{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T17:27:06Z","timestamp":1777483626674,"version":"3.51.4"},"reference-count":30,"publisher":"MDPI AG","issue":"2","license":[{"start":{"date-parts":[[2017,2,20]],"date-time":"2017-02-20T00:00:00Z","timestamp":1487548800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>A UV-curable, flame-retardant monomer, DAPP (bis[di-acryloyloxyethyl]-p-tert-butyl-phenyl-phosphate), was synthesized based on BPDCP (4-tert-butylphenyl-dichloro phosphate) and HEA (2-hydroxy ethyl acrylate). DAPP was blended with regular bisphenol A epoxy acrylate (BAEA) in various ratios to yield various phosphorus contents. The TGA-IR (thermogravimetric analyzer interface with an infrared spectrometer) results demonstrate that compounding 30 mol % DAPP with BAEA significantly reduced the amount of released CO gas. In contrast, the peak intensity of CO2 is independent of phosphorus content. The limiting oxygen index (LOI), reaching the saturated value of 26, and the heat release rate (HRR) measured using a cone-calorimeter, 156.43 KW\/m2, confirm the saturation point when 30 mol % DAPP was compounded into BAEA. A study of the kinetics of pyrolysis reveals that Ea decreases as the phosphorus content increases. Both the TGA-IR and pyrolysis results reveal that the phosphorus compound DAPP is easily decomposed during the initial stage of burning to form an insulating layer, which inhibits further burning of the resin and the consequent release of other flammable gases.<\/jats:p>","DOI":"10.3390\/ma10020202","type":"journal-article","created":{"date-parts":[[2017,2,20]],"date-time":"2017-02-20T11:07:24Z","timestamp":1487588844000},"page":"202","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["A Study of the Curing and Flammability Properties of Bisphenol A Epoxy Diacrylate Resin Utilizing a Novel Flame Retardant Monomer, bis[di-acryloyloxyethyl]-p-tert-butyl-phenyl Phosphate"],"prefix":"10.3390","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6169-5852","authenticated-orcid":false,"given":"Syang-Peng","family":"Rwei","sequence":"first","affiliation":[{"name":"Institute of Organic and Polymeric Materials, National Taipei University of Technology, #1, Sec 3, Chung-Hsiao E. Rd, Taipei 10608, Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yu-Ming","family":"Chen","sequence":"additional","affiliation":[{"name":"Institute of Organic and Polymeric Materials, National Taipei University of Technology, #1, Sec 3, Chung-Hsiao E. Rd, Taipei 10608, Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Whe-Yi","family":"Chiang","sequence":"additional","affiliation":[{"name":"Institute of Organic and Polymeric Materials, National Taipei University of Technology, #1, Sec 3, Chung-Hsiao E. Rd, Taipei 10608, Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yi-Tien","family":"Ting","sequence":"additional","affiliation":[{"name":"Institute of Organic and Polymeric Materials, National Taipei University of Technology, #1, Sec 3, Chung-Hsiao E. Rd, Taipei 10608, Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2017,2,20]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1471","DOI":"10.1002\/pen.10318","article-title":"Characterizations for blends of phosphorus-containing copolyester with poly(ethylene terephthalate)","volume":"38","author":"Chang","year":"1998","journal-title":"Polym. Eng. Sci."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1193","DOI":"10.1016\/j.polymdegradstab.2007.04.008","article-title":"Thermal degradation behavior of hyperbranched polyphosphate acrylate\/tri (acryloyloxyethyl) phosphate as an intumescent flame retardant system","volume":"92","author":"Huang","year":"2007","journal-title":"Polym. Degrad. 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