{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T10:56:45Z","timestamp":1778756205720,"version":"3.51.4"},"reference-count":63,"publisher":"MDPI AG","issue":"18","license":[{"start":{"date-parts":[[2025,9,20]],"date-time":"2025-09-20T00:00:00Z","timestamp":1758326400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"DONGJIN ENGINEERING CO., LTD."}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>The formation and growth processes of octaneselenolate (C8Se) self-assembled monolayers (SAMs) on Au(111) from dioctyl diselenides were investigated by scanning tunneling microscopy (STM) as a function of vapor deposition time at 363 K. STM observations revealed unique surface features of the C8Se SAMs on Au(111) prepared at 363 K for 1 h, consisting of various types of narrow, bright molecular rows and broad, bright molecular rows with three-directional orientations. After increasing the deposition time from 1 and 6 h, interestingly, the structural quality of C8Se SAMs is greatly enhanced, showing the formation of tri-directional highly ordered domains with distinct domain boundaries on an entire Au(111) surface. The observed ordered phase can be described by a (2 \u00d7 2\u221a7)rect packing structure with an arial density of 28.9 \u00c52\/molecule. C8Se SAMs at 363 K for 24 h consisted of long-range, highly ordered domains and large, disordered domains. The ordered phase can be described by a (\u221a3 \u00d7 \u221a23)rect packing structure with an arial density of 23.3 \u00c52\/molecule, which is denser than that of C8Se SAMs formed by vapor deposition at 363 K and for 6 h. This study clearly demonstrates that vapor deposition is a highly effective method for preparing highly ordered alkyl selenolate SAMs on Au(111). Furthermore, molecular-scale STM results provide new insights into the formation and growth processes of alkyl selenolate SAMs on Au(111) formed by vapor deposition of dialkyl diselenides at high temperatures.<\/jats:p>","DOI":"10.3390\/ijms26189192","type":"journal-article","created":{"date-parts":[[2025,9,22]],"date-time":"2025-09-22T13:04:44Z","timestamp":1758546284000},"page":"9192","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Formation and Structure of Highly Ordered Self-Assembled Monolayers on Au(111) via Vapor Deposition of Dioctyl Diselenides"],"prefix":"10.3390","volume":"26","author":[{"given":"Seulki","family":"Han","sequence":"first","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jin Wook","family":"Han","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sicheon","family":"Seong","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Young Ji","family":"Son","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Riko","family":"Kaizu","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, School of Materials and Chemical Technology, Institute of Science Tokyo, Yokohama 226-8502, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-3839-546X","authenticated-orcid":false,"given":"Glenn Villena","family":"Latag","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, School of Materials and Chemical Technology, Institute of Science Tokyo, Yokohama 226-8502, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4065-1807","authenticated-orcid":false,"given":"Tomohiro","family":"Hayashi","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, School of Materials and Chemical Technology, Institute of Science Tokyo, Yokohama 226-8502, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6115-7971","authenticated-orcid":false,"given":"Jaegeun","family":"Noh","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"},{"name":"Research Institute for Convergence of Basic Science, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2025,9,20]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2138","DOI":"10.1021\/acs.chemrev.3c00396","article-title":"Self-Assembled Monolayers for Interfacial Engineering in Solution Processed Thin Film Electronic Devices","volume":"124","author":"Li","year":"2024","journal-title":"Chem. 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