{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,3]],"date-time":"2026-07-03T00:08:55Z","timestamp":1783037335772,"version":"3.54.6"},"reference-count":68,"publisher":"MDPI AG","issue":"24","license":[{"start":{"date-parts":[[2020,12,13]],"date-time":"2020-12-13T00:00:00Z","timestamp":1607817600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["16-13-10537"],"award-info":[{"award-number":["16-13-10537"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Varying the temperature of the reaction of [{Cd(pfb)(H2O)4}+n\u00b7n(pfb)\u2212], [Ln2(pfb)6(H2O)8]\u00b7H2O (Hpfb = pentafluorobenzoic acid), and 1,10-phenanthroline (phen) in MeCN followed by crystallization resulted in the isolation of two type of products: 1D-polymers [LnCd(pfb)5(phen)]n\u00b71.5nMeCN (Ln = Eu (I), Gd (II), Tb (III), Dy (IV)) which were isolated at 25 \u00b0C, and molecular compounds [Tb2Cd2(pfb)10(phen)2] (V) formed at 75 \u00b0C. The transition from a molecular to a polymer structure becomes possible because of intra- and intermolecular interactions between the aromatic cycles of phen and pfb from neighboring tetranuclear Ln2Cd2 fragments. Replacement of cadmium with zinc in the reaction resulted in molecular compounds Ln2Zn2 [Ln2Zn2(pfb)10(phen)2]\u00b74MeCN (Ln = Eu (VI), Tb (VIII), Dy (IX)) and [Gd2Zn2(pfb)10(H2O)2(phen)2]\u00b74MeCN (VII). A new molecular EuCd complex [Eu2Cd2(pfb)10(phen)4]\u00b74MeCN (X)] was isolated from a mixture of cadmium, zinc, and europium pentafluorobenzoates (Cd:Zn:Ln = 1:1:2). Complexes II-IV, VII and IX exhibit magnetic relaxation at liquid helium temperatures in nonzero magnetic fields. Luminescent studies revealed a bright luminescence of complexes with europium(III) and terbium(III) ions.<\/jats:p>","DOI":"10.3390\/ma13245689","type":"journal-article","created":{"date-parts":[[2020,12,13]],"date-time":"2020-12-13T23:39:36Z","timestamp":1607902776000},"page":"5689","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["Molecular and Polymer Ln2M2 (Ln = Eu, Gd, Tb, Dy; M = Zn, Cd) Complexes with Pentafluorobenzoate Anions: The Role of Temperature and Stacking Effects in the Structure; Magnetic and Luminescent Properties"],"prefix":"10.3390","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7345-6856","authenticated-orcid":false,"given":"Maxim A.","family":"Shmelev","sequence":"first","affiliation":[{"name":"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8782-1308","authenticated-orcid":false,"given":"Mikhail A.","family":"Kiskin","sequence":"additional","affiliation":[{"name":"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9222-5853","authenticated-orcid":false,"given":"Julia K.","family":"Voronina","sequence":"additional","affiliation":[{"name":"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1904-9894","authenticated-orcid":false,"given":"Konstantin A.","family":"Babeshkin","sequence":"additional","affiliation":[{"name":"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4651-7948","authenticated-orcid":false,"given":"Nikolay N.","family":"Efimov","sequence":"additional","affiliation":[{"name":"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Evgenia A.","family":"Varaksina","sequence":"additional","affiliation":[{"name":"P. N. Lebedev Physical Institute, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vladislav M.","family":"Korshunov","sequence":"additional","affiliation":[{"name":"P. N. Lebedev Physical Institute, Russian Academy of Sciences, 119991 Moscow, Russia"},{"name":"Faculty of Fundamental Sciences, Bauman Moscow State Technical University, 105005 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ilya V.","family":"Taydakov","sequence":"additional","affiliation":[{"name":"P. N. Lebedev Physical Institute, Russian Academy of Sciences, 119991 Moscow, Russia"},{"name":"Academic Department of Innovational Materials and Technologies Chemistry, Plekhanov Russian University of Economics, 117997 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Natalia V.","family":"Gogoleva","sequence":"additional","affiliation":[{"name":"N. S. 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Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2020,12,13]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"8465","DOI":"10.1016\/j.tet.2011.09.004","article-title":"Ytterbium pentafluorobenzoate as a novel fluorous Lewis acid catalyst in the synthesis of 2,4-disubstituted quinolines","volume":"67","author":"Tang","year":"2011","journal-title":"Tetrahedron"},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Baldov\u00ed, J.J., and Kondinski, A. (2018). Exploring High-Symmetry Lanthanide-Functionalized Polyoxopalladates as Building Blocks for Quantum Computing. Inorganics, 6.","DOI":"10.20944\/preprints201806.0369.v1"},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Efimov, N.N., Koroteev, P.S., Gavrikov, A., Ilyukhin, A.B., Dobrokhotova, Z.V., and Novotortsev, V.M. (2016). 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