{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,16]],"date-time":"2026-05-16T12:40:47Z","timestamp":1778935247673,"version":"3.51.4"},"reference-count":65,"publisher":"MDPI AG","issue":"10","license":[{"start":{"date-parts":[[2021,5,20]],"date-time":"2021-05-20T00:00:00Z","timestamp":1621468800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Deutsche Forschungsgemeinschaft (DFG)","award":["KO1616-4"],"award-info":[{"award-number":["KO1616-4"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>A series of new low-melting triply charged homoleptic Cr(III)-based ionic liquids of the general formula (RMIm)3[Cr(NCS)6] (R = methyl, ethyl, n-butyl, benzyl) is reported. Their syntheses and properties are described in comparison to their singly charged heteroleptic analogues of the general formula (RMIm)[Cr(NCS)4L2] (R = methyl, ethyl, n-butyl, benzyl; L = pyridine, \u03b3-picoline). In total, sixteen new Reineckate related salts with large imidazolium cations are described. Out of these, five compounds were crystallized, and their structures determined by single-crystal X-ray structure analyses. They all consisted of discrete anions and cations with octahedrally coordinated Cr(III) ions. In the structures, various hydrogen contacts interconnect the entities to build up hydrogen bonded networks. Thermal investigations showed relatively low melting points for the homoleptic complexes. The compounds with the [Cr(NCS)6]3\u2212 anion melt without decomposition and are stable up to 200 K above their melting points. The complex salts with the [Cr(NCS)4L2]\u2212 anion, in contrast, start to decompose and lose L molecules (Pyr or Pic) already at the melting point.<\/jats:p>","DOI":"10.3390\/ma14102676","type":"journal-article","created":{"date-parts":[[2021,5,20]],"date-time":"2021-05-20T06:13:45Z","timestamp":1621491225000},"page":"2676","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["New Low-Melting Triply Charged Homoleptic Cr(III)-Based Ionic Liquids in Comparison to Their Singly Charged Heteroleptic Analogues"],"prefix":"10.3390","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7814-7235","authenticated-orcid":false,"given":"Tim","family":"Peppel","sequence":"first","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.V. (LIKAT), Heterogene Photokatalyse, Albert-Einstein-Str. 29a, 18059 Rostock, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Martin","family":"K\u00f6ckerling","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie, Anorganische Festk\u00f6rperchemie, Universit\u00e4t Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany"},{"name":"Department Life, Light and Matter, Universit\u00e4t Rostock, 18051 Rostock, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2021,5,20]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"4317","DOI":"10.1039\/C9CS00016J","article-title":"Biocompatible ionic liquids: Fundamental behaviours and applications","volume":"48","author":"Gomes","year":"2019","journal-title":"Chem. Soc. Rev."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"3508","DOI":"10.1021\/cr1003248","article-title":"Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2","volume":"111","author":"Hallett","year":"2011","journal-title":"Chem. Rev."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"6357","DOI":"10.1021\/cr500411q","article-title":"Structure and Nanostructure in Ionic Liquids","volume":"115","author":"Hayes","year":"2015","journal-title":"Chem. Rev."},{"key":"ref_4","doi-asserted-by":"crossref","unstructured":"Sheldon, R. (2001). Catalytic reactions in ionic liquids. Chem. Commun., 2399\u20132407.","DOI":"10.1039\/b107270f"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"2071","DOI":"10.1021\/cr980032t","article-title":"Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis","volume":"99","author":"Welton","year":"1999","journal-title":"Chem. Rev."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"862","DOI":"10.1016\/j.ccr.2008.05.018","article-title":"Carbenes: Synthesis, properties, and organometallic chemistry","volume":"253","author":"Marion","year":"2009","journal-title":"Coord. Chem. Rev."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"3122","DOI":"10.1002\/anie.200703883","article-title":"Heterocyclic Carbenes: Synthesis and Coordination Chemistry","volume":"47","author":"Hahn","year":"2008","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"485","DOI":"10.1038\/nature13384","article-title":"An overview of N-heterocyclic carbenes","volume":"510","author":"Hopkinson","year":"2014","journal-title":"Nature"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1016\/j.aca.2016.06.011","article-title":"Magnetic ionic liquids in analytical chemistry: A review","volume":"934","author":"Clark","year":"2016","journal-title":"Anal. Chim. Acta"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"319","DOI":"10.1016\/j.molliq.2016.02.086","article-title":"Paramagnetic ionic liquids for advanced applications: A review","volume":"218","author":"Joseph","year":"2016","journal-title":"J. Mol. Liq."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"40008","DOI":"10.1039\/C4RA05156D","article-title":"Magnetic ionic liquids: Synthesis, properties and applications","volume":"4","author":"Santos","year":"2014","journal-title":"RSC Adv."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1675","DOI":"10.1039\/B920046K","article-title":"Design of functional ionic liquids using magneto- and luminescent-active anions","volume":"12","author":"Yoshida","year":"2010","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_13","doi-asserted-by":"crossref","unstructured":"Lozano, P. (2019). Sustainable Catalysis in Ionic Liquids, CRC Press. [1st ed.].","DOI":"10.1201\/9781315148694"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"3701","DOI":"10.1039\/c0sm01221a","article-title":"Magnetorheological fluids: A review","volume":"7","author":"Klingenberg","year":"2011","journal-title":"Soft Matter"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"1740","DOI":"10.1002\/adma.200700302","article-title":"Magnetorheological Fluids Based on Ionic Liquids","volume":"19","author":"Schubert","year":"2007","journal-title":"Adv. Mater."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"391","DOI":"10.1007\/BF01374488","article-title":"Upon the hydrogen-bonding ability of the H4 and H5 protons of the imidazolium cation","volume":"1","author":"Greenway","year":"1990","journal-title":"Struct. Chem."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"2365","DOI":"10.1246\/bcsj.80.2365","article-title":"Syntheses, Structures, and Properties of a Series of Metal Ion-Containing Dialkylimidazolium Ionic Liquids","volume":"80","author":"Chongmin","year":"2007","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref_18","doi-asserted-by":"crossref","unstructured":"Hitchcock, P.B., Seddon, K.R., and Welton, T. (1993). Hydrogen-bond acceptor abilities of tetrachlorometalate(II) complexes in ionic liquids. J. Chem. Soc. Dalton Trans., 2639\u20132643.","DOI":"10.1039\/dt9930002639"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"1524","DOI":"10.1021\/je800846j","article-title":"Paramagnetic Ionic Liquid 1-Butyl-3-methylimidazolium Tetrabromidocobaltate(II): Activity Coefficients at Infinite Dilution of Organic Solutes and Crystal Structure","volume":"54","author":"Kozlova","year":"2009","journal-title":"J. Chem. Eng. Data"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"m46","DOI":"10.1107\/S0108270104030471","article-title":"3,3\u2032-Dimethyl-1,1\u2032-methylenediimidazolium tetrachlorocobaltate(II)","volume":"61","author":"Zeller","year":"2005","journal-title":"Acta Crystallogr. Sect. C"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"530","DOI":"10.1021\/cm030296i","article-title":"Liquid Crystals of N,N\u2032-Dialkylimidazolium Salts Comprising Palladium(II) and Copper(II) Ions","volume":"16","author":"Lee","year":"2004","journal-title":"Chem. Mater."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"42","DOI":"10.1524\/zkri.220.1.42.58889","article-title":"The crystal structure of a metal-containing ionic liquid: A new octachlorotricuprate(II)","volume":"220","author":"Sun","year":"2005","journal-title":"Z. Krist. Cryst. Mater."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"511","DOI":"10.1016\/j.cattod.2004.09.005","article-title":"Ionic liquid-derived zinc tetrahalide complexes: Structure and application to the coupling reactions of alkylene oxides and CO2","volume":"98","author":"Palgunadi","year":"2004","journal-title":"Catal. Today"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"885","DOI":"10.1002\/ejic.201601250","article-title":"Synthesis, Properties, and Structures of Low-Melting Tetraisocyanatocobaltate(II)-Based Ionic Liquids","volume":"2017","author":"Peppel","year":"2017","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"5461","DOI":"10.1021\/cg2010419","article-title":"Investigations on a Series of Ionic Liquids Containing the [CoIIBr3quin]\u2212 Anion (quin = quinoline)","volume":"11","author":"Peppel","year":"2011","journal-title":"Cryst. Growth Des."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"7116","DOI":"10.1002\/anie.201000709","article-title":"Low-Viscosity Paramagnetic Ionic Liquids with Doubly Charged [Co(NCS)4]2\u2212 Ions","volume":"49","author":"Peppel","year":"2010","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"2439","DOI":"10.1002\/zaac.201000196","article-title":"Salts with the 1,3-Dibutyl-2,4,5-trimethyl-imidazolium Cation: (DBTMIm)X (X = Br, PF6) and (DBTMIm)2[MBr4] (M = Co, Ni)","volume":"636","author":"Peppel","year":"2010","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"482","DOI":"10.1016\/j.poly.2012.08.047","article-title":"Salts with the [NiBr3(L)]\u2212 complex anion (L = 1-methylimidazole, 1-methylbenzimidazole, quinoline, and triphenylphosphane) and low melting points: A comparative study","volume":"52","author":"Peppel","year":"2013","journal-title":"Polyhedron"},{"key":"ref_29","doi-asserted-by":"crossref","unstructured":"Peppel, T., Geppert-Rybczy\u0144ska, M., Neise, C., Kragl, U., and K\u00f6ckerling, M. (2019). Low-Melting Manganese(II)-Based Ionic Liquids: Syntheses, Structures, Properties and Influence of Trace Impurities. Materials, 12.","DOI":"10.3390\/ma12223764"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"x191659","DOI":"10.1107\/S2414314619016596","article-title":"Poly[1-ethyl-3-methylimidazolium [tri-[mu]-isothiocyanato-manganate(II)]]","volume":"4","author":"Peppel","year":"2019","journal-title":"IUCrData"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1314","DOI":"10.1002\/zaac.201100091","article-title":"Synthesis, Properties, and Structures of Salts with the Reineckate Anion, [CrIII(NCS)4(NH3)2]\u2013, and Large Organic Cations","volume":"637","author":"Peppel","year":"2011","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"207","DOI":"10.1134\/S1070328412030098","article-title":"Low-melting salts with the [CrIII(NCS)4(1,10-phenanthroline)]\u2212 complex anion: Syntheses, properties, and structures","volume":"38","author":"Peppel","year":"2012","journal-title":"Russ. J. Coord. Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"982","DOI":"10.1021\/ic502358b","article-title":"Low-Melting Imidazolium-Based Salts with the Paramagnetic Reineckate-Analogue Anion [Cr(NCS)4(bipy)]\u2212 (bipy = 2,2\u2032-Bipyridine): Syntheses, Properties, and Structures","volume":"54","author":"Peppel","year":"2015","journal-title":"Inorg. Chem."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"252","DOI":"10.1039\/QJ8611300252","article-title":"XXII.\u2014Notice of a new ammonio-chrome compound","volume":"13","author":"Morland","year":"1861","journal-title":"Q. J. Chem. Soc. Lond."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"126","DOI":"10.1002\/zaac.18920010111","article-title":"\u00dcber die Rhodanide einiger ammoniakalischer Chromverbindungen","volume":"1","year":"1892","journal-title":"Z. Anorg. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"243","DOI":"10.1002\/zaac.18970150145","article-title":"Beitrag zur Konstitution anorganischer Verbindungen. X. Mitteilung. \u00dcber ammoniakalische Chromsulfocyanverbindungen und Stereoisomerie bei denselben","volume":"15","author":"Werner","year":"1897","journal-title":"Z. Anorg. Chem."},{"key":"ref_37","first-page":"49","article-title":"Chromium (III) complexes anions in the chemical analysis. Anafranile determination","volume":"15","author":"Bratulescu","year":"2007","journal-title":"South. Braz. J. Chem."},{"key":"ref_38","first-page":"438","article-title":"Thiocyanatochromium (III) complexes in chemical analysis. Part 52. Volumetric and spectrophotometric determination of chlorpyramine with tetrathiocyanatodiamine chromates","volume":"45","author":"Ganescu","year":"1990","journal-title":"Pharmazie"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1016\/S0020-1693(96)05343-1","article-title":"Charge transfer photochemistry of Reinecke\u2019s salt and of some of its analogues containing organic amines","volume":"255","author":"Mainusch","year":"1997","journal-title":"Inorg. Chim. Acta"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"394","DOI":"10.1021\/ja00955a003","article-title":"Photochemistry of Complex Ions. III. Absolute Quantum Yields for the Photolysis of Some Aqueous Chromium(III) Complexes. Chemical Actinometry in the Long Wavelength Visible Region","volume":"88","author":"Wegner","year":"1966","journal-title":"J. Am. Chem. Soc."},{"key":"ref_41","first-page":"139","article-title":"Thiocyanatochromium(III) complexes in chemical analysis. 35. Determination of bismuth with thiocyanatochromium(III) complexes","volume":"1","author":"Ganescu","year":"1977","journal-title":"Mikrochim. Acta"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"887","DOI":"10.1002\/ardp.19763091105","article-title":"Thiocyanato-Chrom(III)-Komplexe mit Pilocarpin und die analytische Bestimmung dieses Alkaloids","volume":"309","author":"Brinzan","year":"1976","journal-title":"Arch. Pharm."},{"key":"ref_43","doi-asserted-by":"crossref","unstructured":"Turner, S.S., Le Pevelen, D., Day, P., and Prout, K. (2000). TTF based charge transfer salts of [Cr(NCS)4(phen)]\u2212: Bulk magnetic order and crystal structures of the TTF, TMTTF (tetramethyltetrathiafulvalene) and TMTSF (tetramethyltetraselenafulvalene) derivatives. J. Chem. Soc. Dalton Trans., 2739\u20132744.","DOI":"10.1039\/b004140h"},{"key":"ref_44","unstructured":"(2003). Apex-2, v. 1.6\u20138, Saint, v. 6.25a, SADABS\u2014Software for the CCD Detector System, Bruker-Nonius."},{"key":"ref_45","unstructured":"Sheldrick, G.M. (1996). SADABS. Program for Empirical Absorption Correction, University of G\u00f6ttingen."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","article-title":"A short history of SHELX","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Crystallogr. Sect. A"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"717","DOI":"10.1002\/adsc.200404011","article-title":"Highly Selective Copper-Catalyzed Monoarylation of Aniline","volume":"346","author":"Haider","year":"2004","journal-title":"Adv. Synth. Catal."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"156","DOI":"10.1039\/b103275p","article-title":"Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation","volume":"3","author":"Huddleston","year":"2001","journal-title":"Green Chem."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"3161","DOI":"10.1021\/ol026608p","article-title":"Solvent-Free Sonochemical Preparation of Ionic Liquids","volume":"4","author":"Namboodiri","year":"2002","journal-title":"Org. Lett."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1016\/S0022-1139(02)00322-6","article-title":"Physical and electrochemical properties of 1-alkyl-3-methylimidazolium tetrafluoroborate for electrolyte","volume":"120","author":"Nishida","year":"2003","journal-title":"J. Fluor. Chem."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"6685","DOI":"10.1021\/om200864z","article-title":"Synthesis and Structural Characterization of Half-Sandwich Nickel Complexes Bearing Two Different N-Heterocyclic Carbene Ligands","volume":"30","author":"Oertel","year":"2011","journal-title":"Organometallics"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1002\/jlac.18671410206","article-title":"Ueber einige Chromidschwefelcyanverbindungen","volume":"141","author":"Roesler","year":"1867","journal-title":"Justus Liebigs Ann. Chem."},{"key":"ref_53","first-page":"1374","article-title":"Potassium Hexathiocyanatochromate (III)","volume":"Volume 2","author":"Brauer","year":"1965","journal-title":"Handbook of Preparative Inorganic Chemistry"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"200768","DOI":"10.1107\/S2414314620007683","article-title":"1-Benzyl-3-methylimidazolium bromide","volume":"5","author":"Peppel","year":"2020","journal-title":"IUCrData"},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"2115","DOI":"10.1002\/cber.190603902169","article-title":"Tetrarhodanato-dipyridin-chromsalze","volume":"39","author":"Pfeiffer","year":"1906","journal-title":"Ber. Dtsch. Chem. Ges."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"140","DOI":"10.1002\/zaac.19683570306","article-title":"Neue Substitutionsprodukte von K3[Cr(NCS)6] mit einigen heterocyclischen N-Basen","volume":"357","author":"Ripan","year":"1968","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref_57","unstructured":"Gade, L.H. (2013). Grundlagen der Kristall-\/Ligandenfeldtheorie. Koordinationschemie, Wiley-VCH."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"1625","DOI":"10.1021\/ic50055a003","article-title":"Electronic and infrared spectral study of chromium (III) derivatives of the type [Cr(NCS)4.(ligand)2]","volume":"6","author":"Bennett","year":"1967","journal-title":"Inorg. Chem."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"20327","DOI":"10.1039\/C9CP03296G","article-title":"A coarse-grained model of ionic liquid crystals: The effect of stoichiometry on the stability of the ionic nematic phase","volume":"21","author":"Saielli","year":"2019","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"14982","DOI":"10.1039\/c3dt50974e","article-title":"Synthesis, structure and light scattering properties of tetraalkylammonium metal isothiocyanate salts","volume":"42","author":"Savard","year":"2013","journal-title":"Dalton Trans."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"5990","DOI":"10.1002\/ejic.201402779","article-title":"Synthesis, Characterisation and Modelling of a Ferromagnetically Coupled Chromium(III) Dimer: Di-\u03bc-hydroxobis[tetrakis(isothiocyanato)chromate(III)]","volume":"2014","author":"Morsing","year":"2014","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_62","first-page":"127","article-title":"Preparation and crystal structures of trans-K[Cr(NCS)4py2]\u00b74py and mer-[Cr(NCS)3(\u03b3-pic)3]\u00b74\/3(\u03b3-pic)","volume":"80","author":"Kitanovski","year":"2007","journal-title":"Croat. Chem. Acta"},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1016\/j.poly.2015.07.013","article-title":"New crystal packing arrangements in radical cation salts of BEDT-TTF with [Cr(NCS)6]3\u2212 and [Cr(NCS)5(NH3)]2\u2212","volume":"102","author":"Brooks","year":"2015","journal-title":"Polyhedron"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"o1248","DOI":"10.1107\/S1600536814024301","article-title":"Crystal structure of 1-benzyl-3-methyl-1H-imidazolium hexafluoridophosphate","volume":"70","author":"Hillesheim","year":"2014","journal-title":"Acta Crystallogr. Sect. E"},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"o218","DOI":"10.1107\/S1600536809053306","article-title":"1-Benzyl-3-methylimidazolium chloride 0.25-hydrate","volume":"66","author":"Ji","year":"2010","journal-title":"Acta Crystallogr. Sect. 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