{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T09:32:30Z","timestamp":1789032750052,"version":"build-2803163510"},"reference-count":47,"publisher":"MDPI AG","issue":"4","license":[{"start":{"date-parts":[[2023,2,9]],"date-time":"2023-02-09T00:00:00Z","timestamp":1675900800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004281","name":"National Science Centre","doi-asserted-by":"publisher","award":["2020\/39\/B\/NZ9\/01694"],"award-info":[{"award-number":["2020\/39\/B\/NZ9\/01694"]}],"id":[{"id":"10.13039\/501100004281","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004281","name":"National Science Centre","doi-asserted-by":"publisher","award":["UMO-2020\/39\/B\/NZ9\/01694"],"award-info":[{"award-number":["UMO-2020\/39\/B\/NZ9\/01694"]}],"id":[{"id":"10.13039\/501100004281","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>The procedures of putrescine, spermine, spermidine, and cadaverine derivatization using 2-chloro-1,3-dinitro-5-(trifluoromethyl)benzene, 1-fluoro-2-nitro-4-(trifluoromethyl) benzene, and 3,5-bis-(trifluoromethyl)phenyl isothiocyanate for chromatographic determination in home-made wine samples are compared in the present study. The procedures discussed were compared regarding simplicity, linearity, precision, and accuracy. The polyamines derivatives were isolated and characterized by X-ray crystallography and 1H, 13C, and 19F NMR spectroscopy. The obtained structures of aliphatic amines showed that all amino groups, four in spermine, two in putrescine and cadaverine, and three in spermidine, regardless of the applied reagent, were substituted. The applicability of the described procedures was tested during the chromatographic analysis of the compounds\u2019 content in home-made wines. For this purpose, a simple and environmentally friendly sample preparation procedure was developed. The obtained results present the derivatization of polyamines with 1-fluoro-2-nitro-4-(trifluoromethyl)benzene as a better choice for the determination of these compounds in food samples.<\/jats:p>","DOI":"10.3390\/ma16041474","type":"journal-article","created":{"date-parts":[[2023,2,10]],"date-time":"2023-02-10T01:35:29Z","timestamp":1675992929000},"page":"1474","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["The Selection of the Best Derivatization Reagents for the Determination of Polyamines in Home-Made Wine Samples"],"prefix":"10.3390","volume":"16","author":[{"given":"Anna","family":"Kmieciak","sequence":"first","affiliation":[{"name":"Department of Organic Chemistry, Faculty of Chemistry, Nicolaus Copernicus University in Toru\u0144, Gagarin 7 Str., 87-100 Toru\u0144, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5004-0161","authenticated-orcid":false,"given":"Aneta","family":"Jastrz\u0119bska","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry and Applied Spectroscopy, Faculty of Chemistry, Nicolaus Copernicus University in Toru\u0144, Gagarin 7 Str., 87-100 Toru\u0144, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Karolina","family":"Szyma\u0144ska","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry and Applied Spectroscopy, Faculty of Chemistry, Nicolaus Copernicus University in Toru\u0144, Gagarin 7 Str., 87-100 Toru\u0144, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4337-5676","authenticated-orcid":false,"given":"Marek P.","family":"Krzemi\u0144ski","sequence":"additional","affiliation":[{"name":"Department of Organic Chemistry, Faculty of Chemistry, Nicolaus Copernicus University in Toru\u0144, Gagarin 7 Str., 87-100 Toru\u0144, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5220-4430","authenticated-orcid":false,"given":"Tadeusz M.","family":"Muzio\u0142","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Coordination Chemistry, Faculty of Chemistry, Nicolaus Copernicus University in Toru\u0144, Gagarin 7 Str., 87-100 Toru\u0144, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marzanna","family":"Kurzawa","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry and Applied Spectroscopy, Faculty of Chemistry, Nicolaus Copernicus University in Toru\u0144, Gagarin 7 Str., 87-100 Toru\u0144, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2816-2303","authenticated-orcid":false,"given":"Edward","family":"Sz\u0142yk","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry and Applied Spectroscopy, Faculty of Chemistry, Nicolaus Copernicus University in Toru\u0144, Gagarin 7 Str., 87-100 Toru\u0144, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,2,9]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1016\/j.foodchem.2014.03.102","article-title":"Health effects and occurrence of dietary polyamines: A review for the period 2005\u2013mid 2013","volume":"161","year":"2014","journal-title":"Food Chem."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1695","DOI":"10.1007\/s00726-021-03079-4","article-title":"Activation of whole body by high levels of polyamine intake in rats","volume":"53","author":"Teratani","year":"2021","journal-title":"Amino Acids"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"176","DOI":"10.1016\/j.jchromb.2015.08.036","article-title":"Determination of putrescine, cadaverine, spermidine and spermine in different chemical matrices by high performance liquid chromatography\u2013electrospray ionization\u2013ion trap tandem mass spectrometry (HPLC\u2013ESI\u2013ITMS\/MS)","volume":"1002","author":"Ibarra","year":"2015","journal-title":"J. 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