{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T02:51:48Z","timestamp":1760151108935,"version":"build-2065373602"},"reference-count":63,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2022,2,23]],"date-time":"2022-02-23T00:00:00Z","timestamp":1645574400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>This work reports a study on structural, electrical and optical properties of some recently synthesized pyrrolo[1,2-i][1,7] phenanthrolines derivatives in thin films. The thin films were deposited onto glass substrates by spin coating technique, using chloroform as solvent. The obtained films exhibited a polycrystalline structure with an n\u2013type semiconductor behavior after heat treatment in the temperature range 293\u2013543 K, specific to each sample. The thermal activation energy lies between 0.68 and 0.78 eV, while the direct optical band gap values were found in the range 4.17\u20134.24 eV. The electrical and optical properties of the investigated organic semiconductor films were discussed in relation to microstructural properties, determined by the molecular structure. The investigated organic compounds are promising for applications in organic optoelectronics and nanoelectronics.<\/jats:p>","DOI":"10.3390\/ma15051684","type":"journal-article","created":{"date-parts":[[2022,2,23]],"date-time":"2022-02-23T22:54:02Z","timestamp":1645656842000},"page":"1684","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Structural, Electrical and Optical Properties of Pyrrolo[1,2-i][1,7] Phenanthroline-Based Organic Semiconductors"],"prefix":"10.3390","volume":"15","author":[{"given":"Corneliu","family":"Doroftei","sequence":"first","affiliation":[{"name":"Research Center in Environmental Sciences for the North-Eastern Romanian Region (CERNESIM), Science Research Department, Institute of Interdisciplinary Research, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, Nr. 11, 700506 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Aurelian","family":"Carlescu","sequence":"additional","affiliation":[{"name":"Research Center in Environmental Sciences for the North-Eastern Romanian Region (CERNESIM), Science Research Department, Institute of Interdisciplinary Research, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, Nr. 11, 700506 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3155-7007","authenticated-orcid":false,"given":"Liviu","family":"Leontie","sequence":"additional","affiliation":[{"name":"Research Center in Environmental Sciences for the North-Eastern Romanian Region (CERNESIM), Science Research Department, Institute of Interdisciplinary Research, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, Nr. 11, 700506 Iasi, Romania"},{"name":"Faculty of Physics, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, Nr. 11, 700506 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4370-5353","authenticated-orcid":false,"given":"Ramona","family":"Danac","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, Nr. 11, 700506 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9299-1347","authenticated-orcid":false,"given":"Cristina Maria","family":"Al-Matarneh","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, Nr. 11, 700506 Iasi, Romania"},{"name":"Institute of Macromolecular Chemistry \u201cPetru Poni\u201d, Aleea Ghica Voda, No. 41A, 700487 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,2,23]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"012004","DOI":"10.1088\/2053-1591\/ab636f","article-title":"Nanoparticles for organic electronics applications","volume":"7","author":"He","year":"2020","journal-title":"Mater. 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