{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T16:19:12Z","timestamp":1791908352171,"version":"4.3.4"},"reference-count":60,"publisher":"MDPI AG","issue":"8","license":[{"start":{"date-parts":[[2021,4,20]],"date-time":"2021-04-20T00:00:00Z","timestamp":1618876800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>In this work, we continued our systematic investigations on synthesis, structural studies, and electrochemical behavior of Ni-rich materials Li[NixCoyMnz]O2 (x + y + z = 1; x \u2265 0.8) for advanced lithium-ion batteries (LIBs). We focused, herein, on LiNi0.85Co0.10Mn0.05O2 (NCM85) and demonstrated that doping this material with high-charge cation Mo6+ (1 at. %, by a minor nickel substitution) results in substantially stable cycling performance, increased rate capability, lowering of the voltage hysteresis, and impedance in Li-cells with EC-EMC\/LiPF6 solutions. Incorporation of Mo-dopant into the NCM85 structure was carried out by in-situ approach, upon the synthesis using ammonium molybdate as the precursor. From X-ray diffraction studies and based on our previous investigation of Mo-doped NCM523 and Ni-rich NCM811 materials, it was revealed that Mo6+ preferably substitutes Ni residing either in 3a or 3b sites. We correlated the improved behavior of the doped NCM85 electrode materials in Li-cells with a partial Mo segregation at the surface and at the grain boundaries, a tendency established previously in our lab for the other members of the Li[NixCoyMnz]O2 family.<\/jats:p>","DOI":"10.3390\/ma14082070","type":"journal-article","created":{"date-parts":[[2021,4,20]],"date-time":"2021-04-20T13:58:04Z","timestamp":1618927084000},"page":"2070","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Studies of Nickel-Rich LiNi0.85Co0.10Mn0.05O2 Cathode Materials Doped with Molybdenum Ions for Lithium-Ion Batteries"],"prefix":"10.3390","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3778-4200","authenticated-orcid":false,"given":"Francis Amalraj","family":"Susai","sequence":"first","affiliation":[{"name":"Department of Chemistry, Institute for Nanotechnology and Advanced Materials (BINA), Bar-Ilan University, Ramat-Gan 52900, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1799-0851","authenticated-orcid":false,"given":"Daniela","family":"Kovacheva","sequence":"additional","affiliation":[{"name":"Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tatyana","family":"Kravchuk","sequence":"additional","affiliation":[{"name":"Solid State Institute, Technion\u2014Israel Institute of Technology, Haifa 32000, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaron","family":"Kauffmann","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, Technion\u2014Israel Institute of Technology, Haifa 32000, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9661-7037","authenticated-orcid":false,"given":"Sandipan","family":"Maiti","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Institute for Nanotechnology and Advanced Materials (BINA), Bar-Ilan University, Ramat-Gan 52900, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arup","family":"Chakraborty","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Institute for Nanotechnology and Advanced Materials (BINA), Bar-Ilan University, Ramat-Gan 52900, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6734-4786","authenticated-orcid":false,"given":"Sooraj","family":"Kunnikuruvan","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Institute for Nanotechnology and Advanced Materials (BINA), Bar-Ilan University, Ramat-Gan 52900, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Talianker","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 84105, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0633-7782","authenticated-orcid":false,"given":"Hadar","family":"Sclar","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Institute for Nanotechnology and Advanced Materials (BINA), Bar-Ilan University, Ramat-Gan 52900, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yafit","family":"Fleger","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Institute for Nanotechnology and Advanced Materials (BINA), Bar-Ilan University, Ramat-Gan 52900, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Boris","family":"Markovsky","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Institute for Nanotechnology and Advanced Materials (BINA), Bar-Ilan University, Ramat-Gan 52900, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Doron","family":"Aurbach","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Institute for Nanotechnology and Advanced Materials (BINA), Bar-Ilan University, Ramat-Gan 52900, Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2021,4,20]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3243","DOI":"10.1039\/c1ee01598b","article-title":"Challenges in the development of advanced Li-ion batteries: A review","volume":"4","author":"Etacheri","year":"2011","journal-title":"Energy Environ. 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