{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T19:42:09Z","timestamp":1784144529806,"version":"3.55.0"},"reference-count":44,"publisher":"MDPI AG","issue":"20","license":[{"start":{"date-parts":[[2022,10,17]],"date-time":"2022-10-17T00:00:00Z","timestamp":1665964800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"the National Natural Science Foundation of China","award":["21925112"],"award-info":[{"award-number":["21925112"]}]},{"name":"the National Natural Science Foundation of China","award":["22090021"],"award-info":[{"award-number":["22090021"]}]},{"name":"the National Natural Science Foundation of China","award":["21872154"],"award-info":[{"award-number":["21872154"]}]},{"name":"the National Natural Science Foundation of China","award":["2191003"],"award-info":[{"award-number":["2191003"]}]},{"name":"the Beijing Natural Science Foundation","award":["21925112"],"award-info":[{"award-number":["21925112"]}]},{"name":"the Beijing Natural Science Foundation","award":["22090021"],"award-info":[{"award-number":["22090021"]}]},{"name":"the Beijing Natural Science Foundation","award":["21872154"],"award-info":[{"award-number":["21872154"]}]},{"name":"the Beijing Natural Science Foundation","award":["2191003"],"award-info":[{"award-number":["2191003"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Crystalline materials with appealing luminescent properties are attractive materials for various optoelectronic applications. The in situ bicomponent reaction of 1,2-ethylenedisulfonic acid with 1,4-di(pyrid-2-yl)benzene, 1,4-di(pyrid-3-yl)benzene, or 1,4-di(pyrid-4-yl)benzene affords luminescent crystals with hydrogen-bonded polymeric structures. Variations in the positions of the pyridine nitrogen atoms lead to alternating polymeric structures with either a ladder- or zigzag-type of molecular arrangement. By using a nanoprecipitation method, microcrystals of these polymeric structures are prepared, showing polarized luminescence with a moderate degree of polarization.<\/jats:p>","DOI":"10.3390\/ma15207247","type":"journal-article","created":{"date-parts":[[2022,10,17]],"date-time":"2022-10-17T21:11:51Z","timestamp":1666041111000},"page":"7247","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Molecular Cocrystals with Hydrogen-Bonded Polymeric Structures and Polarized Luminescence"],"prefix":"10.3390","volume":"15","author":[{"given":"Jing-Yi","family":"Zhao","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, CAS Research\/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9005-4894","authenticated-orcid":false,"given":"Fa-Feng","family":"Xu","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, CAS Research\/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0979-6936","authenticated-orcid":false,"given":"Zhong-Qiu","family":"Li","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, CAS Research\/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhong-Liang","family":"Gong","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, CAS Research\/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0712-0374","authenticated-orcid":false,"given":"Yu-Wu","family":"Zhong","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, CAS Research\/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiannian","family":"Yao","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, CAS Research\/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,10,17]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"408","DOI":"10.1007\/s11426-021-1130-9","article-title":"Three-primary-color molecular cocrystals showing white-light luminescence, tunable optical waveguide and ultrahigh polarized emission","volume":"65","author":"Li","year":"2022","journal-title":"Sci. China Chem."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"4647","DOI":"10.1021\/acs.nanolett.8b00347","article-title":"Anisotropic Photoluminescence from Isotropic Optical Transition Dipoles in Semiconductor Nanoplatelets","volume":"18","author":"Ma","year":"2018","journal-title":"Nano Lett."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"6157","DOI":"10.1021\/jacs.9b02055","article-title":"Photoluminescent Anisotropy Amplification in Polymorphic Organic Nanocrystals by Light-Harvesting Energy Transfer","volume":"141","author":"Sun","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"e202205033","DOI":"10.1002\/anie.202205033","article-title":"Selective, Anisotropic, or Consistent Polarized-Photon Out-Coupling of 2D Organic Microcrystals","volume":"61","author":"Li","year":"2022","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"2060","DOI":"10.1007\/s11426-021-1146-6","article-title":"Frontiers in Circularly Polarized Luminescence: Molecular Design, Self-Assembly, Nanomaterials, and Applications","volume":"64","author":"Gong","year":"2021","journal-title":"Sci. China Chem."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"1900110","DOI":"10.1002\/adma.201900110","article-title":"Circularly Polarized Luminescence in Nanoassemblies: Generation, Amplification, and Application","volume":"32","author":"Sang","year":"2020","journal-title":"Adv. Mater."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"15755","DOI":"10.1021\/jacs.9b08780","article-title":"Circularly Polarized Luminescence from Achiral Single Crystals of Hybrid Manganese Halides","volume":"141","author":"Zhao","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"250","DOI":"10.31635\/ccschem.021.202000768","article-title":"An Optically Reconfigurable F\u00f6rster Resonance Energy Transfer Process for Broadband Switchable Organic Single-Mode Microlasers","volume":"4","author":"Qiao","year":"2022","journal-title":"CCS Chem."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"1691","DOI":"10.1021\/acs.accounts.6b00209","article-title":"Organic Micro\/Nanoscale Lasers","volume":"49","author":"Zhang","year":"2016","journal-title":"Acc. Chem. Res."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"328","DOI":"10.1007\/s11426-021-1129-0","article-title":"A Pre-Organized Monomer-Reservoir Strategy to Prepare Multidimensional Phosphorescent Organoplatinum Nanocrystals and Suprastructures","volume":"65","author":"Li","year":"2022","journal-title":"Sci. China Chem."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"4325","DOI":"10.1039\/C4CS00098F","article-title":"Organic Nanophotonics: From Controllable Assembly of Functional Molecules to Low-Dimensional Materials with Desired Photonic Properties","volume":"43","author":"Yan","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"740","DOI":"10.1007\/s11426-021-1214-8","article-title":"Organic white-light sources: Multiscale construction of organic luminescent materials from molecular to macroscopic level","volume":"65","author":"Chen","year":"2022","journal-title":"Sci. China Chem."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"14399","DOI":"10.1021\/jacs.0c06473","article-title":"Hydrogen-Bonded Organic Frameworks as a Tunable Platform for Functional Materials","volume":"142","author":"Wang","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"1613","DOI":"10.1007\/s40843-020-1386-7","article-title":"Organic Halogen-Bonded Co-crystals for Optoelectronic Applications","volume":"63","author":"Chen","year":"2020","journal-title":"Sci. China Mater."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"8435","DOI":"10.1021\/acs.chemrev.8b00770","article-title":"Main-Group-Based Electro- and Photoactive Chiral Materials","volume":"119","author":"Pop","year":"2019","journal-title":"Chem. Rev."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"14595","DOI":"10.1002\/anie.202103091","article-title":"Full-Color and White Circularly Polarized Luminescence of Hydrogen-Bonded Ionic Organic Microcrystals","volume":"60","author":"Li","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"467","DOI":"10.1016\/j.dyepig.2017.07.043","article-title":"Photophysical Properties of Acid-Responsive Triphenylamine Derivatives Bearing Pyridine Fragments: Towards White Light Emission","volume":"146","author":"Tydlitat","year":"2017","journal-title":"Dyes Pigment."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"545","DOI":"10.1007\/s11426-017-9202-5","article-title":"Triarylamines with Branched Multi-Pyridine Groups: Modulation of Emission Properties by Structural Variation, Solvents, and Tris(pentafluorophenyl)borane","volume":"61","author":"Li","year":"2018","journal-title":"Sci. China Chem."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"7374","DOI":"10.1039\/C4CC01012D","article-title":"An AIE-active Luminophore with Tunable and Remarkable Fluorescence Switching Based on the Piezo and Protonation-Deprotonation Control","volume":"50","author":"Ma","year":"2014","journal-title":"Chem. Commun."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"179","DOI":"10.1021\/cg200920d","article-title":"Acid-Stimuli-Luminescence and Carbonyl-Proton Interaction Dependent Emission Properties of 2,6-Biphenyl-4-pyrone Crystals","volume":"12","author":"Zhou","year":"2012","journal-title":"Cryst. Growth Des."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"3878","DOI":"10.1039\/c3cc41171k","article-title":"Remarkable Fluorescence Change Based on the Protonation-Deprotonation Control in Organic Crystals","volume":"49","author":"Zhang","year":"2013","journal-title":"Chem. Commun."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"3068","DOI":"10.1021\/acs.jpclett.7b01454","article-title":"Direct Observation of the Symmetrical and Asymmetrical Protonation States in Molecular Crystals","volume":"8","author":"Ma","year":"2017","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"212","DOI":"10.1007\/s11426-018-9366-7","article-title":"A Cyanostilbene-Based Molecule with Aggregation-Induced Emission Properties: Amplified Spontaneous Emission, Protonation Effect and Electroluminescence","volume":"62","author":"Dong","year":"2019","journal-title":"Sci. China Chem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"8847","DOI":"10.1039\/C9TC02524C","article-title":"Salt-Cocrystal Continuum for Photofunction Modulation: Stimuli-Responsive Fluorescence Color-Tuning of Pyridine-Modified Intramolecular Charge-Transfer Dyes and Acid Complexes","volume":"7","author":"Yano","year":"2019","journal-title":"J. Mater. Chem. C"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"436","DOI":"10.1021\/jacs.6b11057","article-title":"Halogen-Assisted Piezochromic Supramolecular Assemblies for Versatile Haptic Memory","volume":"139","author":"Bai","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"9946","DOI":"10.1021\/jacs.9b03502","article-title":"Occurrence of Chiral Nanostructures Induced by Multiple Hydrogen Bonds","volume":"141","author":"Xing","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"7831","DOI":"10.1002\/anie.201703439","article-title":"Intermolecular Charge-Transfer Interactions Facilitate Two-Photon Absorption in Styrylpyridine\u2013Tetracyanobenzene Cocrystals","volume":"56","author":"Sun","year":"2017","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"22623","DOI":"10.1002\/anie.202009714","article-title":"Manipulating Light-Induced Dynamic Macro-Movement and Static Photonic Properties within 1D Isostructural Hydrogen-Bonded Molecular Cocrystals","volume":"59","author":"Li","year":"2020","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"277","DOI":"10.4172\/pharmaceutical-sciences.1000226","article-title":"Solubility Enhancement of Lornoxicam by Crystal Engineering","volume":"79","author":"Gadade","year":"2017","journal-title":"Indian J. Pharm. Sci."},{"key":"ref_30","first-page":"60","article-title":"Accidental Formation of Eutectics during Crystal Engineering of Lamotrigine with Solubility Advantage and Drug Release Efficiency","volume":"15","author":"Pekamwar","year":"2021","journal-title":"Asian J. Pharm."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"54","DOI":"10.53879\/id.58.08.12691","article-title":"Development and Evaluation of Bicomponent Cocrystals of Aceclofenac for Efficient Drug Delivery with Enhanced Solubility and Improved Dissolution","volume":"58","author":"Pekamwar","year":"2021","journal-title":"Indian Drugs"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"556","DOI":"10.1021\/jo0162484","article-title":"Recurrence of Carboxylic Acid-Pyridine Supramolecular Synthon in the Crystal Structures of Some Pyrazinecarboxylic Acids","volume":"67","author":"Vishweshwar","year":"2002","journal-title":"J. Org. Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"547","DOI":"10.1021\/cg034047i","article-title":"Cocrystals of 1,3,5-Cyclohexanetricaboxylic Acid with 4,4\u2019-Bipyridine Homologues: Acid\u2219Pyridine Hydrogen Bonding in Neutral and Ionic Complexes","volume":"3","author":"Bhogala","year":"2003","journal-title":"Cryst. Growth Des."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"3591","DOI":"10.1039\/C5CE00102A","article-title":"Co-crystals and molecular salts of carboxylic acid\/pyridine complexes: Can calculated pKa\u2019s predict proton transfer? A case study of nine complexes","volume":"17","author":"Lemmerer","year":"2015","journal-title":"Cryst. Eng. Comm."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"2881","DOI":"10.1021\/cg9001994","article-title":"Salt or Cocrystal? A New Series of Crystal Structures Formed from Simple Pyridines and Carboxylic Acids","volume":"9","author":"Mohamed","year":"2009","journal-title":"Cryst. Growth Des."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"644","DOI":"10.1002\/chem.201604133","article-title":"Selective Host-Guest Co-crystallization of Pyridine-Functionalized Tetraphenylethylenes with Phthalic Acids and Multicolor Emission of the Co-Crystals","volume":"23","author":"Feng","year":"2017","journal-title":"Chem. Eur. J."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"1590","DOI":"10.1021\/ic202295b","article-title":"Charge Delocalization of 1,4-Benzenedicyclometalated Ruthenium: A Comparison between Tris-bidentate and Bis-tridentate Complexes","volume":"51","author":"Sui","year":"2012","journal-title":"Inorg. Chem."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"e202201823","DOI":"10.1002\/anie.202201823","article-title":"LiBF4-Induced Rearrangement and Desymmetrization of a Palladium-Ligand Assembly","volume":"61","author":"Sudan","year":"2022","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"4456","DOI":"10.1002\/anie.201913441","article-title":"Orientation-Controlled 2D Anisotropic and Isotropic Photon Transport in Co-crystal Polymorph Microplates","volume":"59","author":"Liu","year":"2020","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"11300","DOI":"10.1002\/anie.201806149","article-title":"2D Organic Photonics: An Asymmetric Optical Waveguide in Self-Assembled Halogen-Bonded Cocrystals","volume":"57","author":"Zhuo","year":"2018","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"e202116603","DOI":"10.1002\/anie.202116603","article-title":"Organoplatinum(II) Cruciform: A Versatile Building Block to Fabricate 2D Microcrystals with Full-Color and White Phosphorescence and Anisotropic Photon Transport","volume":"61","author":"Xu","year":"2022","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"11288","DOI":"10.1021\/acs.jpclett.1c03409","article-title":"Highly Polarized Upconversion Emissions from Lanthanide-Doped LiYF4 Crystals as Spatial Orientation Indicators","volume":"12","author":"Lyu","year":"2021","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1103\/PhysRevB.37.785","article-title":"Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density","volume":"37","author":"Lee","year":"1988","journal-title":"Phys. Rev. B Condens. Matter Mater. Phys."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"3763","DOI":"10.1021\/acsphotonics.8b00815","article-title":"Organic Nanophotonics: Self-Assembled Single-Crystalline Homo-\/Heterostructures for Optical Waveguides","volume":"5","author":"Li","year":"2018","journal-title":"ACS Photonics"}],"container-title":["Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1944\/15\/20\/7247\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T00:55:49Z","timestamp":1760144149000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1944\/15\/20\/7247"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,10,17]]},"references-count":44,"journal-issue":{"issue":"20","published-online":{"date-parts":[[2022,10]]}},"alternative-id":["ma15207247"],"URL":"https:\/\/doi.org\/10.3390\/ma15207247","relation":{},"ISSN":["1996-1944"],"issn-type":[{"value":"1996-1944","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,10,17]]}}}