{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T05:26:09Z","timestamp":1790141169099,"version":"4.0.1"},"reference-count":171,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2023,8,10]],"date-time":"2023-08-10T00:00:00Z","timestamp":1691625600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Corrosion inhibitors represent one of the most commonly used methods for significantly reducing the corrosion rate of metals and alloys. Adsorption inhibitors have a wide range of applications in cooling water systems, deicing solutions for aircrafts, airports and ways, etching and degreasing solutions, oil pipelines, paints and coatings and metal processing solutions. Adsorption corrosion inhibitors of metals and alloys are generally organic compounds that contain structures with heteroatoms (N, P, S, As, O) in their molecules, having lone pair electrons or \u03c0 electrons in aromatic rings or multiple bonds. They enable relatively strong interactions between the metal atoms and organic molecules, resulting in a protective layer of organic molecules adsorbed at the metal\u2013corrosive solution interface. Most molecules of active substances from drugs contain similar structures, which is why many drugs have been already tested as corrosion inhibitors. One of the major disadvantages of using drugs for this purpose is their particularly high price. To overcome this impediment, the possibility of using expired drugs as corrosion inhibitors has been investigated since 2009. The present paper is an exhaustive compilation of the scientific published papers devoted to the use of expired drugs as corrosion inhibitors in various aggressive solutions. The inhibitory efficiencies of expired drugs are presented as a function of the studied metal or alloy and the nature of the aggressive solution, as well as the concentration of the inhibitor in such a solution. Research has especially been focused on mild and carbon steel and less on stainless steel, as well as on some metals such as copper, zinc, nickel, tin and aluminum and its alloys. The experimental methods used to assess the inhibitory efficiencies of expired drugs are briefly discussed. Also, the available information on the stability of the active substances in the drugs is presented, although most authors were not concerned with this aspect. Finally, several actions are revealed that must be undertaken by researchers so that the results obtained in the study of the anticorrosive action of expired drugs can be applied at the industrial level and not remain only an academic concern.<\/jats:p>","DOI":"10.3390\/ma16165555","type":"journal-article","created":{"date-parts":[[2023,8,10]],"date-time":"2023-08-10T10:52:40Z","timestamp":1691664760000},"page":"5555","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":71,"title":["Efficiency of Expired Drugs Used as Corrosion Inhibitors: A Review"],"prefix":"10.3390","volume":"16","author":[{"given":"Nicolae","family":"Vaszilcsin","sequence":"first","affiliation":[{"name":"Faculty of Industrial Chemistry and Environmental Engineering, Politehnica University Timisoara, Piata Victoriei No. 2, 300006 Timisoara, Romania"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4594-8092","authenticated-orcid":false,"given":"Andrea","family":"Kellenberger","sequence":"additional","affiliation":[{"name":"Faculty of Industrial Chemistry and Environmental Engineering, Politehnica University Timisoara, Piata Victoriei No. 2, 300006 Timisoara, Romania"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7798-5974","authenticated-orcid":false,"given":"Mircea Laurentiu","family":"Dan","sequence":"additional","affiliation":[{"name":"Faculty of Industrial Chemistry and Environmental Engineering, Politehnica University Timisoara, Piata Victoriei No. 2, 300006 Timisoara, Romania"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Delia Andrada","family":"Duca","sequence":"additional","affiliation":[{"name":"Faculty of Industrial Chemistry and Environmental Engineering, Politehnica University Timisoara, Piata Victoriei No. 2, 300006 Timisoara, Romania"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Valentin Laurentiu","family":"Ordodi","sequence":"additional","affiliation":[{"name":"Faculty of Industrial Chemistry and Environmental Engineering, Politehnica University Timisoara, Piata Victoriei No. 2, 300006 Timisoara, Romania"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,8,10]]},"reference":[{"key":"ref_1","unstructured":"(2022, November 25). NACE Study \u201cInternational Measures of Prevention, Application and Economics of Corrosion Technology\u201d. Available online: https:\/\/www.jm.com\/en\/blog\/2017\/march\/nace-study-estimates-global-cost-of-corrosion-at-25-trillion-annually\/."},{"key":"ref_2","unstructured":"Bockris, J.O., and Reddy, A.K.N. (2000). Modern Electrochemistry, Kluwer Academic. [2nd ed.]."},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Lazzari, L., and Pedeferri, M.P. (2018). Corrosion Science and Engineering, Springer.","DOI":"10.1007\/978-3-319-97625-9"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"117755","DOI":"10.1016\/j.molliq.2021.117755","article-title":"Understanding functional group effect on corrosion inhibition efficiency of selected organic compounds","volume":"344","author":"Assad","year":"2021","journal-title":"J. Mol. Liq."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"129374","DOI":"10.1016\/j.molstruc.2020.129374","article-title":"Molecular structural aspects of organic corrosion inhibitors: Experimental and computational insights","volume":"1227","author":"Chauhan","year":"2021","journal-title":"J. Mol. Struct."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1515\/corrrev-2018-0058","article-title":"Organic green corrosion inhibitors","volume":"37","author":"Popoola","year":"2019","journal-title":"Corros. Rev."},{"key":"ref_7","doi-asserted-by":"crossref","unstructured":"Sastri, V.S. (2011). Green Corrosion Inhibitors-Theory and Practice, Wiley.","DOI":"10.1002\/9781118015438"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"114385","DOI":"10.1016\/j.molliq.2020.114385","article-title":"Frontiers and advances in green and sustainable inhibitors for corrosion applications: A critical review","volume":"321","author":"Chaubey","year":"2021","journal-title":"J. Mol. Liq."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"127030","DOI":"10.1016\/j.jclepro.2021.127030","article-title":"Plant extracts as green corrosion inhibitor for ferrous metal alloys: A review","volume":"304","author":"Salleh","year":"2021","journal-title":"J. Clean. Prod."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"100044","DOI":"10.1016\/j.mtsust.2020.100044","article-title":"Green inhibitors for steel corrosion in acidic environment: State of art","volume":"10","author":"Wei","year":"2020","journal-title":"Mater. Today Sustain."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"1981","DOI":"10.1016\/j.corsci.2003.09.031","article-title":"Antibacterial drugs as corrosion inhibitors for corrosion of aluminum in hydrochloric solution","volume":"46","author":"Abdallah","year":"2004","journal-title":"Corros. Sci."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"225","DOI":"10.1016\/j.arabjc.2010.08.017","article-title":"Antihypertensive drugs as an inhibitors for corrosion of aluminum and aluminum silicon alloys in aqueous solutions","volume":"5","author":"Abdallah","year":"2012","journal-title":"Arab. J. Chem."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"1571","DOI":"10.1016\/j.corsci.2011.01.034","article-title":"Preparation and electrochemical characterization of Amoxicillin-doped cellulose acetate films for AA2024-T3 Aluminum alloy coatings","volume":"53","author":"Tamborin","year":"2011","journal-title":"Corros. Sci."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"35","DOI":"10.1016\/j.corsci.2008.10.016","article-title":"Quantum chemical studies on the corrosion inhibition of some sulphonamides on mild steel in acidic medium","volume":"51","author":"Arslan","year":"2009","journal-title":"Corros. Sci."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"819","DOI":"10.1016\/j.matlet.2009.01.020","article-title":"Streptomycin: A commercially available drug as corrosion inhibitor for mild steel in hydrochloric acid solution","volume":"63","author":"Sudhish","year":"2009","journal-title":"Matter. Lett."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"152","DOI":"10.1016\/j.corsci.2009.08.050","article-title":"Effect of Cefazolin on the corrosion of mild steel in HCl solution","volume":"52","author":"Sing","year":"2010","journal-title":"Corros. Sci."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"436","DOI":"10.1016\/j.corsci.2007.08.018","article-title":"Inhibition of iron corrosion in acid solutions by Cefatrexyl: Behavior near and at the corrosion potential","volume":"50","author":"Morad","year":"2008","journal-title":"Corros. Sci."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"68","DOI":"10.1016\/j.matchemphys.2011.03.054","article-title":"Inhibitive effect of Ceftazidime on corrosion of mild steel in hydrochloric acid solution","volume":"129","author":"Singh","year":"2011","journal-title":"Mater. Chem. Phys."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1080\/03601234.2012.716744","article-title":"A pharmaceutical product as corrosion inhibitor for carbon steel in acidic environment","volume":"48","author":"Samide","year":"2013","journal-title":"J. Environ. Sci. Health Part A"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"566","DOI":"10.1016\/j.apsusc.2005.12.114","article-title":"Caffeine as non-toxic corrosion inhibitor for copper in aqueous solutions of potassium nitrate","volume":"253","author":"Fallavena","year":"2006","journal-title":"Appl. Surf. Sci."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"142","DOI":"10.1016\/j.ijbiomac.2012.12.044","article-title":"Chitosan as a green inhibitor for copper corrosion in acidic medium","volume":"55","year":"2013","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1080\/08927014.2012.763117","article-title":"The corrosion behavior of galvanized steel in cooling tower water containing a biocide and a corrosion inhibitor","volume":"29","author":"Cansever","year":"2013","journal-title":"Biofouling"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"3873","DOI":"10.1016\/j.corsci.2011.08.006","article-title":"Drugs: A review of promising novel corrosion inhibitors","volume":"53","author":"Gece","year":"2011","journal-title":"Corros. Sci."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.corsci.2012.03.049","article-title":"Comment on the paper \u2018\u2018Drugs: A review of promising novel corrosion inhibitors\u2019\u2019 by G. Gece\u2013A (corrosion-free) bridge too far?","volume":"60","author":"Shama","year":"2012","journal-title":"Corros. Sci."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"115395","DOI":"10.1016\/j.molliq.2021.115395","article-title":"Present and emerging trends in using pharmaceutically active compounds as aqueous phase corrosion inhibitors","volume":"328","author":"Verma","year":"2021","journal-title":"J. Mol. Liq."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1233","DOI":"10.29294\/IJASE.6.1.2019.1233-1238","article-title":"Use of ravage Lovastin as a non-toxic corrosion inhibitor for copper in the 3M H2SO4 solution","volume":"6","author":"Raghavendra","year":"2019","journal-title":"Int. J. Adv. Sci. Eng."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"151","DOI":"10.21608\/absb.2009.7551","article-title":"Expired Ranitidine drugs as corrosion inhibitor for corrosion of aluminum in hydrochloric acid","volume":"20","author":"Hameed","year":"2009","journal-title":"Azhar Bull. Sci."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"241","DOI":"10.1016\/j.ijpharm.2012.04.015","article-title":"Corrosion inhibitors from expired drugs","volume":"431","author":"Vaszilcsin","year":"2012","journal-title":"Int. J. Pharm."},{"key":"ref_29","first-page":"680","article-title":"An overview of expired drugs as novel corrosion inhibitors for metals and alloys","volume":"4","author":"Chauhan","year":"2016","journal-title":"Int. J. Chem. Pharm. Sci."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"1316","DOI":"10.22146\/ijc.64048","article-title":"A Review on expired drug-based corrosion inhibitors: Chemical composition, structural effects, inhibition mechanism, current challenges, and future prospects","volume":"21","author":"Baari","year":"2021","journal-title":"Indones. J. Chem."},{"key":"ref_31","unstructured":"Marcuse, P. (2012). Corrosion Mechanisms in Theory and Practice, Taylor and Francis. [3rd ed.]."},{"key":"ref_32","doi-asserted-by":"crossref","unstructured":"McCafferty, E. (2010). Introduction to Corrosion Science, Springer Science.","DOI":"10.1007\/978-1-4419-0455-3"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"130206","DOI":"10.1016\/j.molstruc.2021.130206","article-title":"Adsorption, electrochemistry, DFT and inhibitive effect of imines derived from Tribulin on corrosion of mild steel in 1 M HCl","volume":"1235","author":"Bahron","year":"2021","journal-title":"J. Mol. Struct."},{"key":"ref_34","unstructured":"Baboian, R. (1995). Corrosion Tests and Standards: Application and Interpretation, ASTM International. [2nd ed.]."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"394","DOI":"10.1016\/j.electacta.2013.12.124","article-title":"Accurate electrochemical measurement of magnesium corrosion rates; a combined impedance, mass-loss and hydrogen collection Study","volume":"121","author":"King","year":"2014","journal-title":"Electrochim. Acta"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"105567","DOI":"10.1016\/j.porgcoat.2020.105567","article-title":"Experimental and computational study of Penicillamine drug and cysteine as water-soluble green corrosion inhibitors of mild steel","volume":"142","author":"Farahati","year":"2020","journal-title":"Prog. Org. Coat."},{"key":"ref_37","unstructured":"Schulze, M. (2000). Corrosion and Environmental Degradation, Wiley-VCH."},{"key":"ref_38","doi-asserted-by":"crossref","unstructured":"Orazem, M.E., and Tribollet, B. (2008). Electrochemical Impedance Spectroscopy, John Wiley & Sons.","DOI":"10.1002\/9780470381588"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"101687","DOI":"10.1016\/j.mtcomm.2020.101687","article-title":"Inhibition of mild steel corrosion using Magnolia Kobus extract in sulphuric acid medium","volume":"25","author":"Chung","year":"2020","journal-title":"Mat. Today Commun."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"114509","DOI":"10.1016\/j.molliq.2020.114509","article-title":"A new trend in corrosion protection of copper in acidic medium by using Jujube shell extract as an effective green and environmentally safe corrosion inhibitor: Experimental, quantum chemistry approach and Monte Carlo simulation study","volume":"322","author":"Jmiai","year":"2021","journal-title":"J. Mol. Liq."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"3269","DOI":"10.1016\/j.electacta.2005.09.018","article-title":"Electrochemical frequency modulation as a new technique for monitoring corrosion inhibition of iron in acid media by new thiourea derivative","volume":"51","author":"Khaled","year":"2006","journal-title":"Electrochim. Acta"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"83","DOI":"10.1016\/j.molliq.2017.11.006","article-title":"Electrochemical frequency modulation (EFM) technique: Theory and recent practical applications in corrosion research","volume":"249","author":"Obot","year":"2018","journal-title":"J. Mol. Liq."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1016\/0376-4583(83)90077-8","article-title":"Thermometric and calorimetric methods in electrochemical and corrosion studies","volume":"20","author":"Kuhn","year":"1983","journal-title":"Surf. Technol."},{"key":"ref_44","first-page":"1282","article-title":"Application of expired Tramadol medicinal drug for corrosion inhibition of steel in acidic environment: Analytical, kinetic, and thermodynamic studies","volume":"11","year":"2022","journal-title":"Int. J. Corros. Scale Inhib."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"16","DOI":"10.1007\/s40735-018-0205-5","article-title":"Corrosion inhibition and adsorption properties of mild steel in 1 M hydrochloric acid medium by expired Ambroxol drug","volume":"5","author":"Geethamani","year":"2019","journal-title":"J. Bio-Tribo-Corros."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"046419","DOI":"10.1088\/2053-1591\/aafcd7","article-title":"A study on the inhibition effect of expired Amoxicillin on mild steel corrosion in 1N HCl","volume":"6","author":"Fadila","year":"2019","journal-title":"Mater. Res. Express."},{"key":"ref_47","first-page":"1442","article-title":"An Expired non-toxic drug acts as corrosion inhibitor for mild steel in hydrochloric acid medium","volume":"3","author":"Geethamani","year":"2015","journal-title":"Int. J. Chem. Pharm. Sci."},{"key":"ref_48","first-page":"8","article-title":"Application of expired drugs in corrosion inhibition of mild steel","volume":"4","author":"Gupta","year":"2017","journal-title":"Int. J. Pharm. Chem. Anal."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"363","DOI":"10.1007\/s40090-017-0120-5","article-title":"Expired Atorvastatin drug as corrosion inhibitor for mild steel in hydrochloric acid solution","volume":"8","author":"Singh","year":"2017","journal-title":"Int. J. Ind. Chem."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"102383","DOI":"10.1016\/j.rinp.2019.102383","article-title":"Evaluation of anti-corrosion performance of an expired semi synthetic antibiotic Cefdinir for mild steel in 1 M HCl medium: An experimental and theoretical study","volume":"14","author":"Singh","year":"2019","journal-title":"Results Phys."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"220532","DOI":"10.20964\/2022.05.21","article-title":"Comparative experimental and theoretical studies of three different expired pharmaceutical compounds as green corrosion inhibitors of mild steel in different acidic solutions","volume":"17","author":"Naggar","year":"2022","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"6006","DOI":"10.1016\/S1452-3981(23)10865-0","article-title":"2-(2, 6-dichloranilino) phenyl acetic acid drugs as eco-friendly corrosion inhibitors for mild steel in 1M HCl","volume":"9","author":"Hameed","year":"2014","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"100639","DOI":"10.1016\/j.jics.2022.100639","article-title":"Effect of expired Doxofylline drug on corrosion protection of soft steel in 1 M HCl: Electrochemical, quantum chemical and synergistic effect studies","volume":"99","author":"Kalkhambkar","year":"2022","journal-title":"J. Indian Chem. Soc."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"220655","DOI":"10.20964\/2022.06.69","article-title":"Expired Dulcolax drug as corrosion inhibitor for low carbon steel in acidic environment","volume":"17","author":"Hameed","year":"2022","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"2616","DOI":"10.13005\/ojc\/330559","article-title":"Study of inhibition and adsorption properties of mild steel corrosion by expired pharmaceutical Gentamicin drug in hydrochloric acid media","volume":"33","author":"Srinivasulu","year":"2017","journal-title":"Orient. J. Chem."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"2685","DOI":"10.20964\/2020.03.34","article-title":"Investigation of adsorption and inhibitive effect of expired Helicure drug on mild steel corrosion in hydrochloric acid solution","volume":"15","year":"2020","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"540","DOI":"10.1016\/j.matpr.2022.05.595","article-title":"Investigation of corrosion performance of expired Irnocam on the mild steel in acidic medium","volume":"66","author":"Sharma","year":"2022","journal-title":"Mater. Today Proc."},{"key":"ref_58","first-page":"762","article-title":"Experimental and DFT investigation on the corrosion inhibition behavior of expired drug Lumerax on mild steel in hydrochloric acid","volume":"9","author":"Dohare","year":"2017","journal-title":"Anal. Bioanal. Electrochem."},{"key":"ref_59","first-page":"28406","article-title":"A new pharmaceutically expired drug acts as corrosion inhibitor for mild steel in acid medium","volume":"76","author":"Geethamani","year":"2014","journal-title":"Corros. Dye"},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"491","DOI":"10.3103\/S1068375520040055","article-title":"Adsorption and anticorrosion behavior of expired Meloxicam on mild steel in hydrochloric acid solution","volume":"56","author":"Fouda","year":"2020","journal-title":"Surf. Eng. Appl. Electrochem."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"398","DOI":"10.1108\/ACMM-02-2018-1897","article-title":"Inhibition of three kinds of expired Nitroimidazole antibiotics","volume":"65","author":"Shi","year":"2018","journal-title":"Anti-Corros. Methods Mater."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"273","DOI":"10.4152\/pea.201104273","article-title":"Ranitidine drugs as non-toxic corrosion inhibitors for mild steel in hydrochloric acid medium","volume":"29","author":"Hameed","year":"2011","journal-title":"Port. Electrochim. Acta"},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"30","DOI":"10.1016\/j.md.2017.11.001","article-title":"DFT and experimental studies on the inhibition potentials of expired Tramadol drug on mild steel corrosion in hydrochloric acid","volume":"9","author":"Dohare","year":"2017","journal-title":"Mater. Discov."},{"key":"ref_64","first-page":"610","article-title":"Expired Ceftin as a corrosion inhibitor for mild steel in 5% HCl solution","volume":"8","author":"Raghavendra","year":"2019","journal-title":"Int. J. Green Herbal Chem."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"213","DOI":"10.4152\/pea.201803213","article-title":"Corrosion inhibition activity of an expired antibacterial drug in acidic media amid elucidate DFT and MD simulations","volume":"36","author":"Dahiya","year":"2018","journal-title":"Port. Electrochim. Acta"},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"20","DOI":"10.1007\/s40735-018-0212-6","article-title":"Corrosion Inhibition Study of Expired Acetazolamide on mild steel in dilute hydrochloric acid solution","volume":"5","author":"Chaudhari","year":"2019","journal-title":"J. Bio-Tribo-Corros."},{"key":"ref_67","first-page":"665","article-title":"Green approach to corrosion inhibition on mild steel in acidic media by the expired Sulpha drug","volume":"8","author":"Chaudhari","year":"2018","journal-title":"Int. J. Manag. Technol. Eng."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"1113","DOI":"10.35378\/gujs.469622","article-title":"Expired Abacavir sulfate drug as non-toxic corrosion inhibitor for mild steel (MS) in 3 M hydrochloric acid system","volume":"32","author":"Raghavendra","year":"2019","journal-title":"Gazy Univ. J. Sci."},{"key":"ref_69","first-page":"26","article-title":"Expired Amitriptyline drug as a new nontoxic inhibitor protecting mild steel corrosion in HCl solution","volume":"7","author":"Raghavendra","year":"2019","journal-title":"Sci. Lett."},{"key":"ref_70","first-page":"1","article-title":"The Corrosion Inhibition Study of expired Doxercalciferol drug as nontoxic inhibitor for mild steel (MS) in 3M HCl medium","volume":"10","author":"Raghavendra","year":"2018","journal-title":"J. Chem. Pharm. Res."},{"key":"ref_71","first-page":"1","article-title":"Expired Fluoxymesterone drug as sustainable corrosion inhibitor for mild steel (MS) in 3 M HCl solution: Experimental investigations towards mitigation of metal dissolution","volume":"6","author":"Raghavendra","year":"2019","journal-title":"Int. J. Chem. Mater. Res."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"463","DOI":"10.1007\/s42250-019-00061-2","article-title":"Expired Lorazepam drug: A medicinal compound as green corrosion inhibitor for mild steel in hydrochloric acid system","volume":"2","author":"Raghavendra","year":"2019","journal-title":"Chem. Afr."},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"10289","DOI":"10.20964\/2020.10.37","article-title":"Inhibition potentials and adsorption performance of two sulfonylurea antibiotic expired drugs on the corrosion of mild steel in 0.5 M H2SO4","volume":"15","author":"Abdallah","year":"2020","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"1091558","DOI":"10.1080\/23312009.2015.1091558","article-title":"Adsorption and corrosion inhibition of mild steel in acidic media by expired pharmaceutical drug","volume":"1","author":"Geethamani","year":"2015","journal-title":"Cogent Chem."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"3283","DOI":"10.20964\/2020.04.09","article-title":"Corrosion inhibition effect of expired Ampicillin and Flucloxacillin drugs for mild steel in aqueous acidic medium","volume":"15","author":"Alfakeer","year":"2020","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"490","DOI":"10.1016\/j.jtice.2016.03.008","article-title":"The inhibitory action of expired Asthalin drug on the corrosion of mild steel in acidic media: A comparative study","volume":"63","author":"Geethamani","year":"2016","journal-title":"J. Taiwan Inst. Chem. Eng."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"509","DOI":"10.1080\/17518253.2021.1944329","article-title":"Expired Azithromycin and Roxithromycin drugs as environmentally friendly inhibitors for mild steel corrosion in H2SO4 solutions","volume":"14","author":"Abdallah","year":"2021","journal-title":"Green Chem. Lett. Rev."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"1964","DOI":"10.20964\/2020.03.65","article-title":"Electrochemical studies of expired drug (Formoterol) as oilfield corrosion inhibitor for mild steel in H2SO4 media","volume":"15","author":"Ma","year":"2020","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"2311","DOI":"10.1007\/s13738-021-02446-y","article-title":"Experimental and computational approach of an expired antibiotic drug Kynurenic acid as an efficient corrosion inhibitor for mild steel in HNO3 medium","volume":"19","author":"Sundaram","year":"2022","journal-title":"J. Iranian Chem. Soc."},{"key":"ref_80","doi-asserted-by":"crossref","unstructured":"Tiwari, A., Galanis, A., and Soucek, M.D. (2016). Biobased and Environmental Benign Coatings, Scrivener Publishing.","DOI":"10.1002\/9781119185055"},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"114423","DOI":"10.1016\/j.mseb.2019.114423","article-title":"Rapid investigation expiry drug green corrosion inhibitor on mild steel in NaCl medium","volume":"249","author":"Palaniappana","year":"2019","journal-title":"Mat. Sci. Eng. B"},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"100841","DOI":"10.1016\/j.surfin.2020.100841","article-title":"Surface morphological and quantum chemical studies of some expired drug molecules as potential corrosion inhibitors for mild steel in chloride medium","volume":"22","author":"Vengatesh","year":"2021","journal-title":"Surf. Interfaces"},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"1289","DOI":"10.37624\/IJERT\/13.6.2020.1289-1299","article-title":"Study of corrosion properties, adsorption mechanism and thermodynamics characteristics of expired Artemether-Lumefantrine inhibition drug on mild steel in NaCl solution","volume":"13","author":"Odunlamia","year":"2021","journal-title":"Int. J. Eng. Res. Technol."},{"key":"ref_84","first-page":"31","article-title":"Electrochemical evaluation of an outdated antifungal drug as corrosion inhibitor of mild steel in neutral chloride media","volume":"5","author":"Menchaca","year":"2015","journal-title":"Innov. Corros. Mat. Sci."},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"118482","DOI":"10.1016\/j.molliq.2022.118482","article-title":"Multidimensional insight into the corrosion inhibition of Salbutamol drug molecule on mild steel in oilfield acidizing fluid: Experimental and computer aided modeling approach","volume":"349","author":"Anadebe","year":"2022","journal-title":"J. Mol. Liq."},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"177","DOI":"10.30799\/jaec.056.19050101","article-title":"Use of expired Naftifine drug as corrosion inhibitor for copper in hydrochloric acid","volume":"5","author":"Raghavendra","year":"2019","journal-title":"J. Adv. Electrochem."},{"key":"ref_87","first-page":"677","article-title":"Quantum and electrochemical studies of corrosion inhibition impact on industrial structural steel (E410) by expired Amiloride drug in 0.5 M solutions of HCl, H2SO4 and NaHCO3","volume":"9","author":"Ugi","year":"2021","journal-title":"Mor. J. Chem."},{"key":"ref_88","doi-asserted-by":"crossref","first-page":"114918","DOI":"10.1016\/j.molliq.2020.114918","article-title":"Study the effect of expired Tenoxicam on the inhibition of carbon steel corrosion in a solution of hydrochloric acid","volume":"321","author":"Elabbasy","year":"2021","journal-title":"J. Mol. Liq."},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1007\/s40735-016-0037-0","article-title":"Evaluation of an expired nontoxic Amlodipine Besylate drug as a corrosion inhibitor for low-carbon steel in hydrochloric acid solutions","volume":"2","author":"Fouda","year":"2016","journal-title":"J. Bio- Tribo-Corros."},{"key":"ref_90","first-page":"107","article-title":"Evaluation of an expired non-toxic Amlodipine Besylatedrug as corrosion inhibitor for low carbon steel in hydrochloric acid solutions","volume":"1","author":"Fouda","year":"2016","journal-title":"Benha J. Appl. Sci."},{"key":"ref_91","first-page":"21103","article-title":"Electrochemical and computational studies of Aripiprazole as a novel eco-friendly green corrosion inhibitor for carbon steel in aqueous environment","volume":"16","author":"Shanab","year":"2021","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_92","first-page":"735","article-title":"Evaluation of expired Augmentine drugs as corrosion inhibitor for carbon steel alloy in 1.0 N HCl acidic environment using analytical techniques","volume":"65","author":"Hameed","year":"2022","journal-title":"Egypt. J. Chem."},{"key":"ref_93","doi-asserted-by":"crossref","first-page":"5704","DOI":"10.33263\/BRIAC104.704714","article-title":"Evaluation of expired Bromocriptine drug as eco-friendly corrosion inhibitor for C-steel in acidic media","volume":"10","author":"Fouda","year":"2020","journal-title":"Biointerface Res. Appl. Chem."},{"key":"ref_94","doi-asserted-by":"crossref","first-page":"100522","DOI":"10.1016\/j.jics.2022.100522","article-title":"Corrosion protection of carbon steel in acidic media by expired Bupropion drug; experimental and theoretical study","volume":"99","author":"Zadeh","year":"2022","journal-title":"J. Indian Chem. Soc."},{"key":"ref_95","first-page":"5","article-title":"Efficient corrosion inhibitors by recovery of pharmaceutical waste","volume":"27","author":"Maior","year":"2020","journal-title":"An. Un. Oradea Fasc. Chem."},{"key":"ref_96","doi-asserted-by":"crossref","first-page":"336","DOI":"10.1080\/17518253.2017.1380236","article-title":"Studies on the inhibition of carbon steel corrosion in hydrochloric acid solution by expired Carvedilol drug","volume":"10","author":"Fouda","year":"2017","journal-title":"Green Chem. Lett. Rev."},{"key":"ref_97","doi-asserted-by":"crossref","first-page":"150852","DOI":"10.20964\/2021.01.27","article-title":"Expired Desloratidine drug as inhibitor for corrosion of carbon steel pipeline in hydrochloric acid solution","volume":"16","author":"Eid","year":"2021","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_98","first-page":"1","article-title":"Expired Farcolin drug as corrosion inhibitor for carbon steel in 1M HCl solution","volume":"5","author":"Attia","year":"2015","journal-title":"J. Basic. Appl. Chem."},{"key":"ref_99","doi-asserted-by":"crossref","first-page":"118689","DOI":"10.1016\/j.molliq.2022.118689","article-title":"Herbal expired drug bearing glycosides and polysaccharides moieties as green and cost-effective oilfield corrosion inhibitor: Electrochemical and computational studies","volume":"352","author":"Zakaria","year":"2022","journal-title":"J. Mol. Liq."},{"key":"ref_100","doi-asserted-by":"crossref","first-page":"114","DOI":"10.1007\/s40735-020-00403-5","article-title":"Expired Indomethacin therapeutics as corrosion inhibitors for carbon steel in 1.0 M hydrochloric acid media","volume":"6","author":"Hameed","year":"2020","journal-title":"J. Bio-Tribo-Corros."},{"key":"ref_101","doi-asserted-by":"crossref","first-page":"210446","DOI":"10.20964\/2021.04.15","article-title":"Electrochemical techniques for evaluation of expired Megavit drugs as corrosion inhibitor for steel in hydrochloric acid","volume":"16","author":"Hameed","year":"2021","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_102","doi-asserted-by":"crossref","first-page":"5964","DOI":"10.20964\/2017.07.45","article-title":"Metronidazole performance as corrosion inhibitor for carbon steel, 304L stainless steel and aluminum in hydrochloric acid solution","volume":"12","author":"Samide","year":"2017","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_103","doi-asserted-by":"crossref","first-page":"6682","DOI":"10.20964\/2019.07.25","article-title":"Corrosion inhibition efficiency of expired Nitazoxanide drug on carbon steel in hydrochloric acid solution","volume":"14","author":"Motawea","year":"2019","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_104","doi-asserted-by":"crossref","first-page":"239","DOI":"10.21608\/bjas.2021.214426","article-title":"Test of No Plac expired drug as metallic corrosion inhibitor for carbon steel","volume":"6","author":"Elsaoud","year":"2021","journal-title":"Benha J. Appl. Sci."},{"key":"ref_105","doi-asserted-by":"crossref","first-page":"108674","DOI":"10.1016\/j.jece.2022.108674","article-title":"Synthesis and evaluation of Omeprazole-based derivatives as eco-friendly corrosion inhibitors for Q235 steel in hydrochloric acid","volume":"10","author":"Liu","year":"2022","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_106","first-page":"564","article-title":"Protective efficiency of expired drug against acid corrosion of carbon steel","volume":"11","author":"Tsygankova","year":"2022","journal-title":"Int. J. Corros. Scale Inhib."},{"key":"ref_107","doi-asserted-by":"crossref","first-page":"6327","DOI":"10.20964\/2018.07.33","article-title":"Expired drug (Pantoprazole sodium) as a corrosion inhibitor for high carbon steel in hydrochloric acid solution","volume":"13","author":"Fouda","year":"2018","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_108","doi-asserted-by":"crossref","first-page":"012043","DOI":"10.1088\/1757-899X\/416\/1\/012043","article-title":"Expired domestic drug-Paracetamol-as corrosion inhibitor for carbon steel in acid media","volume":"416","author":"Duca","year":"2018","journal-title":"IOP Conf. Ser. Mater. Sci. Eng."},{"key":"ref_109","first-page":"146","article-title":"Effect of expired drugs as corrosion inhibitors for carbon steel in 1M HCl solution","volume":"27","author":"Hameed","year":"2014","journal-title":"Int. J. Pharm. Sci. Rev. Res."},{"key":"ref_110","first-page":"25","article-title":"Expired Podocip drug as potential corrosion inhibitor for carbon steel in acid chloride solution","volume":"7","author":"Dohare","year":"2018","journal-title":"Int. J. Corros. Scale Inhib."},{"key":"ref_111","doi-asserted-by":"crossref","first-page":"5112","DOI":"10.1016\/S1452-3981(23)06691-9","article-title":"Electrochemical and analytical study of the corrosion inhibitory behavior of expired pharmaceutical compounds for C-steel corrosion","volume":"10","author":"Ahmed","year":"2015","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_112","doi-asserted-by":"crossref","first-page":"139","DOI":"10.1134\/S2070205117010063","article-title":"Unused Clopidogrel drug as eco-friendly corrosion inhibitor for carbon steel in aqueous media","volume":"53","author":"Fouda","year":"2017","journal-title":"Prot. Met. Phys. Chem. Surf."},{"key":"ref_113","first-page":"125","article-title":"Anti-corrosion behaviour of expired Tobramycin drug on carbon steel in acidic medium","volume":"73","author":"Abeng","year":"2020","journal-title":"S. Afr. J. Chem."},{"key":"ref_114","doi-asserted-by":"crossref","first-page":"113716","DOI":"10.1016\/j.molliq.2020.113716","article-title":"Expired Metformin drug as green corrosion inhibitor for simulated oil\/gas well acidizing environment","volume":"315","author":"Haruna","year":"2020","journal-title":"J. Mol. Liq."},{"key":"ref_115","doi-asserted-by":"crossref","first-page":"114295","DOI":"10.1016\/j.molliq.2020.114295","article-title":"Corrosion inhibition of carbon steel by three kinds of expired Cephalosporins in 0.1 M H2SO4","volume":"320","author":"Guo","year":"2020","journal-title":"J. Mol. Liq."},{"key":"ref_116","doi-asserted-by":"crossref","unstructured":"Samide, A., Iacobescu, G.E., Tutunaru, B., Grecu, R., Tigae, C., and Sp\u00eenu, C. (2017). Inhibitory properties of Neomycin thin film formed on carbon steel in sulfuric acid solution: Electrochemical and AFM investigation. Coatings, 7.","DOI":"10.20944\/preprints201709.0061.v1"},{"key":"ref_117","doi-asserted-by":"crossref","first-page":"210771","DOI":"10.20964\/2021.07.73","article-title":"Expired Paracetamol as corrosion inhibitor for low carbon steel in sulfuric acid. Electrochemical, kinetics and thermodynamics investigation","volume":"16","author":"Abdallah","year":"2021","journal-title":"Int. J. Electrochem. 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Soc."},{"key":"ref_121","first-page":"838","article-title":"Corrosion protection of expired Perindopril and expired Alprazolam drug in carbon steel in the 3% NaCl solution","volume":"9","author":"Raghavendra","year":"2019","journal-title":"Int. J. Pharm. Biol. Sci."},{"key":"ref_122","first-page":"1","article-title":"Expired Zosyn drug as corrosion inhibitor for carbon steel in sodium chloride solution","volume":"59","author":"Dan","year":"2014","journal-title":"Chem. Bull. \u201cPOLITEHNICA\u201d Univ."},{"key":"ref_123","first-page":"1","article-title":"Effect of expired Oxazepam medicine on the corrosion of carbon steel in 5% NaCl solution: An experimental approach towards mitigation of dissolution process","volume":"1","author":"Raghavendra","year":"2019","journal-title":"Fron. Chem. Res."},{"key":"ref_124","doi-asserted-by":"crossref","first-page":"838","DOI":"10.1080\/01694243.2020.1826801","article-title":"Effect of expired Paracetamol\u2013Zn+2 system and its synergistic effect towards iron dissolution inhibition and green inhibition performance","volume":"35","author":"Hameed","year":"2020","journal-title":"J. Adhes. Sci. Technol."},{"key":"ref_125","first-page":"399","article-title":"Expired Streptomycin as corrosion inhibitor for carbon steel in acetic acid-sodium acetate buffer solution","volume":"6","author":"Bobina","year":"2021","journal-title":"J. Eng. Sci. Innov."},{"key":"ref_126","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1021\/acsomega.0c03364","article-title":"Electrochemical and computational insights on the application of expired Metformin drug as a novel inhibitor for the sweet corrosion of C1018 steel","volume":"6","author":"Onyeachu","year":"2021","journal-title":"ACS Omega"},{"key":"ref_127","doi-asserted-by":"crossref","first-page":"115702","DOI":"10.1016\/j.molliq.2021.115702","article-title":"Anticorrosion and adsorption performance of expired antibacterial drugs on Sabic iron corrosion in HCl solution: Chemical, electrochemical and theoretical approach","volume":"330","author":"Abdallah","year":"2021","journal-title":"J. Mol. Liq."},{"key":"ref_128","doi-asserted-by":"crossref","first-page":"4739","DOI":"10.20964\/2020.05.86","article-title":"The effect of expired Acyclovir and Omeprazole drugs on the inhibition of Sabic iron corrosion in HCl solution","volume":"15","author":"Abdallah","year":"2020","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_129","doi-asserted-by":"crossref","first-page":"158","DOI":"10.1080\/00986445.2020.1852220","article-title":"Expired Amoxicillin and Cefuroxime drugs as efficient anticorrosives for Sabic iron in 1.0 M hydrochloric acid solution","volume":"209","author":"Abdallah","year":"2022","journal-title":"Chem. Eng. Commun."},{"key":"ref_130","doi-asserted-by":"crossref","first-page":"17092","DOI":"10.1039\/D1RA01010G","article-title":"Enhancing the inhibition and adsorption performance of SABIC iron corrosion in sulfuric acid by expired vitamins. Experimental and computational approach","volume":"11","author":"Abdallah","year":"2021","journal-title":"RSC Adv."},{"key":"ref_131","doi-asserted-by":"crossref","first-page":"3893","DOI":"10.1007\/s11164-016-2852-9","article-title":"Expired pharmaceutical compounds as potential inhibitors for cast iron corrosion in acidic medium","volume":"43","author":"Hameed","year":"2017","journal-title":"Res. Chem. Intermed."},{"key":"ref_132","first-page":"267","article-title":"Pipeline steel protection in oil well acidizing fluids using expired pharmaceutical agent","volume":"6","author":"Iroha","year":"2020","journal-title":"Chem. Int."},{"key":"ref_133","first-page":"714","article-title":"Application of expired Co-Amoxiclav medicinal drugs for corrosion inhibition of steel alloys used in petroleum industry in acidic environment","volume":"10","author":"Hameed","year":"2019","journal-title":"Int. J. Corros. Scale Inhib."},{"key":"ref_134","doi-asserted-by":"crossref","first-page":"288","DOI":"10.1080\/16583655.2022.2048512","article-title":"Evaluation of the anticorrosion performance of Tamsulosin as corrosion inhibitor for pipeline steel in acidic environment: Experimental and theoretical study","volume":"16","author":"Iroha","year":"2022","journal-title":"J. Taibah Univ. Sci."},{"key":"ref_135","doi-asserted-by":"crossref","first-page":"21021","DOI":"10.20964\/2021.02.17","article-title":"Corrosion inhibition effect of expired Levothyroxine drug on stainless steel 304L in 0.5 M H2SO4 Solution","volume":"16","author":"Motawea","year":"2021","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_136","first-page":"226","article-title":"Expired Concor drug as potential nontoxic corrosion inhibitor for 304 stainless steel in hydrochloric acid solution","volume":"59","author":"Fouda","year":"2018","journal-title":"Za\u0161t. Mater."},{"key":"ref_137","doi-asserted-by":"crossref","unstructured":"Yang, B., Dong, J., Bian, H., Lu, H., Bin, D., Tang, S., Song, Y., and Lu, H. (2022). Expired Cefalexin loaded into mesoporous nanosilica for self-healing epoxy coating on 304 stainless steel. Nanomaterials, 12.","DOI":"10.3390\/nano12142406"},{"key":"ref_138","doi-asserted-by":"crossref","first-page":"875","DOI":"10.1016\/j.jmrt.2021.01.055","article-title":"An expired Ceftazidime antibiotic as an inhibitor for disintegration of copper metal in pickling HCl media","volume":"11","author":"Kamel","year":"2021","journal-title":"J. Mat. Res. Technol."},{"key":"ref_139","first-page":"1","article-title":"Expired Ixabepilone as a corrosion inhibitor on copper metal protection in 5 M HCl medium","volume":"6","author":"Raghavendra","year":"2019","journal-title":"Int. J. Sci. Res. Chem. Sci."},{"key":"ref_140","doi-asserted-by":"crossref","first-page":"14710","DOI":"10.1038\/s41598-019-51299-2","article-title":"Ibuprofen as a corrosion inhibitor for copper in synthetic acid rain solution","volume":"9","year":"2019","journal-title":"Sci. Rep."},{"key":"ref_141","doi-asserted-by":"crossref","first-page":"114817","DOI":"10.1016\/j.molliq.2020.114817","article-title":"Experimental and theoretical studies of Paracetamol as a copper corrosion inhibitor","volume":"327","year":"2021","journal-title":"J. Mol. Liq."},{"key":"ref_142","doi-asserted-by":"crossref","first-page":"5982","DOI":"10.20964\/2020.07.62","article-title":"Corrosion inhibition of \u03b1-brass alloy in aqueous solution by using expired Ranitidine","volume":"15","author":"Fouda","year":"2020","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_143","doi-asserted-by":"crossref","first-page":"572","DOI":"10.1134\/S2070205119030146","article-title":"Adsorption and corrosion inhibition of cu in nitric acid by expired Simvastatin drug. Prot","volume":"55","author":"Fouda","year":"2019","journal-title":"Met. Phys. Chem. Surf."},{"key":"ref_144","doi-asserted-by":"crossref","unstructured":"Kellenberger, A., Duca, D.A., Dan, M.L., and Medeleanu, M. (2022). Recycling unused Midazolam drug as efficient corrosion inhibitor for copper in nitric acid solution. Materials, 15.","DOI":"10.3390\/ma15082918"},{"key":"ref_145","doi-asserted-by":"crossref","first-page":"5520","DOI":"10.20964\/2016.07.67","article-title":"Electrochemical and theoretical study of Metronidazole drug as inhibitor for copper corrosion in hydrochloric acid solution","volume":"11","author":"Samide","year":"2016","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_146","doi-asserted-by":"crossref","first-page":"9745","DOI":"10.20964\/2016.11.36","article-title":"Unused Meropenem drug as corrosion inhibitor for copper in acidic medium; experimental and theoretical studies","volume":"11","author":"Fouda","year":"2016","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_147","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1007\/s40735-021-00494-8","article-title":"Recyclization of expired Megavit Zinc (MZ) drug as metallic corrosion inhibitor for copper alloy C10100 in nitric acid solution","volume":"7","author":"Elsaoud","year":"2021","journal-title":"J. Bio-Tribo-Corros."},{"key":"ref_148","first-page":"5116","article-title":"Eco-friendly approach to corrosion inhibition of copper in HNO3 solution by the expired Tylosin drug","volume":"12","author":"Ali","year":"2022","journal-title":"Biointerface Res. Appl. Chem."},{"key":"ref_149","doi-asserted-by":"crossref","first-page":"1950009","DOI":"10.1142\/S2251237319500096","article-title":"Expired Atenolol drug: A nontoxic corrosion inhibitor for Al in 3 M HCl pickling environment","volume":"7","author":"Raghavendra","year":"2019","journal-title":"J. Mol. Eng. Mater."},{"key":"ref_150","doi-asserted-by":"crossref","first-page":"1864","DOI":"10.1007\/s11668-020-01005-6","article-title":"Prevention of aluminum corrosion in hydrochloric acid using expired Oseltamivir drug as an inhibitor","volume":"20","author":"Raghavendra","year":"2020","journal-title":"J. Fail. Anal. Prev."},{"key":"ref_151","first-page":"917","article-title":"Expired Naproxen drug as a robust corrosion inhibitor of Al in 3 M hydrochloric acid system","volume":"42","author":"Raghavendra","year":"2020","journal-title":"Songklanakarin J. Sci. Technol."},{"key":"ref_152","doi-asserted-by":"crossref","first-page":"2098","DOI":"10.1016\/S1452-3981(23)04832-0","article-title":"Expired Voltaren drugs as corrosion inhibitor for aluminum in hydrochloric acid","volume":"10","author":"Hameed","year":"2015","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_153","first-page":"7","article-title":"Expired Cidamex drug as corrosion inhibitor for aluminum in acidic solution","volume":"16","author":"Motawea","year":"2016","journal-title":"Glo. J. Res. Eng. Chem. Eng."},{"key":"ref_154","doi-asserted-by":"crossref","first-page":"4","DOI":"10.1007\/s40735-017-0120-1","article-title":"Expired drugs: Environmentally safe inhibitors for aluminum corrosion in 1 M H2SO4","volume":"4","author":"Nathiya","year":"2018","journal-title":"J. Bio-Tribo-Corros."},{"key":"ref_155","doi-asserted-by":"crossref","first-page":"220462","DOI":"10.20964\/2022.04.61","article-title":"Appraisal of adsorption and inhibition effect of expired Micardis drug on aluminum corrosion in hydrochloric acid solution","volume":"17","author":"Abdallah","year":"2022","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_156","doi-asserted-by":"crossref","first-page":"100960","DOI":"10.1016\/j.cdc.2022.100960","article-title":"Evaluation of expired Linezolid and Norfloxacin drugs as proficient environmentally safe inhibitors for mitigation of aluminum corrosion in sodium chloride medium","volume":"42","year":"2022","journal-title":"Chem. Data Collect."},{"key":"ref_157","doi-asserted-by":"crossref","first-page":"1412","DOI":"10.20964\/2020.02.25","article-title":"Expired drug Theophylline as potential corrosion inhibitor for 7075 Aluminum alloy in 1 M NaOH solution","volume":"15","author":"Su","year":"2020","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_158","first-page":"9","article-title":"Corrosion protection of tin in 1M HCl by expired Primperan and E-mox drugs-Part I","volume":"7","author":"Attia","year":"2017","journal-title":"J. Basic. Appl. Chem."},{"key":"ref_159","doi-asserted-by":"crossref","first-page":"117656","DOI":"10.1016\/j.molliq.2021.117656","article-title":"Corrosion inhibition behavior of expired Diclofenac sodium drug for Al 6061 alloy in aqueous media: Electrochemical, morphological, and theoretical investigations","volume":"343","author":"Almashhadani","year":"2021","journal-title":"J. Mol. Liq."},{"key":"ref_160","doi-asserted-by":"crossref","first-page":"130881","DOI":"10.1016\/j.molstruc.2021.130881","article-title":"Eco-friendly approach to corrosion inhibition of AA5083 aluminum alloy in HCl solution by the expired Vitamin B1 drugs","volume":"1244","author":"Chen","year":"2021","journal-title":"J. Mol. Struct."},{"key":"ref_161","first-page":"2863","article-title":"Inhibition studies of aluminum alloy (2024) corrosion in acid hydrochloride solution using an expired Phenylphrine drug","volume":"63","author":"Hamza","year":"2020","journal-title":"Egypt. J. Chem."},{"key":"ref_162","first-page":"872","article-title":"Corrosion protection of tin in 1M HCl by expired Novacid drug-Part I","volume":"4","author":"Attia","year":"2016","journal-title":"Int. J. Adv. Res."},{"key":"ref_163","doi-asserted-by":"crossref","first-page":"129518","DOI":"10.1016\/j.colsurfa.2022.129518","article-title":"Impact of an expired hemorheologic drug on the mitigation of zinc corrosion in acidic environment: Insights from chemical, electrochemical, and surface evaluation","volume":"650","author":"Abbar","year":"2022","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"ref_164","doi-asserted-by":"crossref","first-page":"74","DOI":"10.4028\/www.scientific.net\/AEF.27.74","article-title":"Ceftriaxone as corrosion inhibitor for nickel in acid solutions","volume":"27","author":"Duca","year":"2018","journal-title":"Adv. Electron. Forum."},{"key":"ref_165","first-page":"1","article-title":"Corrosion protection of tin in 1M HCl by expired Primperan and E-mox drugs-Part II","volume":"8","author":"Attia","year":"2018","journal-title":"J. Basic. Appl. Chem."},{"key":"ref_166","first-page":"11","article-title":"Potentiodynamic study on the effect of expired Septazole and Septrin drugs on the corrosion inhibition of tin electrode in 1M HCl solution","volume":"9","author":"Attia","year":"2019","journal-title":"J. Basic. Appl. Chem."},{"key":"ref_167","doi-asserted-by":"crossref","first-page":"71","DOI":"10.22153\/kej.2019.08.002","article-title":"Antibacterial inhibitor as an expired Metoclopramide in 0.5M phosphoric acid","volume":"15","author":"Anaee","year":"2019","journal-title":"Al-Khwarizmi Eng. J."},{"key":"ref_168","doi-asserted-by":"crossref","unstructured":"Ellepola, N., and Rubasinghege, G. (2022). Heterogeneous photocatalysis of Amoxicillin under natural conditions and high-intensity light: Fate, transformation, and mineralogical impacts. Environments., 9.","DOI":"10.3390\/environments9070077"},{"key":"ref_169","doi-asserted-by":"crossref","first-page":"985","DOI":"10.1016\/j.chemosphere.2013.01.095","article-title":"Amoxicillin-degradation products formed under controlled environmental conditions: Identification and determination in the aquatic environment","volume":"91","author":"Gozlan","year":"2013","journal-title":"Chemosphere"},{"key":"ref_170","doi-asserted-by":"crossref","first-page":"070006","DOI":"10.1063\/5.0005931","article-title":"Effective utilization of drugs as green corrosion inhibitor-A review","volume":"2225","author":"Shamnamola","year":"2020","journal-title":"AIP Conf. Proc."},{"key":"ref_171","doi-asserted-by":"crossref","first-page":"1275","DOI":"10.3891\/acta.chem.scand.23-1275","article-title":"N-Demethylstreptomycin-Degradation studies","volume":"23","author":"Heding","year":"1969","journal-title":"Acta Chem. 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