{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T14:19:44Z","timestamp":1787581184666,"version":"build-2736575974"},"reference-count":61,"publisher":"MDPI AG","issue":"17","license":[{"start":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T00:00:00Z","timestamp":1787529600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["25-73-20065"],"award-info":[{"award-number":["25-73-20065"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]},{"award":["25-73-20065"],"award-info":[{"award-number":["25-73-20065"]}],"id":[{"id":"https:\/\/ror.org\/03y2gwe85","id-type":"ROR","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Int. J. Mol. Sci.","IJMS"],"abstract":"<jats:p>Three zinc(II) complexes based on 1-phenyl-3-methyl-4-acyl-5-pyrazolone were synthesized and characterized by elemental analysis, by X-ray crystallography and spectroscopy (UV-vis, fluorescence and IR). Crystallographic studies reveal that the complexes have a mononuclear structure in the solid state; however, intermolecular interactions combine the complexes into a 1D polymer chain. The complexes exhibit weak luminescence in the polycrystalline state and moderate emission in solutions and thin amorphous films. Thin films of the studied compounds were deposited on a glass substrate using thermal vacuum spraying, spin coating, and Langmuir-Blodgett technology and were studied using atomic force microscopy (AFM), X-ray spectroscopy, and fluorescence spectroscopy.<\/jats:p>","DOI":"10.3390\/ijms27177560","type":"journal-article","created":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T13:20:43Z","timestamp":1787577643000},"page":"7560","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Zn Complexes with the 4-Acyl-Pyrazol-5-One Basis and Their Thin Films"],"prefix":"10.3390","volume":"27","author":[{"given":"Alexey","family":"Gusev","sequence":"first","affiliation":[{"name":"General Chemistry Department, Crimean Federal University V.I. 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Chall."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1704158","DOI":"10.1002\/adfm.201704158","article-title":"History of Organic-Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications","volume":"28","author":"Faustini","year":"2018","journal-title":"Adv. Funct. Mater."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"2011","DOI":"10.1039\/D2QM00213B","article-title":"Inorganic\u2013organic hybrid materials to detect urinary biomarkers: Recent progress and future prospects","volume":"6","author":"Hu","year":"2022","journal-title":"Mater. Chem. Front."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"2011","DOI":"10.1039\/C8CS00656C","article-title":"Perovskite precursor solution chemistry: From fundamentals to photovoltaic applications","volume":"48","author":"Jung","year":"2019","journal-title":"Chem. Soc. Rev."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1016\/j.ccr.2018.09.004","article-title":"Metal-containing crystalline luminescent thermochromic materials","volume":"377","author":"Li","year":"2018","journal-title":"Coord. Chem. Rev."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"266","DOI":"10.1039\/D3CS01102J","article-title":"Metal complex-based TADF: Design, characterization, and lighting devices","volume":"54","author":"Farokhi","year":"2025","journal-title":"Chem. Soc. Rev."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"e01732","DOI":"10.1002\/adom.202501732","article-title":"Highly Efficient Aggregation Induced Blue-Emitting Copper(I) Halide Complexes via TADF for OLED and X-Ray Scintillator","volume":"14","author":"Chen","year":"2026","journal-title":"Adv. Opt. Mater."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"13736","DOI":"10.1021\/acs.chemrev.3c00755","article-title":"The golden age of thermally activated delayed fluorescence materials: Design and exploitation","volume":"124","author":"Hall","year":"2024","journal-title":"Chem. Rev."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"13522","DOI":"10.1021\/jacs.8b08822","article-title":"Photoactive Complexes with Earth-Abundant Metals","volume":"140","author":"Wenger","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"100478","DOI":"10.1016\/j.jphotochemrev.2021.100478","article-title":"Solid-state luminescence of Au(I) complexes with external stimuli-responsive properties","volume":"51","author":"Jin","year":"2022","journal-title":"J. Photochem. Photobiol. C"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"2046","DOI":"10.1039\/C6DT04386K","article-title":"Luminescent aryl\u2013group eleven metal complexes","volume":"46","author":"Monge","year":"2017","journal-title":"Dalton Trans."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"100484","DOI":"10.1016\/j.jphotochemrev.2022.100484","article-title":"Luminescence of lanthanide complexes: From fundamental to prospective approaches related to water- and molecular-stimuli","volume":"50","author":"Hasegawa","year":"2022","journal-title":"J. Photochem. Photobio. C"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"138600","DOI":"10.1016\/j.cplett.2021.138600","article-title":"The role played by structural and energy parameters of \u03b2-Diketones derivatives as antenna ligands in Eu(III) complexes","volume":"773","author":"Pizarro","year":"2021","journal-title":"Chem. Phys. Lett."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1038\/s41427-018-0012-y","article-title":"Effective photosensitized, electrosensitized, and mechanosensitized luminescence of lanthanide complexes","volume":"10","author":"Hasegawa","year":"2018","journal-title":"NPG Asia Mater."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"e202500041","DOI":"10.1002\/cptc.202500041","article-title":"Recent Advances in Luminescence of Platinum Complexes in the Near Infrared Second Window","volume":"9","author":"Hattori","year":"2025","journal-title":"ChemPhotoChem"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1016\/j.ccr.2018.02.006","article-title":"Cyclometalated Iridium(III) Complexes for Life Science","volume":"363","author":"Caporale","year":"2018","journal-title":"Coord. Chem. Rev."},{"key":"ref_17","doi-asserted-by":"crossref","unstructured":"Dave, K., Huang, W.-T., and Liu, R.-S. (2023). All Inorganic Lead-Free Zero-Dimensional Metal Halide Luminescent Materials and Applications. Crystals, 13.","DOI":"10.3390\/cryst13030499"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"2626","DOI":"10.1039\/D0CS00779J","article-title":"Recent progress of zero-dimensional luminescent metal halides","volume":"50","author":"Li","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"521","DOI":"10.1039\/D4TC04153D","article-title":"\u201cThis or that\u201d\u2014Light emission from hybrid organic\u2013inorganic vs. coordination Cu(I) halides","volume":"13","author":"Popy","year":"2025","journal-title":"J. Mater. Chem. C"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"213331","DOI":"10.1016\/j.ccr.2020.213331","article-title":"Luminescent manganese(II) complexes: Synthesis, properties and optoelectronic applications","volume":"416","author":"Qin","year":"2020","journal-title":"Coord. Chem. Rev."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"514","DOI":"10.1016\/j.ccr.2018.05.010","article-title":"Recent advances in copper complexes for electrical\/light energy conversion","volume":"375","author":"Liu","year":"2018","journal-title":"Coord. Chem. Rev."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"3573","DOI":"10.1039\/D4DT03210A","article-title":"Earth Abundant Transition Metals Complexes in Light-emitting Electrochemical Cells: Successes, Challenges and Perspectives","volume":"54","author":"Giobbio","year":"2025","journal-title":"Dalton Trans."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"117980","DOI":"10.1016\/j.synthmet.2025.117980","article-title":"Zinc(II) based organic metal complexes for OLED applications","volume":"316","author":"Paul","year":"2026","journal-title":"Synth. Met."},{"key":"ref_24","doi-asserted-by":"crossref","unstructured":"Rashamuse, T.J., Mohlala, R.L., Coyanis, E.M., and Magwa, N.P. (2023). A Review: Blue Fluorescent Zinc(II) Complexes for OLEDs\u2014A Last Five-Year Recap. Molecules, 28.","DOI":"10.3390\/molecules28135272"},{"key":"ref_25","doi-asserted-by":"crossref","unstructured":"Barwiolek, M., Jankowska, D., Kaczmarek-K\u0119dziera, A., Wojtulewski, S., Skowro\u0144ski, L., Rerek, T., Popielarski, P., and Muziol, T.M. (2022). Experimental and Theoretical Studies of the Optical Properties of the Schiff Bases and Their Materials Obtained from o-Phenylenediamine. Molecules, 27.","DOI":"10.3390\/molecules27217396"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"140351","DOI":"10.1016\/j.tsf.2024.140351","article-title":"Stability of Zinc (8-hydroxyquinoline) thin films toward photodetection performance: Effect of annealing","volume":"797","author":"Amin","year":"2024","journal-title":"Thin Solid Films"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"2083","DOI":"10.1039\/D4NA01021C","article-title":"Investigating the thin film growth of [Ni(Hvanox)2] by microscopic and spectroscopic techniques","volume":"7","author":"Sapre","year":"2025","journal-title":"Nanoscale Adv."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"8395","DOI":"10.1021\/acs.chemrev.2c00905","article-title":"Recent advances in copper and related complexes","volume":"123","author":"Khasbaatar","year":"2023","journal-title":"Chem. Rev."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1049\/nde2.12026","article-title":"Review on nanodielectrics","volume":"5","author":"Song","year":"2022","journal-title":"IET Nanodielectrics"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"2201888","DOI":"10.1002\/admt.202201888","article-title":"High-Resolution Lithography for High-Frequency Organic Thin-Film Transistors","volume":"8","author":"Zschieschang","year":"2023","journal-title":"Adv. Mater. Technol."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1134\/S1070328422010080","article-title":"Iron(II) Clathrochelates in Molecular Spintronic Devices: A Vertical Spin Valve","volume":"48","author":"Zlobin","year":"2022","journal-title":"Russ. J. Coord. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"S7","DOI":"10.1134\/S1070328423600791","article-title":"Manufacturing Technology of OLED Structures. Control of Basic Parameters","volume":"49","author":"Pozin","year":"2023","journal-title":"Russ. J. Coord. Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"7267","DOI":"10.1039\/C5TC01314C","article-title":"A \u039b-shaped donor\u2013\u03c0\u2013acceptor\u2013\u03c0\u2013donor molecule with AIEE and CIEE activity and sequential logic gate behaviour","volume":"3","author":"Mei","year":"2015","journal-title":"J. Mater. Chem. C"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"14","DOI":"10.1039\/D0TC04146G","article-title":"Layer-by-layer fabrication of organic photovoltaic devices: Material selection and processing conditions","volume":"9","author":"Faure","year":"2020","journal-title":"J. Mater. Chem. C"},{"key":"ref_35","first-page":"393","article-title":"The world of advanced thin films: Design, fabrication, and applications","volume":"4","author":"Rubin","year":"2023","journal-title":"Fusion Multidiscip. Res."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1134\/S0036023624602769","article-title":"Composition and Morphology of Transparent Thin Films Prepared from Water\u2013Ethanol Sols Based on Tin(IV) Compounds","volume":"70","author":"Shilova","year":"2025","journal-title":"Russ. J. Inorg. Chem."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"1263","DOI":"10.1134\/S0036023623700298","article-title":"Lanthanum Propionate Monohydrate and Its Mixed-Ligand Complex with Diethylenetriamine: Synthesis, Crystal Structure, and Use in Chemical Solution Deposition of Lanthanum Nickelate Thin Films","volume":"68","author":"Kendin","year":"2023","journal-title":"Russ. J. Inorg. Chem."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.ccr.2015.05.003","article-title":"Recent advances in acylpyrazolone metal complexes and their potential applications","volume":"303","author":"Marchetti","year":"2015","journal-title":"Coord. Chem. Rev."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"1027","DOI":"10.1002\/ejic.201900775","article-title":"Zinc(II) Complexes of Acylpyrazolones Decorated with a Cyclohexyl Group Display Antiproliferative Activity Against Human Breast Cancer Cells","volume":"2020","author":"Marchetti","year":"2020","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_40","doi-asserted-by":"crossref","unstructured":"Di Nicola, C., Marchetti, F., Pettinari, R., Tombesi, A., Pettinari, C., Grappasonni, I., Dyson, P.J., and Scuri, S. (2020). Tethering (Arene)Ru(II) Acylpyrazolones Decorated with Long Aliphatic Chains to Polystyrene Surfaces Provides Potent Antibacterial Plastics. Materials, 13.","DOI":"10.3390\/ma13030526"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"1800","DOI":"10.1002\/zaac.201200513","article-title":"Synthesis, structure, antibacterial and spectroscopic properties of a zinc(II) complex with 4-heptanoyl-pyrazol-5-one","volume":"639","author":"Xu","year":"2013","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"e202400568","DOI":"10.1002\/ejic.202400568","article-title":"Rare Earth Acylpyrazolonates-Synthesis, Structure, Luminescent Properties and Applications","volume":"28","author":"Belousov","year":"2025","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"1159","DOI":"10.1070\/RC2012v081n12ABEH004255","article-title":"Lanthanide acylpyrazolonates: Synthesis, properties and structural features","volume":"81","author":"Drozdov","year":"2012","journal-title":"Russ. Chem. Rev."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"117263","DOI":"10.1016\/j.inoche.2026.117263","article-title":"Tailoring the antioxidant activity of Zn(II)(acylpyrazolone)-doped chitosan films through structural modification of the zinc coordination environment","volume":"192","author":"Policastro","year":"2026","journal-title":"Inorg. Chem. Commun."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","article-title":"Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen\u2013sulfur donor ligands; the crystal and molecular structure of aqua [1,7-bis(N-methylbenzimidazol-2\u2032-yl)-2,6-dithiaheptane]copper(II) perchlorate","volume":"13","author":"Addison","year":"1984","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/j.ica.2013.03.044","article-title":"Anionic lanthanide complexes with 3-methyl-1-phenyl-4-formylpyrazole-5-one and hydroxonium as counter ion","volume":"402","author":"Konnik","year":"2013","journal-title":"Inorg. Chim. Acta"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"2909","DOI":"10.1016\/j.ccr.2005.03.013","article-title":"Acylpyrazolone ligands: Synthesis, structures, metal coordination chemistry and applications","volume":"249","author":"Marchetti","year":"2005","journal-title":"Coord. Chem. Rev."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"16","DOI":"10.1016\/j.colsurfa.2007.12.059","article-title":"Dewetting of core\/ring microstructure in Langmuir\u2013Blodgett films","volume":"321","author":"Zhang","year":"2008","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"4228","DOI":"10.1080\/00958972.2018.1536783","article-title":"Tb(III) complexes with 1-phenyl-3-methyl-4-stearoyl-pyrazol-5-one as materials for luminescence Langmuir\u2013Blodgett films","volume":"71","author":"Pevzner","year":"2018","journal-title":"J. Coord. Chem."},{"key":"ref_50","doi-asserted-by":"crossref","unstructured":"Gu, W., Li, Q., Wang, R., Zhang, L., Liu, Z., and Jiao, T. (2024). Recent progress in the applications of Langmuir\u2013Blodgett film technology. Nanomaterials, 14.","DOI":"10.3390\/nano14121039"},{"key":"ref_51","doi-asserted-by":"crossref","unstructured":"Gusev, A., Braga, E., Tyutyunik, A., Gurchenko, V., Berezovskaya, M., Kryukova, M., Kiskin, M., and Linert, W. (2020). Synthesis, photoluminescence and electrical study of pyrazolone-based azomethine Zn(II) complexes. Materials, 13.","DOI":"10.3390\/ma13245698"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","article-title":"Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","article-title":"SHELXT\u2013Integrated space-group and crystal-structure determination","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr. Sect. A"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","article-title":"OLEX2: A complete structure solution, refinement and analysis program","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Crystallogr."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"2999","DOI":"10.1021\/cr9904009","article-title":"Quantum mechanical continuum solvation models","volume":"105","author":"Tomasi","year":"2005","journal-title":"Chem. Rev."},{"key":"ref_56","unstructured":"Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Scalmani, G., Barone, V., Mennucci, B., and Petersson, G.A. (2009). Gaussian 09, Gaussian, Inc."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"5648","DOI":"10.1063\/1.464913","article-title":"Density functional thermochemistry. III. The role of exact exchange","volume":"98","author":"Becke","year":"1993","journal-title":"J. Chem. Phys."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"8822","DOI":"10.1103\/PhysRevB.33.8822","article-title":"Density-Functional approximation for the correlation energy of the inhomogeneous electron gas","volume":"33","author":"Perdew","year":"1986","journal-title":"Phys. Rev. B"},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"2193","DOI":"10.1063\/1.455064","article-title":"A complete basis set model chemistry. I. The total energies of closed-shell atoms and hydrides of the first-row elements","volume":"89","author":"Petersson","year":"1988","journal-title":"J. Chem. Phys."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"724","DOI":"10.1063\/1.1674902","article-title":"Self-Consistent molecular orbital methods. IX. An extended Gaussian-type basis for molecular orbital studies of organic molecules","volume":"54","author":"Ditchfield","year":"1971","journal-title":"J. Chem. Phys."},{"key":"ref_61","first-page":"148","article-title":"Platon\/squeeze","volume":"65","author":"Spek","year":"2009","journal-title":"Acta Crystallogr."}],"container-title":["International Journal of Molecular Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1422-0067\/27\/17\/7560\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T13:21:31Z","timestamp":1787577691000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1422-0067\/27\/17\/7560"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,24]]},"references-count":61,"journal-issue":{"issue":"17","published-online":{"date-parts":[[2026,9]]}},"alternative-id":["ijms27177560"],"URL":"https:\/\/doi.org\/10.3390\/ijms27177560","relation":{},"ISSN":["1422-0067"],"issn-type":[{"value":"1422-0067","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,24]]}}}