms of tetracycline and polystyrene nanospheres under different conditions","volume":"249","author":"Wan","year":"2019","journal-title":"Environ. Pollut."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"123199","DOI":"10.1016\/j.apcatb.2023.123199","article-title":"One-pot synthesis of NH2-MIL-101(Fe) and \u03b1-Fe2O3 composite as efficient heterojunction for multifunctional photocatalytic membranes: Towards zero waste generation","volume":"340","author":"Vinothkumar","year":"2024","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"7568","DOI":"10.1021\/ic800538r","article-title":"High-throughput assisted rationalization of the formation of metal organic frameworks in the iron(III) aminoterephthalate solvothermal system","volume":"47","author":"Bauer","year":"2008","journal-title":"Inorg. Chem."}],"container-title":["International Journal of Molecular Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1422-0067\/25\/18\/9855\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T15:54:34Z","timestamp":1760111674000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1422-0067\/25\/18\/9855"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,9,12]]},"references-count":57,"journal-issue":{"issue":"18","published-online":{"date-parts":[[2024,9]]}},"alternative-id":["ijms25189855"],"URL":"https:\/\/doi.org\/10.3390\/ijms25189855","relation":{},"ISSN":["1422-0067"],"issn-type":[{"value":"1422-0067","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,9,12]]}}}