{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T22:28:39Z","timestamp":1792794519240,"version":"4.5.0"},"reference-count":71,"publisher":"MDPI AG","issue":"18","license":[{"start":{"date-parts":[[2025,9,22]],"date-time":"2025-09-22T00:00:00Z","timestamp":1758499200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>Mesoporous silica materials with well-organized architectures were synthesized using a series of Pluronic PE-type triblock copolymers (PE6800, PE9200, PE9400, PE10500) as structure-directing agents under acidic conditions. The study aimed to elucidate the impact of synthesis parameters\u2014copolymer type, presence of a swelling agent, 1,3,5-trimethylbenzene, aging temperature, and silica precursor\u2014on the structural, textural, and functional properties of the resulting mesocellular foam materials. Characterization by Nitrogen Adsorption\/Desorption, Transmission Electron Microscopy, X-ray Diffraction, and Small-angle X-ray Scattering revealed that structural ordering and pore morphology are significantly influenced by the EO\/PO ratio of the copolymers and the use of the expander. Materials synthesized with PE9400 and PE10500 in the presence of a swelling agent exhibited highly uniform bottle-shaped mesopores with increased surface area and pore volume. Thermal behavior studied via Differential Scanning Calorimetry indicated a correlation between pore size and melting point depression of confined water, consistent with the Gibbs\u2013Thomson effect. Adsorption capacity and kinetics for methylene blue varied significantly with pore structure, with materials possessing narrow mesopores showing superior dye uptake, and materials with larger mesopores and open-pore architecture exhibiting faster adsorption rates. This work demonstrates the tunability of mesoporous silica structure through precise control of synthesis conditions and highlights its potential in applications involving adsorption and phase phenomena in confined pore systems.<\/jats:p>","DOI":"10.3390\/ijms26189255","type":"journal-article","created":{"date-parts":[[2025,9,22]],"date-time":"2025-09-22T17:08:17Z","timestamp":1758560897000},"page":"9255","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Mesoporous Silicas of Well-Organized Structure: Synthesis, Characterization, and Investigation of Physical Processes Occurring in Confined Pore Spaces"],"prefix":"10.3390","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6281-9084","authenticated-orcid":false,"given":"Magdalena","family":"Blachnio","sequence":"first","affiliation":[{"name":"Department of Physical Chemistry, Institute of Chemical Sciences, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Square 3, 20-031 Lublin, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0775-5417","authenticated-orcid":false,"given":"Malgorzata","family":"Zienkiewicz-Strzalka","sequence":"additional","affiliation":[{"name":"Department of Physical Chemistry, Institute of Chemical Sciences, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Square 3, 20-031 Lublin, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0208-1257","authenticated-orcid":false,"given":"Anna","family":"Derylo-Marczewska","sequence":"additional","affiliation":[{"name":"Department of Physical Chemistry, Institute of Chemical Sciences, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Square 3, 20-031 Lublin, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,9,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"12149","DOI":"10.1016\/j.ceramint.2019.03.118","article-title":"Dependence of mesoporous silica properties on its template","volume":"45","author":"Mahmud","year":"2019","journal-title":"Ceram. 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