{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T11:33:16Z","timestamp":1768822396294,"version":"3.49.0"},"reference-count":140,"publisher":"MDPI AG","issue":"23","license":[{"start":{"date-parts":[[2019,11,22]],"date-time":"2019-11-22T00:00:00Z","timestamp":1574380800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004837","name":"Ministerio de Ciencia e Innovaci\u00f3n","doi-asserted-by":"publisher","award":["CTQ2016-77147"],"award-info":[{"award-number":["CTQ2016-77147"]}],"id":[{"id":"10.13039\/501100004837","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Volatile organic compounds (VOCs) are recognized as hazardous contributors to air pollution, precursors of multiple secondary byproducts, troposphere aerosols, and recognized contributors to respiratory and cancer-related issues in highly populated areas. Moreover, VOCs present in indoor environments represent a challenging issue that need to be addressed due to its increasing presence in nowadays society. Catalytic oxidation by noble metals represents the most effective but costly solution. The use of photocatalytic oxidation has become one of the most explored alternatives given the green and sustainable advantages of using solar light or low-consumption light emitting devices. Herein, we have tried to address the shortcomings of the most studied photocatalytic systems based on titania (TiO2) with limited response in the UV-range or alternatively the high recombination rates detected in other transition metal-based oxide systems. We have developed a silver-copper oxide heteronanostructure able to combine the plasmonic-enhanced properties of Ag nanostructures with the visible-light driven photoresponse of CuO nanoarchitectures. The entangled Ag-CuO heteronanostructure exhibits a broad absorption towards the visible-near infrared (NIR) range and achieves total photo-oxidation of n-hexane under irradiation with different light-emitting diodes (LEDs) specific wavelengths at temperatures below 180 \u00b0C and outperforming its thermal catalytic response or its silver-free CuO illuminated counterpart.<\/jats:p>","DOI":"10.3390\/ma12233858","type":"journal-article","created":{"date-parts":[[2019,11,22]],"date-time":"2019-11-22T09:02:52Z","timestamp":1574413372000},"page":"3858","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Silver-Copper Oxide Heteronanostructures for the Plasmonic-Enhanced Photocatalytic Oxidation of N-Hexane in the Visible-NIR Range"],"prefix":"10.3390","volume":"12","author":[{"given":"Hugo","family":"Suarez","sequence":"first","affiliation":[{"name":"Institute of Nanoscience of Aragon (INA) and Department of Chemical and Environmental Engineering, C\/Poeta Mariano Esquillor, s\/n; Campus Rio Ebro, Edificio I+D, 50018 Zaragoza, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5036-1355","authenticated-orcid":false,"given":"Adrian","family":"Ramirez","sequence":"additional","affiliation":[{"name":"Institute of Nanoscience of Aragon (INA) and Department of Chemical and Environmental Engineering, C\/Poeta Mariano Esquillor, s\/n; Campus Rio Ebro, Edificio I+D, 50018 Zaragoza, Spain"},{"name":"KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), 23955 Thuwal, Saudi Arabia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Carlos J.","family":"Bueno-Alejo","sequence":"additional","affiliation":[{"name":"Institute of Nanoscience of Aragon (INA) and Department of Chemical and Environmental Engineering, C\/Poeta Mariano Esquillor, s\/n; Campus Rio Ebro, Edificio I+D, 50018 Zaragoza, Spain"},{"name":"Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), 28029 Madrid, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jose L.","family":"Hueso","sequence":"additional","affiliation":[{"name":"Institute of Nanoscience of Aragon (INA) and Department of Chemical and Environmental Engineering, C\/Poeta Mariano Esquillor, s\/n; Campus Rio Ebro, Edificio I+D, 50018 Zaragoza, Spain"},{"name":"Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), 28029 Madrid, Spain"},{"name":"Instituto de Ciencia de Materiales de Aragon (ICMA), Consejo Superior de Investigaciones Cientificas (CSIC-University of Zaragoza), 50018 Zaragoza, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2019,11,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1016\/j.atmosenv.2016.05.031","article-title":"Catalytic oxidation of volatile organic compounds (VOCs)\u2014A review","volume":"140","author":"Kamal","year":"2016","journal-title":"Atmos. 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