{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T12:01:20Z","timestamp":1768824080173,"version":"3.49.0"},"reference-count":54,"publisher":"MDPI AG","issue":"15","license":[{"start":{"date-parts":[[2024,7,30]],"date-time":"2024-07-30T00:00:00Z","timestamp":1722297600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"National Natural Science Foundation of China","award":["52201089"],"award-info":[{"award-number":["52201089"]}]},{"name":"National Natural Science Foundation of China","award":["2023CXPT008"],"award-info":[{"award-number":["2023CXPT008"]}]},{"name":"National Natural Science Foundation of China","award":["2021SFGC0701"],"award-info":[{"award-number":["2021SFGC0701"]}]},{"name":"Key Research and Development Program of Shandong Province","award":["52201089"],"award-info":[{"award-number":["52201089"]}]},{"name":"Key Research and Development Program of Shandong Province","award":["2023CXPT008"],"award-info":[{"award-number":["2023CXPT008"]}]},{"name":"Key Research and Development Program of Shandong Province","award":["2021SFGC0701"],"award-info":[{"award-number":["2021SFGC0701"]}]},{"name":"Key Research and Development Program of Shandong Province","award":["52201089"],"award-info":[{"award-number":["52201089"]}]},{"name":"Key Research and Development Program of Shandong Province","award":["2023CXPT008"],"award-info":[{"award-number":["2023CXPT008"]}]},{"name":"Key Research and Development Program of Shandong Province","award":["2021SFGC0701"],"award-info":[{"award-number":["2021SFGC0701"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>High toxicity is the main reason for the limited application of traditional corrosion inhibitors. Herein, it is critical to find a green, efficient, and long-term stable alternative substitute for the hazardous and conventional corrosion inhibitor. Ambrosia trifida L is widely distributed in fields and riverside wetlands as an invasive plant in China. According to the concept of turning waste into treasure, the extract of Ambrosia trifida L leaves (ATL) has the potential to address this issue due to its natural origin and abundant presence of heterocyclic organics. Therefore, ATL, as a green corrosion inhibitor, is prepared for the first time via a simple water-based extraction method. FT-IR (Fourier transform infrared spectroscopy) and UV-Vis (UV-visible) indicate that ATL extract contains abundant heterocyclic organics with conjugated structures, which exhibit the potential to become a high-efficiency inhibitor. Notably, the active sites of ATL molecules and their interaction with Q235 steel at the molecular\/atomic level are revealed via theoretical calculations. The highest Ebinding value observed for the major components in the ATL extract is 259.66 kcal\/mol, implying a significant adsorption capacity. The electrochemical results verify that microdose ATL extract can prominently inhibit steel corrosion, and the highest inhibition efficiency (\u03b7) is 97.5% (1000 mg\/L). Following immersion for 24 h, the \u03b7 value is enhanced to 99.0%, indicating a reliable and long-term ATL extract protection film is formed on the steel surface in harsh acidic solutions. The results of the weight loss, SEM (scanning electron microscope), and LSCM (laser scanning confocal microscopy) are consistent with the above conclusions. Finally, this study anticipates providing theoretical support for developing novel green plant extract inhibitors and aiding in their application in industrial pickling environments.<\/jats:p>","DOI":"10.3390\/ma17153758","type":"journal-article","created":{"date-parts":[[2024,7,30]],"date-time":"2024-07-30T08:51:42Z","timestamp":1722329502000},"page":"3758","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Turning Waste into Treasure: Invasive Plant Ambrosia trifida L Leaves as a High-Efficiency Inhibitor for Steel in Simulated Pickling Solutions"],"prefix":"10.3390","volume":"17","author":[{"given":"Xin","family":"Sun","sequence":"first","affiliation":[{"name":"Key Laboratory of Advanced Marine Materials, Key Laboratory of Marine Environmental Corrosion and Bio-Fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Huiwen","family":"Tian","sequence":"additional","affiliation":[{"name":"Key Laboratory of Advanced Marine Materials, Key Laboratory of Marine Environmental Corrosion and Bio-Fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5416-9176","authenticated-orcid":false,"given":"Fangxin","family":"Zou","sequence":"additional","affiliation":[{"name":"Department of Aeronautical and Aviation Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Weihua","family":"Li","sequence":"additional","affiliation":[{"name":"Henan Academy of Sciences, Zhengzhou 450046, China"},{"name":"North China University of Water Resources and Electric Power, Zhengzhou 450046, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0444-3066","authenticated-orcid":false,"given":"Yujie","family":"Qiang","sequence":"additional","affiliation":[{"name":"National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Baorong","family":"Hou","sequence":"additional","affiliation":[{"name":"Key Laboratory of Advanced Marine Materials, Key Laboratory of Marine Environmental Corrosion and Bio-Fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China"},{"name":"Department of Aeronautical and Aviation Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2024,7,30]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"147859","DOI":"10.1016\/j.cej.2023.147859","article-title":"Active\/passive protection and anti-UV waterborne epoxy coatings based on low defect functionalized PDA-GO-CeO2 material for excellent corrosion control","volume":"479","author":"Li","year":"2024","journal-title":"Chem. 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