{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T02:19:31Z","timestamp":1760149171740,"version":"build-2065373602"},"reference-count":85,"publisher":"MDPI AG","issue":"7","license":[{"start":{"date-parts":[[2023,7,19]],"date-time":"2023-07-19T00:00:00Z","timestamp":1689724800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Ministry of Research, Innovation and Digitization","award":["FAIR_09\/24.11.2020","PN-III-P4-ID-PCE2020-0332","PD 145\/2020"],"award-info":[{"award-number":["FAIR_09\/24.11.2020","PN-III-P4-ID-PCE2020-0332","PD 145\/2020"]}]},{"name":"Executive Agency for Higher Education, Research, Development and Innovation, UEFISCDI, and ROBIM","award":["FAIR_09\/24.11.2020","PN-III-P4-ID-PCE2020-0332","PD 145\/2020"],"award-info":[{"award-number":["FAIR_09\/24.11.2020","PN-III-P4-ID-PCE2020-0332","PD 145\/2020"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["JFB"],"abstract":"<jats:p>Iron-based SMAs can be used in the medical field for both their shape memory effect (SME) and biodegradability after a specific period, solving complicated chirurgical problems that are partially now addressed with shape-memory polymers or biodegradable polymers. Iron-based materials with (28\u201332 wt %) Mn and (4\u20136 wt %) Si with the addition of 1 and 2 wt % Ag were obtained using levitation induction melting equipment. Addition of silver to the FeMnSi alloy was proposed in order to enhance its antiseptic property. Structural and chemical composition analyses of the newly obtained alloys were performed by X-ray diffraction (confirming the presence of \u03b5 phase), scanning electron microscopy (SEM) and energy-dispersive spectroscopy. The corrosion resistance was evaluated through immersion tests and electrolyte pH solution variation. Dynamic mechanical solicitations were performed with amplitude sweep performed on the FeMnSi\u20131Ag and FeMnSi\u20132Ag samples, including five deformation cycles at 40 \u00b0C, with a frequency of 1 Hz, 5 Hz and 20 Hz. These experiments were meant to simulate the usual behavior of some metallic implants subjected to repetitive mechanical loading. Atomic force microscopy was used to analyze the surface roughness before and after the dynamic mechanical analysis test followed by the characterization of the surface profile change by varying dynamic mechanical stress. Differential scanning calorimetry was performed in order to analyze the thermal behavior of the material in the range of \u221250\u2013+200 \u00b0C. X-ray diffraction and Fourier transform infrared spectroscopy (FTIR) along with Neaspec nano-FTIR experiments were performed to identify and confirm the corrosion compounds (oxides, hydroxides or carbonates) formed on the surface.<\/jats:p>","DOI":"10.3390\/jfb14070377","type":"journal-article","created":{"date-parts":[[2023,7,19]],"date-time":"2023-07-19T21:21:46Z","timestamp":1689801706000},"page":"377","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Influence of Dynamic Strain Sweep on the Degradation Behavior of FeMnSi\u2013Ag Shape Memory Alloys"],"prefix":"10.3390","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8798-1849","authenticated-orcid":false,"given":"Ana-Maria","family":"Roman","sequence":"first","affiliation":[{"name":"Faculty of Materials Science and Engineering, \u201cGheorghe Asachi\u201d Technical University of Ia\u0219i, Blvd. Dimitrie Mangeron 71A, 700050 Ia\u0219i, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5128-4491","authenticated-orcid":false,"given":"Ramona","family":"Cimpoe\u0219u","sequence":"additional","affiliation":[{"name":"Faculty of Materials Science and Engineering, \u201cGheorghe Asachi\u201d Technical University of Ia\u0219i, Blvd. Dimitrie Mangeron 71A, 700050 Ia\u0219i, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5528-9177","authenticated-orcid":false,"given":"Bogdan","family":"Pricop","sequence":"additional","affiliation":[{"name":"Faculty of Materials Science and Engineering, \u201cGheorghe Asachi\u201d Technical University of Ia\u0219i, Blvd. Dimitrie Mangeron 71A, 700050 Ia\u0219i, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3078-6553","authenticated-orcid":false,"given":"Nicoleta-Monica","family":"Lohan","sequence":"additional","affiliation":[{"name":"Faculty of Materials Science and Engineering, \u201cGheorghe Asachi\u201d Technical University of Ia\u0219i, Blvd. Dimitrie Mangeron 71A, 700050 Ia\u0219i, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7297-6411","authenticated-orcid":false,"given":"Marius Mihai","family":"Cazacu","sequence":"additional","affiliation":[{"name":"Physics Department, \u201cGheorghe Asachi\u201d Technical University of Ia\u0219i, Blvd. Dimitrie Mangeron 71A, 700050 Ia\u0219i, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8092-913X","authenticated-orcid":false,"given":"Leandru-Gheorghe","family":"Bujoreanu","sequence":"additional","affiliation":[{"name":"Faculty of Materials Science and Engineering, \u201cGheorghe Asachi\u201d Technical University of Ia\u0219i, Blvd. Dimitrie Mangeron 71A, 700050 Ia\u0219i, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5407-3895","authenticated-orcid":false,"given":"C\u0103t\u0103lin","family":"Panaghie","sequence":"additional","affiliation":[{"name":"Faculty of Materials Science and Engineering, \u201cGheorghe Asachi\u201d Technical University of Ia\u0219i, Blvd. Dimitrie Mangeron 71A, 700050 Ia\u0219i, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Georgeta","family":"Zegan","sequence":"additional","affiliation":[{"name":"Faculty of Dental Medicine, \u201cGrigore T. Popa\u201d University of Medicine and Pharmacy University, 16 University Street, 700115 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nicanor","family":"Cimpoe\u0219u","sequence":"additional","affiliation":[{"name":"Faculty of Materials Science and Engineering, \u201cGheorghe Asachi\u201d Technical University of Ia\u0219i, Blvd. Dimitrie Mangeron 71A, 700050 Ia\u0219i, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alice Mirela","family":"Murariu","sequence":"additional","affiliation":[{"name":"Department of Surgicals, Faculty of Dental Medicine, \u201cGrigore T. Popa\u201d University of Medicine and Pharmacy, 16 University Street, 700115 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2023,7,19]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"61","DOI":"10.1038\/s41578-019-0150-z","article-title":"Design of biodegradable, implantable devices towards clinical translation","volume":"51","author":"Li","year":"2019","journal-title":"Nat. Rev. Mater."},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Istrate, B., Munteanu, C., Antoniac, I.-V., and Lupescu, \u0218.-C. (2022). Current Research Studies of Mg\u2013Ca\u2013Zn Biodegradable Alloys Used as Orthopedic Implants\u2014Review. 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