{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T12:44:58Z","timestamp":1790685898527,"version":"4.1.0"},"reference-count":38,"publisher":"MDPI AG","issue":"9","license":[{"start":{"date-parts":[[2020,4,25]],"date-time":"2020-04-25T00:00:00Z","timestamp":1587772800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["382919963"],"award-info":[{"award-number":["382919963"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Corrosion of taper connections in total hip arthroplasty remains of concern, as particles and ions generated by corrosive processes can cause clinical problems such as periprosthetic osteolysis or adverse reaction to metallic debris. Mechanical surface treatments that introduce compressive residual stresses (RSs) in metallic materials can lead to a better performance in terms of fretting and fatigue and may lower the susceptibility to corrosion. The study investigates the impact of mechanical surface treatments on the corrosion behavior of metallic biomaterials. Compressive RSs were introduced by deep rolling and microblasting in Ti6Al4V and CoCrMo samples. Polished samples served as reference. Corrosion behavior was characterized by repeated anodic polarization. Residual stresses of up to about \u2212900 MPa were introduced by deep rolling with a reach in depth of approximately 500 \u00b5m. Microblasting led to compressive RSs up to approximately \u2212800 and \u2212600 MPa for Ti6Al4V and CoCrMo, respectively, in the immediate vicinity of the surface. For Ti6Al4V, microblasting resulted in decreased corrosion resistance with lower breakdown potentials and\/or increased passive current densities in comparison to the polished and deep-rolled samples. The corrosion behavior of CoCrMo on the other hand was not affected by the mechanical surface treatments.<\/jats:p>","DOI":"10.3390\/ma13092011","type":"journal-article","created":{"date-parts":[[2020,4,28]],"date-time":"2020-04-28T05:05:32Z","timestamp":1588050332000},"page":"2011","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Corrosion Behavior of Surface-Treated Metallic Implant Materials"],"prefix":"10.3390","volume":"13","author":[{"given":"Therese","family":"Bormann","sequence":"first","affiliation":[{"name":"Laboratory of Biomechanics and Implant Research, Clinic for Orthopedics and Trauma Surgery, Heidelberg University Hospital, 69118 Heidelberg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Phuong Thao","family":"Mai","sequence":"additional","affiliation":[{"name":"Institute for Applied Materials, Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jens","family":"Gibmeier","sequence":"additional","affiliation":[{"name":"Institute for Applied Materials, Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1809-7528","authenticated-orcid":false,"given":"Robert","family":"Sonntag","sequence":"additional","affiliation":[{"name":"Laboratory of Biomechanics and Implant Research, Clinic for Orthopedics and Trauma Surgery, Heidelberg University Hospital, 69118 Heidelberg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1684-7671","authenticated-orcid":false,"given":"Ulrike","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Laboratory of Biomechanics and Implant Research, Clinic for Orthopedics and Trauma Surgery, Heidelberg University Hospital, 69118 Heidelberg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J. Philippe","family":"Kretzer","sequence":"additional","affiliation":[{"name":"Laboratory of Biomechanics and Implant Research, Clinic for Orthopedics and Trauma Surgery, Heidelberg University Hospital, 69118 Heidelberg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2020,4,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2546","DOI":"10.1016\/j.arth.2017.03.020","article-title":"Ten-Year Cross-Sectional Study of Mechanically Assisted Crevice Corrosion in 1352 Consecutive Patients With Metal-on-Polyethylene Total Hip Arthroplasty","volume":"32","author":"Hussey","year":"2017","journal-title":"J. Arthroplast."},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Hall, D.J., Pourzal, R., and Jacobs, J.J. (2020). What Surgeons Need to Know About Adverse Local Tissue Reaction in Total Hip Arthroplasty. J. Arthroplast.","DOI":"10.1016\/j.arth.2020.01.016"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"1533","DOI":"10.1002\/jbm.820271210","article-title":"In vivo corrosion of modular hip prosthesis components in mixed and similar metal combinations. The effect of crevice, stress, motion, and alloy coupling","volume":"27","author":"Gilbert","year":"1993","journal-title":"J. Biomed. Mater. Res."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"NP1","DOI":"10.1177\/1120700019860774","article-title":"Catastrophic femoral head trunnion dissociation: A case series with surface wear analysis","volume":"29","author":"Wood","year":"2019","journal-title":"HIP Int."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"711","DOI":"10.1007\/s00590-018-2333-5","article-title":"A case example and literature review of catastrophic wear before catastrophic failure: Identification of trunnionosis and metallosis in metal-on-polyethylene hip arthroplasty prior to frank failure or fracture","volume":"29","author":"Hunter","year":"2019","journal-title":"Eur. J. Orthop. Surg.Traumatol."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"2996","DOI":"10.1002\/jor.24107","article-title":"Role of corrosion in taper failure and head disassociation in total hip arthroplasty of a single design","volume":"36","author":"Martin","year":"2018","journal-title":"J. Orthop. Res."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"1945","DOI":"10.1016\/j.arth.2017.12.044","article-title":"Retrieval Analysis of Large-Head Modular Metal-on-Metal Hip Replacements of a Single Design","volume":"33","author":"Gascoyne","year":"2018","journal-title":"J. Arthroplast."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"3270","DOI":"10.1007\/s11999-013-3096-2","article-title":"Do Ceramic Femoral Heads Reduce Taper Fretting Corrosion in Hip Arthroplasty? A Retrieval Study","volume":"471","author":"Kurtz","year":"2013","journal-title":"Clin. Orthop. Relat. Res."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/j.clinbiomech.2011.08.002","article-title":"Influence of assembly procedure and material combination on the strength of the taper connection at the head\u2013neck junction of modular hip endoprostheses","volume":"27","author":"Rehmer","year":"2012","journal-title":"Clin. Biomech."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"109424","DOI":"10.1016\/j.jbiomech.2019.109424","article-title":"Micromotion at the head-stem taper junction of total hip prostheses is influenced by prosthesis design-, patient- and surgeon-related factors","volume":"98","author":"Falkenberg","year":"2020","journal-title":"J. Biomech."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"405","DOI":"10.1002\/jor.23601","article-title":"Effect of impact assembly on the interface deformation and fretting corrosion of modular hip tapers: An in vitro study","volume":"36","author":"Panagiotidou","year":"2018","journal-title":"J. Orthop. Res."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1675","DOI":"10.1016\/j.arth.2016.11.054","article-title":"Assessment of Head Displacement and Disassembly Force With Increasing Assembly Load at the Head\/Trunnion Junction of a Total Hip Arthroplasty Prosthesis","volume":"32","author":"Ramoutar","year":"2017","journal-title":"J. Arthroplast."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"292","DOI":"10.1016\/j.surfcoat.2017.08.067","article-title":"On the effect of shot-peening on fretting fatigue of Al7075-T6 under cyclic normal contact loading","volume":"328","author":"Majzoobi","year":"2017","journal-title":"Surf. Coat. Technol."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"1250","DOI":"10.1016\/j.triboint.2009.04.005","article-title":"The effects of laser peening and shot peening on fretting fatigue in Ti\u20136Al\u20134V coupons","volume":"42","author":"Liu","year":"2009","journal-title":"Tribol. Int."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"452","DOI":"10.1016\/j.rinp.2018.09.047","article-title":"Effect of shot peening on the fatigue properties of nickel-based superalloy GH4169 at high temperature","volume":"11","author":"Zhao","year":"2018","journal-title":"Results Phys."},{"key":"ref_16","doi-asserted-by":"crossref","unstructured":"Sonntag, R., Reinders, J., Gibmeier, J., and Kretzer, J.P. (2015). Fatigue performance of medical Ti6Al4V alloy after mechanical surface treatments. PLoS ONE, 10.","DOI":"10.1371\/journal.pone.0121963"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"292","DOI":"10.1016\/j.ijfatigue.2012.03.008","article-title":"On the effect of deep-rolling and laser-peening on the stress-controlled low- and high-cycle fatigue behavior of Ti\u20136Al\u20134V at elevated temperatures up to 550 \u00b0C","volume":"44","author":"Altenberger","year":"2012","journal-title":"Int. J. Fatigue"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"433","DOI":"10.1016\/j.msea.2013.10.066","article-title":"Effect of residual stress induced by pulsed-laser irradiation on initiation of chloride stress corrosion cracking in stainless steel","volume":"590","author":"Eto","year":"2014","journal-title":"Mater. Sci. Eng. A"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"1641","DOI":"10.1016\/S1003-6326(19)65071-5","article-title":"Microstructure, mechanical and corrosion properties of magnesium alloy bone plate treated by high-energy shot peening","volume":"29","author":"Wu","year":"2019","journal-title":"Trans. Nonferrous Met. Soc. China"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.corsci.2018.08.030","article-title":"Improvement of corrosion resistance of AA2024-T3 using femtosecond laser peening without protective and confining medium","volume":"143","author":"Trdan","year":"2018","journal-title":"Corros. Sci."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"72","DOI":"10.1016\/j.msea.2006.01.031","article-title":"Fretting fatigue behavior of shot-peened Ti\u20136Al\u20134V under seawater environment","volume":"420","author":"Lee","year":"2006","journal-title":"Mater. Sci. Eng. A"},{"key":"ref_22","first-page":"59","article-title":"Mechanical Surface Treatment by Micro Peening","volume":"70","author":"Hoffmeister","year":"2015","journal-title":"HTM J. Heat Treat. Mater."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"781","DOI":"10.1023\/A:1018568830442","article-title":"Characterization of microblasted and reactive ion etched surfaces on the commercially pure metals niobium, tantalum and titanium","volume":"8","author":"Pypen","year":"1997","journal-title":"J. Mater. Sci. Mater. Med."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1002\/mawe.19950260310","article-title":"R\u00f6ntgenographische Untersuchung von Spannungszust\u00e4nden in Werkstoffen","volume":"26","author":"Eigenmann","year":"1995","journal-title":"Materialwissenschaft Werkst."},{"key":"ref_25","unstructured":"ASTM (2015). F2129-15, Standard Test Method for Conducting Cyclic Poentiodynamic Polarization Measurements to Determine the Corrosion Susceptibility of Small Implant Devices, ASTM International."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.biotri.2017.07.002","article-title":"Biomechanical Evaluation of the Fatigue Performance, the Taper Corrosion and the Metal Ion Release of a Dual Taper Hip Prosthesis under Physiological Environmental Conditions","volume":"12","author":"Baxmann","year":"2017","journal-title":"Biotribology"},{"key":"ref_27","unstructured":"ASTM (2003). G48-03, Standard Test Methods for Pitting and Crevice Corrosion Resistance of Stainless Steels and Related Alloys by Use of Ferric Chloride Solution, ASTM International."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"2103","DOI":"10.1016\/S0142-9612(00)00145-9","article-title":"Passive film on orthopaedic TiAlV alloy formed in physiological solution investigated by X-ray photoelectron spectroscopy","volume":"21","author":"Strehblow","year":"2000","journal-title":"Biomaterials"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"385","DOI":"10.1016\/j.apsusc.2017.01.033","article-title":"Role of surface roughness on corrosion and fretting corrosion behaviour of commercially pure titanium in Ringer\u2019s solution for bio-implant application","volume":"401","author":"Sivakumar","year":"2017","journal-title":"Appl. Surf. Sci."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"3262","DOI":"10.1016\/j.corsci.2011.06.009","article-title":"Effects of bovine serum albumin on the corrosion behaviour of AISI 316L, Co\u201328Cr\u20136Mo, and Ti\u20136Al\u20134V alloys in phosphate buffered saline solutions","volume":"53","author":"Karimi","year":"2011","journal-title":"Corros. Sci."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"2767","DOI":"10.1016\/S0013-4686(03)00396-7","article-title":"The composition of the surface passive film formed on CoCrMo alloy in simulated physiological solution","volume":"48","author":"Strehblow","year":"2003","journal-title":"Electrochim. Acta"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"1087","DOI":"10.1016\/j.msec.2011.11.007","article-title":"The corrosion resistance of Nitinol alloy in simulated physiological solutions: Part 1: The effect of surface preparation","volume":"32","author":"Kapun","year":"2012","journal-title":"Mater. Sci. Eng. C"},{"key":"ref_33","first-page":"433","article-title":"An investigation into the effects of polishing on surface hardness and corrosion of orthodontic archwires","volume":"69","author":"Hunt","year":"1999","journal-title":"Angle Orthod."},{"key":"ref_34","doi-asserted-by":"crossref","unstructured":"Chi, G., Yi, D., and Liu, H. (2019). Effect of roughness on electrochemical and pitting corrosion of Ti-6Al-4V alloy in 12 wt.% HCl solution at 35 \u00b0C. J. Mater. Res. Technol.","DOI":"10.1016\/j.jmrt.2019.11.044"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"3546","DOI":"10.1016\/j.surfcoat.2010.04.015","article-title":"The effect of shot peening on fatigue and corrosion behavior of 316L stainless steel in Ringer\u2019s solution","volume":"204","author":"Azar","year":"2010","journal-title":"Surf. Coat. Technol."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"507","DOI":"10.1007\/s10800-013-0534-5","article-title":"Influence of surface roughness on the electrochemical behavior of carbon steel","volume":"43","author":"Kim","year":"2013","journal-title":"J. Appl. Electrochem."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"149","DOI":"10.1097\/00003086-200208000-00018","article-title":"A multicenter retrieval study of the taper interfaces of modular hip prostheses","volume":"401","author":"Goldberg","year":"2002","journal-title":"Clin. Orthop. Relat. Res."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"579","DOI":"10.1302\/0301-620X.98B5.35592","article-title":"Corrosion at the head-neck interface of current designs of modular femoral components","volume":"98","author":"Osman","year":"2016","journal-title":"Bone Joint J."}],"container-title":["Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1944\/13\/9\/2011\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T13:23:44Z","timestamp":1760361824000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1944\/13\/9\/2011"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,4,25]]},"references-count":38,"journal-issue":{"issue":"9","published-online":{"date-parts":[[2020,5]]}},"alternative-id":["ma13092011"],"URL":"https:\/\/doi.org\/10.3390\/ma13092011","relation":{},"ISSN":["1996-1944"],"issn-type":[{"value":"1996-1944","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,4,25]]}}}