{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,3]],"date-time":"2026-06-03T22:23:02Z","timestamp":1780525382992,"version":"3.54.1"},"reference-count":63,"publisher":"MDPI AG","issue":"23","license":[{"start":{"date-parts":[[2022,11,25]],"date-time":"2022-11-25T00:00:00Z","timestamp":1669334400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Russian Science Foundation","award":["22-13-00406"],"award-info":[{"award-number":["22-13-00406"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Chlorine- and nitrogen-containing carbon nanofibers (CNFs) were obtained by combined catalytic pyrolysis of trichloroethylene (C2HCl3) and acetonitrile (CH3CN). Their efficiency in the adsorption of 1,2-dichlorobenzene (1,2-DCB) from water has been studied. The synthesis of CNFs was carried out over self-dispersing nickel catalyst at 600 \u00b0C. The produced CNFs possess a well-defined segmented structure, high specific surface area (~300 m2\/g) and high porosity (0.5\u20130.7 cm3\/g). The addition of CH3CN into the reaction mixture allows the introduction of nitrogen into the CNF structure and increases the volume of mesopores. As a result, the capacity of CNF towards adsorption of 1,2-DCB from its aqueous solution increased from 0.41 to 0.57 cm3\/g. Regardless of the presence of N, the CNF samples exhibited a degree of 1,2-DCB adsorption from water\u2013organic emulsion exceeding 90%. The adsorption process was shown to be well described by the Dubinin\u2013Astakhov equation. The regeneration of the used CNF adsorbent through liquid-phase hydrodechlorination was also investigated. For this purpose, Pd nanoparticles (1.5 wt%) were deposited on the CNF surface to form the adsorbent with catalytic function. The presence of palladium was found to have a slight effect on the adsorption capacity of CNF. Further regeneration of the adsorbent-catalyst via hydrodechlorination of adsorbed 1,2-DCB was completed within 1 h with 100% conversion. The repeated use of regenerated adsorbent-catalysts for purification of solutions after the first cycle of adsorption ensures almost complete removal of 1,2-DCB.<\/jats:p>","DOI":"10.3390\/ma15238414","type":"journal-article","created":{"date-parts":[[2022,11,28]],"date-time":"2022-11-28T07:38:49Z","timestamp":1669621129000},"page":"8414","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Synthesis of Chlorine- and Nitrogen-Containing Carbon Nanofibers for Water Purification from Chloroaromatic Compounds"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4747-6714","authenticated-orcid":false,"given":"Anna M.","family":"Ozerova","sequence":"first","affiliation":[{"name":"Boreskov Institute of Catalysis SB RAS, Lavrentieva Av. 5, 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arina R.","family":"Potylitsyna","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis SB RAS, Lavrentieva Av. 5, 630090 Novosibirsk, Russia"},{"name":"Department of Natural Sciences, Novosibirsk State University, Pirogova Str. 2, 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1835-1901","authenticated-orcid":false,"given":"Yury I.","family":"Bauman","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis SB RAS, Lavrentieva Av. 5, 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elena S.","family":"Tayban","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis SB RAS, Lavrentieva Av. 5, 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Inna L.","family":"Lipatnikova","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis SB RAS, Lavrentieva Av. 5, 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8008-3613","authenticated-orcid":false,"given":"Anna V.","family":"Nartova","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis SB RAS, Lavrentieva Av. 5, 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6930-936X","authenticated-orcid":false,"given":"Aleksey A.","family":"Vedyagin","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis SB RAS, Lavrentieva Av. 5, 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1738-128X","authenticated-orcid":false,"given":"Ilya V.","family":"Mishakov","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis SB RAS, Lavrentieva Av. 5, 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4029-2338","authenticated-orcid":false,"given":"Yury V.","family":"Shubin","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva Av. 3, 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2323-7372","authenticated-orcid":false,"given":"Olga V.","family":"Netskina","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis SB RAS, Lavrentieva Av. 5, 630090 Novosibirsk, Russia"},{"name":"Department of Natural Sciences, Novosibirsk State University, Pirogova Str. 2, 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1016\/j.envint.2014.06.013","article-title":"Chlorinated volatile organic compounds (Cl-VOCs) in environment\u2014Sources, potential human health impacts, and current remediation technologies","volume":"71","author":"Huang","year":"2014","journal-title":"Environ. 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