{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,16]],"date-time":"2026-01-16T14:03:16Z","timestamp":1768572196036,"version":"3.49.0"},"reference-count":27,"publisher":"MDPI AG","issue":"8","license":[{"start":{"date-parts":[[2022,4,7]],"date-time":"2022-04-07T00:00:00Z","timestamp":1649289600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"the Nuclear Material Innovation Foundation of China","award":["Grant no. ICNM-2019-ZN-05"],"award-info":[{"award-number":["Grant no. ICNM-2019-ZN-05"]}]},{"name":"the Nuclear Material Innovation Foundation of China","award":["ICNM-2019-ZH-05"],"award-info":[{"award-number":["ICNM-2019-ZH-05"]}]},{"name":"the Nuclear Material Innovation Foundation of China","award":["Grant no. ICNM-2019-ZH-05"],"award-info":[{"award-number":["Grant no. ICNM-2019-ZH-05"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Selenium (Se) is a key mobile fission product in the geological disposal of nuclear waste. It is necessary to analyze the reductive deposition behavior of iron-based materials to Se(IV) and Se(VI) in groundwater. In the present work, the corrosion behavior of 304 stainless steel in simulated groundwater (SG) and the effects of corrosion products on the dissolution of Se were investigated by electrochemical and immersion tests. Experimental results revealed that passivation films formed on 304 stainless-steel samples were destroyed by polarization measurements, forming corrosion products consisting of Fe(II) compounds, such as Fe3O4 and FeO. Corrosion products deposited on the surface of steel samples previously treated by polarization measurements in SG + CaCl2\/Na2CO3\/Na2SiO3 solutions effectively reduced soluble Se(IV) and Se(VI) during immersion tests, depositing FeSe2 on sample surfaces.<\/jats:p>","DOI":"10.3390\/ma15082705","type":"journal-article","created":{"date-parts":[[2022,4,7]],"date-time":"2022-04-07T21:08:22Z","timestamp":1649365702000},"page":"2705","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Effects of Corrosion Products Deposited on 304 Stainless Steel on Reduction of Se (IV\/VI) in Simulated Groundwater"],"prefix":"10.3390","volume":"15","author":[{"given":"Guokai","family":"Huang","sequence":"first","affiliation":[{"name":"School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Teng","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3635-5930","authenticated-orcid":false,"given":"Xian","family":"Zhang","sequence":"additional","affiliation":[{"name":"Collaborative Innovation Center for Advanced Steels, Wuhan University of Science and Technology, Wuhan 430081, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lingyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daqing","family":"Cui","sequence":"additional","affiliation":[{"name":"Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China"},{"name":"Department of Materials and Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4522-772X","authenticated-orcid":false,"given":"Miao","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,4,7]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"80","DOI":"10.1016\/j.radphyschem.2013.06.033","article-title":"Radiation induced corrosion of copper for spent nuclear fuel storage","volume":"92","author":"Hosseinpour","year":"2013","journal-title":"Radiat. Phys. Chem."},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Li, T., Huang, G., Feng, Y., Yang, M., Wang, L., Cui, D., and Zhang, X. (2020). Effects of different ions and temperature on corrosion behavior of pure iron in anoxic simulated groundwater. Materials, 13.","DOI":"10.3390\/ma13122713"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1016\/j.apradiso.2006.09.009","article-title":"A new determination of 79Se half-life","volume":"65","author":"Bienvenu","year":"2007","journal-title":"Appl. Radiat. Isot."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"20","DOI":"10.1016\/j.jhazmat.2012.12.037","article-title":"Interaction of aqueous Se(IV)\/Se(VI) with FeSe\/FeSe2: Implication to Se redox process","volume":"248\u2013249","author":"Kang","year":"2013","journal-title":"J. Hazard. Mater."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"649","DOI":"10.1515\/ract-2015-2496","article-title":"The influence of pH and reaction time on the formation of FeSe2 upon selenite reduction by nano-sized pyrite-greigite","volume":"104","author":"Kang","year":"2016","journal-title":"Radiochim. Acta"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"2704","DOI":"10.1021\/es1033553","article-title":"Effect of pH on aqueous Se(IV) reduction by pyrite","volume":"45","author":"Kang","year":"2011","journal-title":"Environ. Sci. Technol."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"1106","DOI":"10.1126\/science.278.5340.1106","article-title":"Abiotic selenium redox transformations in the presence of Fe(II,III) oxides","volume":"278","author":"Myneni","year":"1997","journal-title":"Science"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"228","DOI":"10.1016\/j.jconhyd.2008.09.018","article-title":"X-ray absorption and photoelectron spectroscopy investigation of selenite reduction by FeII-bearing minerals","volume":"102","author":"Scheinost","year":"2008","journal-title":"J. Contam. Hydrol."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"1984","DOI":"10.1021\/es071573f","article-title":"Selenite reduction by mackinawite, magnetite and siderite: XAS characterization of nanosized redox products","volume":"42","author":"Scheinost","year":"2008","journal-title":"Environ. Sci. Technol."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"451","DOI":"10.1016\/j.jhazmat.2010.11.017","article-title":"Sorption of selenium(IV) and selenium(VI) to mackinawite (FeS): Effect of contact time, extent of removal, sorption envelopes","volume":"186","author":"Han","year":"2011","journal-title":"J. Hazard. Mater."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"30","DOI":"10.1016\/j.jconhyd.2012.03.003","article-title":"Structure of selenium incorporated in pyrite and mackinawite as determined by XAFS analyses","volume":"133","author":"Diener","year":"2012","journal-title":"J. Contam. Hydrol."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"791","DOI":"10.1524\/ract.2011.1883","article-title":"Synthesis and incorporation of selenide in pyrite and mackinawite","volume":"99","author":"Diener","year":"2011","journal-title":"Radiochim. Acta"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"5376","DOI":"10.1021\/es0704481","article-title":"Interactions of aqueous selenium (-II) and (IV) with metallic sulfide surfaces","volume":"41","author":"Naveau","year":"2007","journal-title":"Environ. Sci. Technol."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"3595","DOI":"10.1021\/es071370r","article-title":"XANES-EXAFS analysis of se solid-phase reaction products formed upon contacting Se(IV) with FeS2 and FeS","volume":"42","author":"Breynaert","year":"2008","journal-title":"Environ. Sci. Technol."},{"key":"ref_15","doi-asserted-by":"crossref","unstructured":"Cui, D., Ranebo, Y., Low, J., Rondinella, V., and Spahiu, K. (2008, January 2\u20134). Immobilization of Radionuclides on Iron Canister Material at Simulated Near-field Conditions. Proceedings of the 2008 MRS Fall Meetin, Boston, MA, USA.","DOI":"10.1557\/PROC-1124-Q02-04"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"108405","DOI":"10.1016\/j.corsci.2019.108405","article-title":"Characterization of the passive properties of 254SMO stainless steel in simulated desulfurized flue gas condensates by electrochemical analysis, XPS and ToF-SIMS","volume":"165","author":"Dou","year":"2020","journal-title":"Corros. Sci."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"12378","DOI":"10.1016\/j.jmrt.2020.08.056","article-title":"Natural passivation behavior and its influence on chloride-induced corrosion resistance of stainless steel in simulated concrete pore solution","volume":"9","author":"Yuan","year":"2020","journal-title":"J. Mater. Res. Technol."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"403","DOI":"10.1016\/j.corsci.2018.08.009","article-title":"Comparative study of the surface oxide films on lean duplex and corresponding single phase stainless steels by XPS and ToF-SIMS","volume":"143","author":"Gardin","year":"2018","journal-title":"Corros. Sci."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1016\/j.matchemphys.2017.04.011","article-title":"Characterization of Desulfovibrio desulfuricans biofilm on high-alloyed stainless steel: XPS and electrochemical studies","volume":"195","author":"Dec","year":"2017","journal-title":"Mater. Chem. Phys."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"108844","DOI":"10.1016\/j.corsci.2020.108844","article-title":"Effect of high temperature on the corrosion behavior and passive film composition of 316 L stainless steel in high H2S-containing environments","volume":"174","author":"Wang","year":"2020","journal-title":"Corros. Sci."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"257","DOI":"10.1016\/S0169-4332(01)00292-6","article-title":"Black spots on carbon steel after contact to lubricating oil with extreme pressure additives: An XPS study","volume":"179","author":"Mayer","year":"2001","journal-title":"Appl. Surf. Sci."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"26921","DOI":"10.1021\/acs.jpcc.9b06774","article-title":"Degradation Mechanism of Methylene Blue by H2O2 and Synthesized Carbon Nanodots\/Graphitic Carbon Nitride\/Fe(II) Composite","volume":"123","author":"Fang","year":"2019","journal-title":"J. Phys. Chem. C"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1016\/j.electacta.2014.02.117","article-title":"Corrosion Inhibition of AA2024-T3 By Sodium Silicate","volume":"130","author":"Frankel","year":"2014","journal-title":"Electrochim. Acta"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1016\/j.corsci.2018.04.035","article-title":"Effect of silicate-based films on the corrosion behavior of the API 5L X80 pipeline steel","volume":"139","author":"Correa","year":"2018","journal-title":"Corros. Sci."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"1079","DOI":"10.3390\/catal5031079","article-title":"Microwave synthesis of high activity FeSe2\/C catalyst toward oxygen reduction reaction","volume":"5","author":"Zheng","year":"2015","journal-title":"Catalysts"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"885","DOI":"10.1016\/j.jnoncrysol.2011.12.080","article-title":"Fine-grained amorphous calcium silicate CaSiO3 from vacuum dried sol-gel-Production, characterisation and thermal behaviour","volume":"358","author":"Thompson","year":"2012","journal-title":"J. Non. Cryst. Solids"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"114","DOI":"10.1016\/j.corsci.2015.09.025","article-title":"Effects of alloyed Cr and Cu on the corrosion behavior of low-alloy steel in a simulated groundwater solution","volume":"102","author":"Xu","year":"2016","journal-title":"Corros. Sci."}],"container-title":["Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1944\/15\/8\/2705\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T22:49:32Z","timestamp":1760136572000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1944\/15\/8\/2705"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,4,7]]},"references-count":27,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2022,4]]}},"alternative-id":["ma15082705"],"URL":"https:\/\/doi.org\/10.3390\/ma15082705","relation":{},"ISSN":["1996-1944"],"issn-type":[{"value":"1996-1944","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,4,7]]}}}