{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,13]],"date-time":"2026-05-13T01:26:12Z","timestamp":1778635572733,"version":"3.51.4"},"reference-count":93,"publisher":"MDPI AG","issue":"11","license":[{"start":{"date-parts":[[2024,6,1]],"date-time":"2024-06-01T00:00:00Z","timestamp":1717200000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004837","name":"Spanish Government","doi-asserted-by":"publisher","award":["PID2019-111029RB-I00"],"award-info":[{"award-number":["PID2019-111029RB-I00"]}],"id":[{"id":"10.13039\/501100004837","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>The CO2 adsorption of a phenylene-bridged ordered mesoporous organosilica (PMO\u2013benzene) was analyzed. The maximum capture capacity was 638.2 mg\u00b7g\u22121 (0 \u00b0C and 34 atm). Approximately 0.43 g would be enough to reduce the amount of atmospheric CO2 in 1 m3 to pre-industrial levels. The CO2 adsorption data were analyzed using several isotherm models, including Langmuir, Freundlich, Sips, Toth, Dubinin\u2013Radushkevich, and Temkin models. This study confirmed the capability of this material for use in reversible CO2 capture with a minimal loss of capacity (around 1%) after 10 capture cycles. Various techniques were employed to characterize this material. The findings from this study can help mitigate the greenhouse effect caused by CO2.<\/jats:p>","DOI":"10.3390\/ma17112669","type":"journal-article","created":{"date-parts":[[2024,6,3]],"date-time":"2024-06-03T05:58:00Z","timestamp":1717394280000},"page":"2669","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Use of Periodic Mesoporous Organosilica\u2013Benzene Adsorbent for CO2 Capture to Reduce the Greenhouse Effect"],"prefix":"10.3390","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9622-9226","authenticated-orcid":false,"given":"David","family":"Cantador-Fernandez","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica e Ingenier\u00eda Qu\u00edmica, Campus de Rabanales, Edificio Marie Curie, Universidad de C\u00f3rdoba, 14071 C\u00f3rdoba, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4323-8698","authenticated-orcid":false,"given":"Dolores","family":"Esquivel","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica, Universidad de C\u00f3rdoba, 14001 C\u00f3rdoba, Spain"},{"name":"Instituto para la Energ\u00eda y el Medioambiente (IQUEMA), Universidad de C\u00f3rdoba, 14071 C\u00f3rdoba, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8414-4615","authenticated-orcid":false,"given":"Jos\u00e9 Ram\u00f3n","family":"Jim\u00e9nez","sequence":"additional","affiliation":[{"name":"Departamento de Ingenier\u00eda Rural, Escuela Polit\u00e9cnica Superior de Belmez, Universidad de C\u00f3rdoba, Ed. 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N-IV, km-396, 14001 C\u00f3rdoba, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0809-4959","authenticated-orcid":false,"given":"Jos\u00e9 Mar\u00eda","family":"Fern\u00e1ndez-Rodr\u00edguez","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica e Ingenier\u00eda Qu\u00edmica, Campus de Rabanales, Edificio Marie Curie, Universidad de C\u00f3rdoba, 14071 C\u00f3rdoba, Spain"},{"name":"Instituto para la Energ\u00eda y el Medioambiente (IQUEMA), Universidad de C\u00f3rdoba, 14071 C\u00f3rdoba, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2024,6,1]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1062","DOI":"10.1039\/C7EE02342A","article-title":"Carbon Capture and Storage (CCS): The Way Forward","volume":"11","author":"Bui","year":"2018","journal-title":"Energy Environ. 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