{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,2]],"date-time":"2026-06-02T02:14:24Z","timestamp":1780366464363,"version":"3.54.1"},"reference-count":27,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2022,6,15]],"date-time":"2022-06-15T00:00:00Z","timestamp":1655251200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52002379"],"award-info":[{"award-number":["52002379"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology&amp; Engineering, Chinese Academy of Sciences","award":["52002379"],"award-info":[{"award-number":["52002379"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>In this study, the joining of silicon carbide (SiC) ceramics was achieved via a Si\u2013C reaction bonding method using the phenolic resin (PF)\u2013MgCl2 system as the carbon precursor. Specifically, by adding MgCl2 to the phenolic resin mixture, the average pore size of the product of carbonization of the PF resin mixture increased from 14 \u00b1 5 nm to 524 \u00b1 21 nm, which was beneficial for the infiltration of molten silicon at high temperature. The microstructure of the joined specimens and the effect of the inert filler on the joint strength were investigated. It was demonstrated that SiC\u2013SiC joints with strong interfacial bonding and high flexural strength could be obtained by the Si\u2013C reaction bonding method using a phenol formaldehyde resin\/alcohol sol-gel system as the carbon precursor. The flexural strength of the joined specimens reached the highest value, i.e., 308 \u00b1 27 MPa when the solid loading of the inert filler was 26%. Overall, stable joining of silicon carbide ceramics was achieved by the proposed method, which has significance for realizing the preparation of complex-shaped or large silicon carbide ceramic parts.<\/jats:p>","DOI":"10.3390\/ma15124242","type":"journal-article","created":{"date-parts":[[2022,6,16]],"date-time":"2022-06-16T03:01:22Z","timestamp":1655348482000},"page":"4242","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Joining of SiC Ceramic by Si\u2013C Reaction Bonding Using Organic Resin as Carbon Precursor"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3545-4972","authenticated-orcid":false,"given":"Xishi","family":"Wu","sequence":"first","affiliation":[{"name":"Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China"},{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qing","family":"Huang","sequence":"additional","affiliation":[{"name":"Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunzhou","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengren","family":"Huang","sequence":"additional","affiliation":[{"name":"Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China"},{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,6,15]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Camarano, A., Giuranno, D., and Narciso, J. (2019). SiC-IrSi3 for high oxidation resistance. Materials, 13.","DOI":"10.3390\/ma13010098"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"159297","DOI":"10.1016\/j.jallcom.2021.159297","article-title":"In-situ fabrication of lightweight SiC (Al, rGO) bulk ceramics derived from silicon oxycarbide for aerospace components","volume":"869","author":"Li","year":"2021","journal-title":"J. Alloys Compd."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"153155","DOI":"10.1016\/j.jnucmat.2021.153155","article-title":"Impact of nuclear environment on hydrothermal corrosion and silica transport for CVD SiC in light water reactors","volume":"556","author":"Seshadri","year":"2021","journal-title":"J. Nucl. Mater."},{"key":"ref_4","doi-asserted-by":"crossref","unstructured":"Ge, S., Yao, X., Liu, Y., Duan, H., Huang, Z., and Liu, X. (2020). Effect of Sintering Temperature on the Properties of Highly Electrical Resistive SiC Ceramics as a Function of Y2O3-Er2O3 Additions. Materials, 13.","DOI":"10.3390\/ma13214768"},{"key":"ref_5","doi-asserted-by":"crossref","unstructured":"Xia, X., Deng, J., Kou, S., Luan, C., Fan, S., Wang, P., Cheng, L., and Zhang, L. (2022). Microstructure and properties of pressure-less joining of SiCf\/SiC composites by Ti\u2013Si alloys. Ceram. Int.","DOI":"10.1016\/j.ceramint.2022.04.245"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"3727","DOI":"10.1016\/j.jeurceramsoc.2018.04.025","article-title":"Wetting of SiC by Al-Ti alloys and joining by in-situ formation of interfacial Ti3Si (Al) C2","volume":"38","author":"Valenza","year":"2018","journal-title":"J. Eur. Ceram. Soc."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"122","DOI":"10.1080\/10426914.2014.952019","article-title":"Silicon Carbide Diffusion Bonding by Spark Plasma Sintering","volume":"30","author":"Aroshas","year":"2015","journal-title":"Mater. Manuf. Processes"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"12559","DOI":"10.1016\/j.ceramint.2020.02.018","article-title":"Preparation and microstructure characterization of SiC\/SiC joints reinforced by in-situ SiC nanowires","volume":"46","author":"Tang","year":"2020","journal-title":"Ceram. Int."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"150951","DOI":"10.1016\/j.apsusc.2021.150951","article-title":"Wetting and joining of surface-oxidized SiC ceramic with calcium lithium aluminosilicate glass filler","volume":"568","author":"Fang","year":"2021","journal-title":"Appl. Surf. Sci."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"109799","DOI":"10.1016\/j.matchar.2019.109799","article-title":"Joining of the Cf\/SiC composites by a one-step Si infiltration reaction bonding","volume":"155","author":"Wu","year":"2019","journal-title":"Mater. Charact."},{"key":"ref_11","first-page":"89","article-title":"Ceramic joining technology","volume":"154","author":"Singh","year":"1998","journal-title":"Adv. Mater. Processes"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"5781","DOI":"10.1023\/A:1004489712447","article-title":"Microstructure and mechanical properties of reaction-formed joints in reaction-bonded silicon carbide ceramics","volume":"33","author":"Singh","year":"1998","journal-title":"J. Mater. Sci."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"747","DOI":"10.1016\/j.msea.2006.12.181","article-title":"Reaction forming of joints in silicon carbide ceramic materials","volume":"483\u2013484","author":"Li","year":"2008","journal-title":"Mater. Sci. Eng. a-Struct. Mater. Prop. Microstruct. Process."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1016\/j.msea.2011.10.026","article-title":"Joining of SiC with Si infiltrated tape-cast TiB2-C interlayer: Effect of interlayer composition and thickness on the microstructure and mechanical properties","volume":"530","author":"Tian","year":"2011","journal-title":"Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"3819","DOI":"10.1016\/j.jeurceramsoc.2012.04.049","article-title":"Development of SiC-SiC joint by reaction bonding method using SiC\/C tapes as the interlayer","volume":"32","author":"Luo","year":"2012","journal-title":"J. Eur. Ceram. Soc."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"2641","DOI":"10.1016\/S0955-2219(00)00156-4","article-title":"Interfacial and thermomechanical characterization of reaction formed joints in silicon carbide-based materials","volume":"20","author":"Singh","year":"2000","journal-title":"J. Eur. Ceram. Soc."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"1258","DOI":"10.1016\/S0022-3115(00)00247-6","article-title":"Joining of silicon carbide composites for fusion energy applications","volume":"283","author":"Lewinsohn","year":"2000","journal-title":"J. Nucl. Mater."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"459","DOI":"10.1023\/A:1006568124914","article-title":"Joining of sintered silicon carbide ceramics for high-temperature applications","volume":"17","author":"Singh","year":"1998","journal-title":"J. Mater. Sci. Lett."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"7873","DOI":"10.1016\/j.ceramint.2013.12.134","article-title":"Gelcasting of silicon carbide ceramics using phenolic resin and furfuryl alcohol as the gel former","volume":"40","author":"Zhang","year":"2014","journal-title":"Ceram. Int."},{"key":"ref_20","first-page":"3447","article-title":"Kinetics of the metal-catalyzed condensations of phenols and polyelavonoid tannins with formaldehyde","volume":"18","author":"Pizzi","year":"1980","journal-title":"J. Polym. Sci."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"833","DOI":"10.1163\/156856107781061503","article-title":"Cure rate of Phenol\u2013Formaldehyde (PF) resol resins catalyzed with MgO","volume":"21","author":"Zhang","year":"2007","journal-title":"J. Adhes. Sci. Technol."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"2103","DOI":"10.1016\/j.carbon.2009.03.069","article-title":"Pore structure control of mesoporous carbon monoliths derived from mixtures of phenolic resin and ethylene glycol","volume":"47","author":"Xu","year":"2009","journal-title":"Carbon"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"4105","DOI":"10.1016\/j.jnucmat.2008.02.020","article-title":"Joining of machined Sic\/Sic composites for thermonuclear fusion reactors","volume":"375","author":"Ferraris","year":"2008","journal-title":"J. Nucl. Mater."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"5007","DOI":"10.1023\/A:1004411108502","article-title":"Joining of silicon carbide using MgO\u2013Al2O3\u2013SiO2 filler","volume":"33","author":"Lee","year":"1998","journal-title":"J. Mater. Sci."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1016\/0272-8842(87)90039-3","article-title":"Mechanism of reactions in the Si+Cf system and the self-propagating high-temperature synthesis of silicon carbide","volume":"13","author":"Pampuch","year":"1987","journal-title":"Ceram. Int."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1377","DOI":"10.1007\/BF00553278","article-title":"Microstructural evolution in reaction-bonded silicon carbide","volume":"21","author":"Ness","year":"1986","journal-title":"J. Mater. Sci."},{"key":"ref_27","first-page":"298","article-title":"Joining of 3D-Cf\/SiC composites via silicone resin as precursor Influence of pyrolysis temperature and inert fillers","volume":"34","author":"Suo","year":"2005","journal-title":"Rare Met. Mater. 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