{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,13]],"date-time":"2026-05-13T21:12:22Z","timestamp":1778706742451,"version":"3.51.4"},"reference-count":31,"publisher":"MDPI AG","issue":"10","license":[{"start":{"date-parts":[[2019,5,20]],"date-time":"2019-05-20T00:00:00Z","timestamp":1558310400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001824","name":"Grantov\u00e1 Agentura \u010cesk\u00e9 Republiky","doi-asserted-by":"publisher","award":["16-13778S"],"award-info":[{"award-number":["16-13778S"]}],"id":[{"id":"10.13039\/501100001824","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001824","name":"Grantov\u00e1 Agentura \u010cesk\u00e9 Republiky","doi-asserted-by":"publisher","award":["19-11027S"],"award-info":[{"award-number":["19-11027S"]}],"id":[{"id":"10.13039\/501100001824","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Adsorption properties of waste brick dust (WBD) were studied by the removing of PbII and CsI from an aqueous system. For adsorption experiments, 0.1 M and 0.5 M aqueous solutions of Cs+ and Pb2+ and two WBD (Libochovice\u2014LB, and Tyn nad Vltavou\u2014TN) in the fraction below 125 \u00b5m were used. The structural and surface properties of WBD were characterized by X-ray diffraction (XRD) in combination with solid-state nuclear magnetic resonance (NMR), supplemented by scanning electron microscopy (SEM), specific surface area (SBET), total pore volume and zero point of charge (pHZPC). LB was a more amorphous material showing a better adsorption condition than that of TN. The adsorption process indicated better results for Pb2+, due to the inner-sphere surface complexation in all Pb2+ systems, supported by the formation of insoluble Pb(OH)2 precipitation on the sorbent surface. A weak adsorption of Cs+ on WBD corresponded to the non-Langmuir adsorption run followed by the outer-sphere surface complexation. The leachability of Pb2+ from saturated WBDs varied from 0.001% to 0.3%, while in the case of Cs+, 4% to 12% of the initial amount was leached. Both LB and TN met the standards for PbII adsorption, yet completely failed for any CsI removal from water systems.<\/jats:p>","DOI":"10.3390\/ma12101647","type":"journal-article","created":{"date-parts":[[2019,5,20]],"date-time":"2019-05-20T11:05:07Z","timestamp":1558350307000},"page":"1647","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Waste Brick Dust as Potential Sorbent of Lead and Cesium from Contaminated Water"],"prefix":"10.3390","volume":"12","author":[{"given":"Barbora","family":"Dou\u0161ov\u00e1","sequence":"first","affiliation":[{"name":"University of Chemistry and Technology Prague, Faculty of Chemical Technology, Technick\u00e1 5, 166 28 Praha 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"David","family":"Kolou\u0161ek","sequence":"additional","affiliation":[{"name":"University of Chemistry and Technology Prague, Faculty of Chemical Technology, Technick\u00e1 5, 166 28 Praha 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Miloslav","family":"Lhotka","sequence":"additional","affiliation":[{"name":"University of Chemistry and Technology Prague, Faculty of Chemical Technology, Technick\u00e1 5, 166 28 Praha 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6878-1291","authenticated-orcid":false,"given":"Martin","family":"Keppert","sequence":"additional","affiliation":[{"name":"Faculty of Civil Engineering, Czech Technical University in Prague, Th\u00e1kurova 7, 166 29 Praha 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Martina","family":"Urbanov\u00e1","sequence":"additional","affiliation":[{"name":"Institute of Macromolecular Chemistry AS CR, Heyrovsk\u00e9ho n\u00e1m. 2, 162 06 Praha 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8826-948X","authenticated-orcid":false,"given":"Libor","family":"Kobera","sequence":"additional","affiliation":[{"name":"Institute of Macromolecular Chemistry AS CR, Heyrovsk\u00e9ho n\u00e1m. 2, 162 06 Praha 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ji\u0159\u00ed","family":"Brus","sequence":"additional","affiliation":[{"name":"Institute of Macromolecular Chemistry AS CR, Heyrovsk\u00e9ho n\u00e1m. 2, 162 06 Praha 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2019,5,20]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1016\/S0048-9697(03)00403-0","article-title":"Pb contamination and isotopic composition of urban soils in Hong Kong","volume":"319","author":"Wong","year":"2004","journal-title":"Sci. Total Environ."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"332","DOI":"10.1016\/j.jhazmat.2009.04.092","article-title":"Removal of Pb(II) from aqueous solution using modified and unmodified kaolinite clay","volume":"170","author":"Jiang","year":"2009","journal-title":"J. Hazard. Mater."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"4909","DOI":"10.1021\/es5003346","article-title":"Interlayer Collapse Affects on Cesium Adsorption onto Illite","volume":"48","author":"Benedicto","year":"2014","journal-title":"Environ. Sci. Technol."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"483","DOI":"10.1007\/BF02219872","article-title":"Adsorption of cesium on minerals: A review","volume":"171","author":"Cornell","year":"1993","journal-title":"J. Radioanal. Nuclear Chem."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"376","DOI":"10.1016\/j.jhazmat.2007.04.134","article-title":"Biosorption of heavy metals and radionuclide from aqueous solutions by pre-treated arcashell biomass","volume":"150","author":"Dahiya","year":"2008","journal-title":"J. Hazard. Mater."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"862","DOI":"10.1021\/es00173a002","article-title":"Metals in aquatic environment","volume":"22","author":"Honeyman","year":"1988","journal-title":"Environ. Sci. Technol."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1016\/S1383-5866(97)00045-2","article-title":"Simultaneous removal of the radiotoxic nuclides 137Cs & 129I from aqueous solution","volume":"12","author":"Song","year":"1997","journal-title":"Sep. Purif. Technol."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1016\/j.jhazmat.2004.08.022","article-title":"Biosorption of cesium by native and chemically modified biomass of marine algae: Introduce the new biosorbent for biotechnology applications","volume":"B116","author":"Jalali","year":"2004","journal-title":"J. Hazard. Mater."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"480","DOI":"10.1016\/j.jhazmat.2006.02.018","article-title":"Removal of copper(II) and lead(II) from aqueous solution by manganese oxide coated sand. II. Equilibrium study and competitive adsorption","volume":"B137","author":"Han","year":"2006","journal-title":"J. Hazard. Mater."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"307","DOI":"10.4067\/S0717-97072010000300006","article-title":"Kinetic and equilibrium studies on the removal of Pb(II) from aqueous solution using nettle ash","volume":"55","author":"Mousavi","year":"2010","journal-title":"J. Chil. Chem. Soc."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"187","DOI":"10.1016\/j.jhazmat.2014.01.056","article-title":"Selective removal of cesium from aqueous solutions with nickel (II) hexacyanoferrate (III) functionalized agricultural residue\u2013walnut shell","volume":"270","author":"Ding","year":"2014","journal-title":"J. Hazard. Mater."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"288","DOI":"10.1016\/j.jenvman.2018.07.066","article-title":"Valorisation possibilities of exhausted biosorbents loaded with metal ions\u2014A review","volume":"224","author":"Badescu","year":"2018","journal-title":"J. Environ. Manag."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1016\/j.conbuildmat.2014.04.117","article-title":"Properties and composition of recycled aggregates from construction and demolition waste suitable for concrete production","volume":"65","author":"Silva","year":"2014","journal-title":"Con. Build. Mat."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1016\/j.cemconcomp.2011.09.018","article-title":"Properties of high performance concrete containing fine-ground ceramics as supplementary cementitious material","volume":"34","author":"Keppert","year":"2012","journal-title":"Cement Concrete Compos."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"145","DOI":"10.1016\/j.clay.2016.02.016","article-title":"Use of waste ceramics in adsorption technologies","volume":"134","author":"Dousova","year":"2016","journal-title":"Appl. Clay Sci."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"424","DOI":"10.1016\/j.jcis.2006.06.054","article-title":"Sorption of AsV on aluminosilicates treated with FeII nanoparticles","volume":"302","author":"Grygar","year":"2006","journal-title":"J. Colloid Interface Sci."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"1030","DOI":"10.1016\/j.cep.2007.05.004","article-title":"Evaluation of iron oxide and aluminium oxide as potential arsenic(V) adsorbents","volume":"46","author":"Jeong","year":"2007","journal-title":"Chem. Eng. Process."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/0923-1137(93)90054-J","article-title":"Langmuir isotherm and its application in ion-exchange reactions","volume":"21","author":"Misak","year":"1993","journal-title":"React. Polym."},{"key":"ref_19","unstructured":"CEN 2002 (2003, October 01). CEN 2002. Characterization of Waste-Leaching-Compliance Test for Leaching of Granular Waste Material and Sludge Part 2. Comite Europeen de Normalisation 2002, EN 12457-2. Available online: https:\/\/www.sis.se\/en\/produkter\/environment-health-protection-safety\/wastes\/solid-wastes\/ssen124574\/."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"241","DOI":"10.1016\/0926-2040(95)00002-8","article-title":"Ga-71 and Ga-69 Nuclear-Magnetic-Resonance Study of Beta-Ga2O3-Resolution of 4-Fold and 6-Fold Coordinated Ga Sites in Static Conditions","volume":"4","author":"Massiot","year":"1995","journal-title":"Solid State Nucl. Magn. Reson."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"151","DOI":"10.1016\/S0926-2040(00)00061-8","article-title":"Heating of samples induced by fast magic-angle spinning","volume":"16","author":"Brus","year":"2000","journal-title":"Solid State Nucl. Magn. Reson."},{"key":"ref_22","unstructured":"Walther, J.V. (2009). Essentials of Geochemistry, Jones and Bartlett Publishers Inc.. [2nd ed.]."},{"key":"ref_23","unstructured":"Bohn, H.L., Mc Neal, B.L., and O\u2019Conner, G.A. (1985). Soil Chemistry, John Wiley and Sons. [2nd ed.]."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"2028","DOI":"10.2138\/am-2003-11-1247","article-title":"Sorption mechanisms of Sr(II) and Pb(II) on zeolitized tuffs from the Nevada Test Site as a function of pH and ionic strength","volume":"88","author":"Um","year":"2003","journal-title":"Am. Mineral."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"2995","DOI":"10.1039\/FT9918702995","article-title":"Thermodynamics of Solvation of Ions","volume":"87","author":"Marcus","year":"1991","journal-title":"J. Chem. Soc. Faraday Trans."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1209","DOI":"10.1016\/S0016-7037(99)00386-5","article-title":"XPS studies on the electronic structure of bonding between solid and solutes: Adsorption of arsenate, chromate, phosphate, Pb2+, and Zn2+ ions on amorphous black ferric oxyhydroxide","volume":"64","author":"Ding","year":"2000","journal-title":"Geochim. Cosmochim. Acta"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"870","DOI":"10.1021\/es970098q","article-title":"Surface complexation model for the heavy metal adsorption on natural sediment","volume":"32","author":"Wen","year":"1998","journal-title":"Environ. Sci. Technol."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"6837","DOI":"10.1021\/ja963593f","article-title":"Empirical Correlations between 207Pb NMR Chemical Shifts and Structure in Solids","volume":"119","author":"Fayon","year":"1997","journal-title":"J. Am. Chem. Soc."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1007\/BF02389445","article-title":"Sorption of caesium and strontium on clinoptilolite- and mordenite-containing sedimentary rocks","volume":"229","author":"Rajec","year":"1998","journal-title":"J. Radioanal. Nucl. Chem."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"655","DOI":"10.1016\/S0969-8043(98)00134-1","article-title":"The use of clinoptilolite and its sodium form for removal of radioactive cesium and strontium from nuclear wastewater and Pb2+, Ni2+, Cd2+, Ba2+ from municipal wastewater","volume":"50","author":"Faghihian","year":"1999","journal-title":"Appl. Radiat. Isotopes"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"23","DOI":"10.1016\/j.clay.2004.09.002","article-title":"Caesium adsorption on soil clay: Macroscopic and spectroscopic measurements","volume":"29","author":"Bergaoui","year":"2005","journal-title":"Appl. Clay Sci."}],"container-title":["Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1944\/12\/10\/1647\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T12:53:44Z","timestamp":1760187224000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1944\/12\/10\/1647"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,5,20]]},"references-count":31,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2019,5]]}},"alternative-id":["ma12101647"],"URL":"https:\/\/doi.org\/10.3390\/ma12101647","relation":{},"ISSN":["1996-1944"],"issn-type":[{"value":"1996-1944","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,5,20]]}}}