{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T15:34:38Z","timestamp":1789832078497,"version":"4.0.1"},"reference-count":79,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2024,6,14]],"date-time":"2024-06-14T00:00:00Z","timestamp":1718323200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"European Union","award":["POWR.03.05.00-00-Z098\/17"],"award-info":[{"award-number":["POWR.03.05.00-00-Z098\/17"]}]},{"name":"European Union","award":["BK\u2013214\/RIE-4\/2024"],"award-info":[{"award-number":["BK\u2013214\/RIE-4\/2024"]}]},{"name":"Polish Ministry of Science and Higher Education","award":["POWR.03.05.00-00-Z098\/17"],"award-info":[{"award-number":["POWR.03.05.00-00-Z098\/17"]}]},{"name":"Polish Ministry of Science and Higher Education","award":["BK\u2013214\/RIE-4\/2024"],"award-info":[{"award-number":["BK\u2013214\/RIE-4\/2024"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Precipitation is an important factor that influences the quality of surface water in many regions of the world. The pollution of stormwater runoff from roads and parking lots is an understudied area in water quality research. Therefore, a comprehensive analysis of the physicochemical properties of rainwater flowing from parking lots was carried out, considering heavy metals and organic micropollutants. High concentrations of zinc were observed in rainwater, in addition to alkanes, e.g., tetradecane, hexadecane, octadecane, 2,6,10-trimethyldodecane, 2-methyldodecane; phenolic derivatives, such as 2,6-dimethoxyphenol and 2,4-di-tertbutylphenol; and compounds such as benzothiazole. To remove the contaminants present in rainwater, adsorption using silica carriers of the MCF (Mesostructured Cellular Foams) type was performed. Three groups of modified carriers were prepared, i.e., (1) SH (thiol), (2) NH2 (amino), and (3) NH2\/SH (amine and thiol functional groups). The research problem, which is addressed in the presented article, is concerned with the silica carrier influence of the functional group on the adsorption efficiency of micropollutants. The study included an evaluation of the effects of adsorption dose and time on the efficiency of the contaminant removal process, as well as an analysis of adsorption isotherms and reaction kinetics. The colour adsorption from rainwater was 94\u201395% for MCF-NH2 and MCF-NH2\/SH. Zinc adsorbance was at a level of 90% for MCF-NH2, and for MCF-NH2\/SH, 52%. Studies have shown the high efficacy (100%) of MCF-NH2 in removing organic micropollutants, especially phenolic compounds and benzothiazole. On the other hand, octadecane was the least susceptible to adsorption in each case. It was found that the highest efficiency of removal of organic micropollutants and zinc ions was obtained through the use of functionalized silica NH2.<\/jats:p>","DOI":"10.3390\/ma17122917","type":"journal-article","created":{"date-parts":[[2024,6,14]],"date-time":"2024-06-14T08:02:26Z","timestamp":1718352146000},"page":"2917","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Application of Mesoporous Silicas for Adsorption of Organic and Inorganic Pollutants from Rainwater"],"prefix":"10.3390","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6931-1083","authenticated-orcid":false,"given":"Anna","family":"Marsza\u0142ek","sequence":"first","affiliation":[{"name":"Department of Water and Wastewater Engineering, Faculty of Energy and Environmental Engineering, University of Technology, 44-100 Gliwice, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ewa","family":"Puszcza\u0142o","sequence":"additional","affiliation":[{"name":"Department of Air Protection, Faculty of Energy and Environmental Engineering, Silesian University of Technology, 44-100 Gliwice, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katarzyna","family":"Szyma\u0144ska","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering and Process Design, Faculty of Chemistry, Silesian University of Technology, 44-100 Gliwice, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8711-5534","authenticated-orcid":false,"given":"Marek","family":"Sroka","sequence":"additional","affiliation":[{"name":"Department of Engineering Materials and Biomaterials, Faculty of Mechanical Engineering, Silesian University of Technology, 44-100 Gliwice, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0068-1996","authenticated-orcid":false,"given":"Edyta","family":"Kudlek","sequence":"additional","affiliation":[{"name":"Department of Water and Wastewater Engineering, Faculty of Energy and Environmental Engineering, University of Technology, 44-100 Gliwice, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8219-0340","authenticated-orcid":false,"given":"Agnieszka","family":"Generowicz","sequence":"additional","affiliation":[{"name":"Department of Environmental Technologies, Cracow University of Technology, 31-155 Krak\u00f3w, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,6,14]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Gabr, M.E., El Shorbagy, A.M., and Faheem, H.B. 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