{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,10]],"date-time":"2026-04-10T21:57:14Z","timestamp":1775858234398,"version":"3.50.1"},"reference-count":50,"publisher":"MDPI AG","issue":"1","license":[{"start":{"date-parts":[[2017,12,26]],"date-time":"2017-12-26T00:00:00Z","timestamp":1514246400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003329","name":"Ministerio de Econom\u00eda y Competitividad","doi-asserted-by":"publisher","award":["MAT2014-59242-C2-1-R"],"award-info":[{"award-number":["MAT2014-59242-C2-1-R"]}],"id":[{"id":"10.13039\/501100003329","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Ministerio de Econom\u00eda, Cultura y Deportes","award":["FPU13\/06011"],"award-info":[{"award-number":["FPU13\/06011"]}]},{"name":"Ministerio de Econom\u00eda, Cultura y Deportes","award":["FPU15\/03812"],"award-info":[{"award-number":["FPU15\/03812"]}]},{"DOI":"10.13039\/501100003359","name":"Generalitat Valenciana","doi-asserted-by":"publisher","award":["ACIF\/2016\/182"],"award-info":[{"award-number":["ACIF\/2016\/182"]}],"id":[{"id":"10.13039\/501100003359","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Highly environmentally-friendly fibreboards were manufactured by hot-press moulding using Posidonia ocaeanica wastes and a partially biobased epoxy resin as binder. Fibreboards with a constant fibre content of 70 wt % were successfully manufactured by thermo-compression. The effects of a conventional alkali treatment were compared to the synergistic effects that additional silanization with two silanes (amino and glycidyl) can exert on the mechanical and thermo-mechanical properties of fibreboards. The results revealed a remarkable improvement of the mechanical properties with the combination of the alkali treatment followed by the silanization. Scanning electron microscopy also revealed increased resin-fibre interactions due to the synergistic effect of both amino- and glycidyl-silanes. These fibreboards represent a formaldehyde-free solution and can positively contribute to sustainable development as the lignocellulosic component is a waste and the binder resin is partially biobased.<\/jats:p>","DOI":"10.3390\/ma11010035","type":"journal-article","created":{"date-parts":[[2017,12,26]],"date-time":"2017-12-26T11:13:23Z","timestamp":1514286803000},"page":"35","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":36,"title":["Manufacturing and Characterization of Composite Fibreboards with Posidonia oceanica Wastes with an Environmentally-Friendly Binder from Epoxy Resin"],"prefix":"10.3390","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2520-0186","authenticated-orcid":false,"given":"Daniel","family":"Garcia-Garcia","sequence":"first","affiliation":[{"name":"Instituto de Tecnolog\u00eda de Materiales-ITM, Universitat Polit\u00e8cnica de Val\u00e8ncia-UPV, Plaza Ferr\u00e1ndiz y Carbonell 1, 03801 Alcoy, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8037-2215","authenticated-orcid":false,"given":"Luis","family":"Quiles-Carrillo","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda de Materiales-ITM, Universitat Polit\u00e8cnica de Val\u00e8ncia-UPV, Plaza Ferr\u00e1ndiz y Carbonell 1, 03801 Alcoy, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nestor","family":"Montanes","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda de Materiales-ITM, Universitat Polit\u00e8cnica de Val\u00e8ncia-UPV, Plaza Ferr\u00e1ndiz y Carbonell 1, 03801 Alcoy, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vicent","family":"Fombuena","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda de Materiales-ITM, Universitat Polit\u00e8cnica de Val\u00e8ncia-UPV, Plaza Ferr\u00e1ndiz y Carbonell 1, 03801 Alcoy, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5670-7126","authenticated-orcid":false,"given":"Rafael","family":"Balart","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda de Materiales-ITM, Universitat Polit\u00e8cnica de Val\u00e8ncia-UPV, Plaza Ferr\u00e1ndiz y Carbonell 1, 03801 Alcoy, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2017,12,26]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"675","DOI":"10.1007\/s00226-012-0525-4","article-title":"Corn flour-mimosa tannin-based adhesives without formaldehyde for interior particleboard production","volume":"47","author":"Moubarik","year":"2013","journal-title":"Wood Sci. Technol."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"436","DOI":"10.1016\/j.conbuildmat.2016.10.040","article-title":"Some properties of composite corn cob and sawdust particle boards","volume":"127","author":"Akinyemi","year":"2016","journal-title":"Constr. Build. Mater."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"76","DOI":"10.1016\/j.wasman.2015.09.011","article-title":"Substitution potentials of recycled hdpe and wood particles from post-consumer packaging waste in wood-plastic composites","volume":"46","author":"Sommerhuber","year":"2015","journal-title":"Waste Manag."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"153","DOI":"10.1016\/j.polymertesting.2017.03.028","article-title":"Mechanical and acoustical properties of particleboards made with date palm branches and vermiculite","volume":"60","author":"Ghofrani","year":"2017","journal-title":"Polym. Test."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/j.carbpol.2014.12.001","article-title":"Suitability of sorghum stalk fibers for production of particleboard","volume":"120","author":"Khazaeian","year":"2015","journal-title":"Carbohydr. Polym."},{"key":"ref_6","doi-asserted-by":"crossref","unstructured":"Sabbatini, A., Lanari, S., Santulli, C., and Pettinari, C. (2017). Use of almond shells and rice husk as fillers of poly(methyl methacrylate) (PMMA) composites. Materials, 10.","DOI":"10.3390\/ma10080872"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1016\/j.wasman.2016.04.037","article-title":"Utilization of agricultural and forest industry waste and residues in natural fiber-polymer composites: A review","volume":"54","author":"Vaisanen","year":"2016","journal-title":"Waste Manag."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"1291","DOI":"10.1016\/j.wasman.2008.09.012","article-title":"Characteristics of wood-fiber plastic composites made of recycled materials","volume":"29","author":"Ashori","year":"2009","journal-title":"Waste Manag."},{"key":"ref_9","first-page":"369","article-title":"Properties of particleboards made from acacia seyal var. Using uf-tannin modified adhesives","volume":"49","author":"Elbadawi","year":"2015","journal-title":"Cellul. Chem. Technol."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"2444","DOI":"10.15376\/biores.10.2.2444-2460","article-title":"Investigation of a new natural particleboard adhesive composed of tannin and sucrose. 2. Effect of pressing temperature and time on board properties, and characterization of adhesive","volume":"10","author":"Zhao","year":"2015","journal-title":"Bioresources"},{"key":"ref_11","doi-asserted-by":"crossref","unstructured":"Koumba-Yoya, G., and Stevanovic, T. (2017). Study of organosolv lignins as adhesives in wood panel production. Polymers, 9.","DOI":"10.3390\/polym9020046"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"239","DOI":"10.1016\/j.ijadhadh.2016.07.002","article-title":"Lignin-derived non-toxic aldehydes for ecofriendly tannin adhesives for wood panels","volume":"70","author":"Foyer","year":"2016","journal-title":"Int. J. Adhes. Adhes."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"166","DOI":"10.7569\/JRM.2013.634133","article-title":"Formaldehyde-free wood composites from soybean protein adhesive","volume":"2","author":"Ferguson","year":"2014","journal-title":"J. Renew. Mater."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"2053","DOI":"10.1080\/01694243.2012.696950","article-title":"Preparation and evaluation of particleboard bonded with a soy flour-based adhesive with a new curing agent","volume":"27","author":"Gu","year":"2013","journal-title":"J. Adhes. Sci. Technol."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"1447","DOI":"10.1016\/j.compositesa.2010.06.006","article-title":"A new method of making particleboard with a formaldehyde-free soy-based adhesive","volume":"41","author":"Prasittisopin","year":"2010","journal-title":"Compos. Part A Appl. Sci. Manuf."},{"key":"ref_16","doi-asserted-by":"crossref","unstructured":"Baroncini, E.A., Yadav, S.K., Palmese, G.R., and Stanzione, J.F. (2016). Recent advances in bio-based epoxy resins and bio-based epoxy curing agents. J. Appl. Polym. Sci., 133.","DOI":"10.1002\/app.44103"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"447","DOI":"10.1177\/0731684415618459","article-title":"Recent advances in epoxy resin, natural fiber-reinforced epoxy composites and their applications","volume":"35","author":"Saba","year":"2016","journal-title":"J. Reinf. Plast. Compos."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.indcrop.2014.10.025","article-title":"Epoxidation of camelina sativa oil and peel adhesion properties","volume":"64","author":"Kim","year":"2015","journal-title":"Ind. Crops Prod."},{"key":"ref_19","doi-asserted-by":"crossref","unstructured":"Obradovic, J., Voutilainen, M., Virtanen, P., Lassila, L., and Fardim, P. (2017). Cellulose fibre-reinforced biofoam for structural applications. Materials, 10.","DOI":"10.3390\/ma10060619"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"38","DOI":"10.1016\/j.compositesa.2015.11.027","article-title":"Binderless all-cellulose fibreboard from microfibrillated lignocellulosic natural fibres","volume":"83","author":"Arevalo","year":"2016","journal-title":"Compos. Part A Appl. Sci. Manuf."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"6853","DOI":"10.3390\/ma7096853","article-title":"Evaluation of binding effects in wood flour board containing ligno-cellulose nanofibers","volume":"7","author":"Kojima","year":"2014","journal-title":"Materials"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"983","DOI":"10.1007\/s13762-013-0483-x","article-title":"Adsorptive removal of cadmium from aqueous media using posidonia oceanica biomass: Equilibrium, dynamic and thermodynamic studies","volume":"12","author":"Krika","year":"2015","journal-title":"Int. J. Environ. Sci. Tecnol."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"3711","DOI":"10.1080\/19443994.2014.995136","article-title":"Removal of methyl orange from aqueous solution via adsorption on cork as a natural and low-coast adsorbent: Equilibrium, kinetic and thermodynamic study of removal process","volume":"53","author":"Krika","year":"2015","journal-title":"Desalination Water Treat."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"205","DOI":"10.1016\/j.jaap.2014.06.010","article-title":"Preparation and characterization of chemically activated carbons derived from mediterranean Posidonia oceanica (L.) fibres","volume":"109","author":"Ncibi","year":"2014","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"106","DOI":"10.1016\/j.indcrop.2012.12.007","article-title":"Macroscopic and microscopic studies of methylene blue sorption onto extracted celluloses from posidonia oceanica","volume":"45","author":"Bergaoui","year":"2013","journal-title":"Ind. Crops Prod."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"12730","DOI":"10.1080\/19443994.2015.1052564","article-title":"Adsorption thermodynamics in the framework of the statistical physics formalism: Basic blue 41 adsorption onto posidonia biomass","volume":"57","author":"Nakhli","year":"2016","journal-title":"Desalination Water Treat."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"1937","DOI":"10.1016\/j.jtice.2014.02.006","article-title":"On the adsorption mechanisms of diethylamine by medically-certified activated carbons: Investigation of critical parameters controlling sorption properties","volume":"45","author":"Venault","year":"2014","journal-title":"J. Taiwan Inst. Chem. Eng."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"99","DOI":"10.1016\/j.carbpol.2015.01.026","article-title":"Mechanical and thermal properties of posidonia oceanica cellulose nanocrystal reinforced polymer","volume":"123","author":"Bettaieb","year":"2015","journal-title":"Carbohydr. Polym."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"97","DOI":"10.1016\/j.indcrop.2014.12.060","article-title":"Nanofibrillar cellulose from posidonia oceanica: Properties and morphological features","volume":"72","author":"Bettaieb","year":"2015","journal-title":"Ind. Crops Prod."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"664","DOI":"10.1016\/j.carbpol.2015.07.091","article-title":"Effect of the oxidation treatment on the production of cellulose nanofiber suspensions from posidonia oceanica: The rheological aspect","volume":"134","author":"Bettaieb","year":"2015","journal-title":"Carbohydr. Polym."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1867","DOI":"10.1016\/j.compscitech.2011.08.022","article-title":"New lignocellulosic fibres-reinforced composite materials: A stepforward in the valorisation of the posidonia oceanica balls","volume":"71","author":"Khiari","year":"2011","journal-title":"Compos. Sci. Technol."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"439","DOI":"10.1016\/j.indcrop.2015.01.075","article-title":"Processing of pla nanocomposites with cellulose nanocrystals extracted from posidonia oceanica waste: Innovative reuse of coastal plant","volume":"67","author":"Fortunati","year":"2015","journal-title":"Ind. Crops Prod."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"190","DOI":"10.7569\/JRM.2015.634134","article-title":"Modulation of acid hydrolysis reaction time for the extraction of cellulose nanocrystals from posidonia oceanica leaves","volume":"4","author":"Luzi","year":"2016","journal-title":"J. Renew. Mater."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"2043","DOI":"10.3390\/ma6052043","article-title":"Posidonia oceanica as a renewable lignocellulosic biomass for the synthesis of cellulose acetate and glycidyl methacrylate grafted cellulose","volume":"6","author":"Coletti","year":"2013","journal-title":"Materials"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"78","DOI":"10.1016\/j.wasman.2010.08.016","article-title":"Comparative management of offshore posidonia residues: Composting vs. Energy recovery","volume":"31","author":"Cocozza","year":"2011","journal-title":"Waste Manag."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"66","DOI":"10.7569\/JRM.2013.634134","article-title":"Revalorisation of posidonia oceanica as reinforcement in polyethylene\/maleic anhydride grafted polyethylene composites","volume":"2","author":"Puglia","year":"2014","journal-title":"J. Renew. Mater."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"1378","DOI":"10.1002\/pc.23042","article-title":"Development of natural fiber-reinforced plastics (NFRP) based on biobased polyethylene and waste fibers from posidonia oceanica seaweed","volume":"36","author":"Ferrero","year":"2015","journal-title":"Polym. Compos."},{"key":"ref_38","doi-asserted-by":"crossref","unstructured":"Seggiani, M., Cinelli, P., Mallegni, N., Balestri, E., Puccini, M., VItolo, S., Lardicci, C., and Lazzeri, A. (2017). New bio-composites based on polyhydroxyalkanoates and posidonia oceanica fibres for applications in a marine environment. Materials, 10.","DOI":"10.3390\/ma10040326"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.compositesb.2016.08.018","article-title":"Mechanical properties of boards made in biocomposites reinforced with wood and posidonia oceanica fibers","volume":"104","author":"Macia","year":"2016","journal-title":"Compos. Part B Eng."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"1663","DOI":"10.1002\/pc.22567","article-title":"Green composites based on wheat gluten matrix and posidonia oceanica waste fibers as reinforcements","volume":"34","author":"Ferrero","year":"2013","journal-title":"Polym. Compos."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"282","DOI":"10.1080\/15440478.2013.800812","article-title":"Effect of alkali treatment on the properties of century fibers","volume":"10","author":"Zhang","year":"2013","journal-title":"J. Nat. Fibers"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1080\/10236660802601415","article-title":"Characterization of natural fabric sterculia urens","volume":"14","author":"Jayaramudu","year":"2009","journal-title":"Int. J. Polym. Anal. Charact."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"1575","DOI":"10.1007\/s12034-011-0361-4","article-title":"Effect of fibre content and alkali treatment on mechanical properties of roystonea regia-reinforced epoxy partially biodegradable composites","volume":"34","author":"Goud","year":"2011","journal-title":"Bull. Mater. Sci."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"1115","DOI":"10.1016\/S0266-3538(00)00012-9","article-title":"Surface modification of jute and its influence on performance of biodegradable jute-fabric\/biopol composites","volume":"60","author":"Mohanty","year":"2000","journal-title":"Compos. Sci. Technol."},{"key":"ref_45","first-page":"1103","article-title":"The effect of alkali treatment on the mechanical properties of short pineapple leaf fibre (PALF) reinforced high impact polystyrene (HIPS) composites","volume":"8","author":"Siregar","year":"2010","journal-title":"J. Food Agric. Environ."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"5171","DOI":"10.3390\/ma6115171","article-title":"Recent development of flax fibres and their reinforced composites based on different polymeric matrices","volume":"6","author":"Zhu","year":"2013","journal-title":"Materials"},{"key":"ref_47","doi-asserted-by":"crossref","unstructured":"Nishitani, Y., Kajiyama, T., and Yamanaka, T. (2017). Effect of silane coupling agent on tribological properties of hemp fiber-reinforced plant-derived polyamide 1010 biomass composites. Materials, 10.","DOI":"10.1063\/1.5016730"},{"key":"ref_48","first-page":"116","article-title":"The effect of alkali treatment on mechanical, morphological and thermal properties of date palm fibers (DPFs): Study of the interface of DPF-polyurethane composite","volume":"23","author":"Oushabi","year":"2017","journal-title":"S. Afr. J. Chem. Eng."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"611","DOI":"10.1021\/acsomega.6b00458","article-title":"Exploring the effect of poly(propylene carbonate) polyol in a biobased epoxy interpenetrating network","volume":"2","author":"Roudsari","year":"2017","journal-title":"ACS Omega"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"683","DOI":"10.1002\/pc.22192","article-title":"Use of eco-friendly epoxy resins from renewable resources as potential substitutes of petrochemical epoxy resins for ambient cured composites with flax reinforcements","volume":"33","author":"Bertomeu","year":"2012","journal-title":"Polym. Compos."}],"container-title":["Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1944\/11\/1\/35\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T18:55:38Z","timestamp":1760208938000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1944\/11\/1\/35"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,12,26]]},"references-count":50,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2018,1]]}},"alternative-id":["ma11010035"],"URL":"https:\/\/doi.org\/10.3390\/ma11010035","relation":{},"ISSN":["1996-1944"],"issn-type":[{"value":"1996-1944","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,12,26]]}}}