{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,15]],"date-time":"2026-04-15T19:57:53Z","timestamp":1776283073910,"version":"3.50.1"},"reference-count":55,"publisher":"MDPI AG","issue":"21","license":[{"start":{"date-parts":[[2020,10,22]],"date-time":"2020-10-22T00:00:00Z","timestamp":1603324800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001793","name":"Queensland University of Technology","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100001793","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Distinctive Cr-MOF@Da composites have been constructed using chromium-based metal-organic frameworks (MOFs) and diatomite (Da). The new materials have hierarchical pore structures containing micropores, mesopores and macropores. We have synthesized various morphologies of the MOF compound Cr-MIL-101 to combine with Da in a one-pot reaction step. These distinctive hierarchical pore networks within Cr-MIL-101@Da enable exceptional adsorptive performance for a range of molecules, including hydrogen (H2), carbon dioxide (CO2) and water (H2O) vapor. Selectivity for H2 or CO2 can be moderated by the morphology and composition of the Cr-MIL-101 included in the Cr-MOF@Da composite. The encapsulation and growth of Cr-MIL-101 within and on Da have resulted in excellent water retention as well as high thermal and hydrolytic stability. In some cases, Cr-MIL-101@Da composite materials have demonstrated increased thermal stability compared with that of Cr-MIL-101; for example, decomposition temperatures &gt;340 \u2103 can be achieved. Furthermore, these Cr-MIL-101@Da composites retain structural and morphological integrity after 60 cycles of repeated hydration\/dehydration, and after storage for more than one year. These characteristics are difficult to achieve with many MOF materials, and thus suggest that MOF\u2013mineral composites show high potential for practical gas storage and water vapor capture.<\/jats:p>","DOI":"10.3390\/ma13214700","type":"journal-article","created":{"date-parts":[[2020,10,22]],"date-time":"2020-10-22T10:27:58Z","timestamp":1603362478000},"page":"4700","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Diatomite-Metal-Organic Framework Composite with Hierarchical Pore Structures for Adsorption\/Desorption of Hydrogen, Carbon Dioxide and Water Vapor"],"prefix":"10.3390","volume":"13","author":[{"given":"Gaofeng","family":"Wang","sequence":"first","affiliation":[{"name":"Institute for Future Environments and Science and Engineering Faculty, Queensland University of Technology (QUT), Brisbane, Queensland 4001, Australia"},{"name":"CAS Key Laboratory of Mineralogy and Metallogeny, Guangdong Provincial Key Laboratory of Mineral Physics and Material Research and Development, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Elizabeth","family":"Graham","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Mineralogy and Metallogeny, Guangdong Provincial Key Laboratory of Mineral Physics and Material Research and Development, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shuilin","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jianxi","family":"Zhu","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Mineralogy and Metallogeny, Guangdong Provincial Key Laboratory of Mineral Physics and Material Research and Development, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Runliang","family":"Zhu","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Mineralogy and Metallogeny, Guangdong Provincial Key Laboratory of Mineral Physics and Material Research and Development, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hongping","family":"He","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Mineralogy and Metallogeny, Guangdong Provincial Key Laboratory of Mineral Physics and Material Research and Development, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9818-1994","authenticated-orcid":false,"given":"Zhiming","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0732-8987","authenticated-orcid":false,"given":"Ian D. R.","family":"Mackinnon","sequence":"additional","affiliation":[{"name":"Institute for Future Environments and Science and Engineering Faculty, Queensland University of Technology (QUT), Brisbane, Queensland 4001, Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2924-9494","authenticated-orcid":false,"given":"Yunfei","family":"Xi","sequence":"additional","affiliation":[{"name":"Institute for Future Environments and Science and Engineering Faculty, Queensland University of Technology (QUT), Brisbane, Queensland 4001, Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2020,10,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"483","DOI":"10.1021\/acs.accounts.5b00530","article-title":"Metal\u2013organic frameworks as platforms for functional materials","volume":"49","author":"Cui","year":"2016","journal-title":"Acc. Chem. 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