{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T20:40:18Z","timestamp":1786135218905,"version":"build-2736575974"},"reference-count":60,"publisher":"MDPI AG","issue":"2","license":[{"start":{"date-parts":[[2025,1,20]],"date-time":"2025-01-20T00:00:00Z","timestamp":1737331200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Ministry of Science and Higher Education of the Russian Federation","award":["122011300078-1"],"award-info":[{"award-number":["122011300078-1"]}]},{"name":"Ministry of Science and Higher Education of the Russian Federation","award":["FFZS-2022-0013"],"award-info":[{"award-number":["FFZS-2022-0013"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>The behavior of low-carbon steels (LCSs), a high-strength steel and a nickel\u2013chromium alloy in HCl solutions in the presence of N-containing organic substances has been studied. N-containing organic substances that comprise 1,2,4-triazole in their structure (substance I and substance II) provide comprehensive protection of various steel grades from corrosion and hydrogen absorption by the metal bulk in HCl solutions under both isobaric and isochoric conditions. All the compounds studied reduce, to varying degrees, the concentration of hydrogen adsorbed and absorbed by steel in HCl solutions. The most promising way to expand the scope of application is to use substance I in HCl solutions for protecting steels from high-temperature corrosion as a mixture with hexamethylenetetramine (HMT). In 2 M HCl (100 \u00b0C) under isochoric conditions, a mixture of compound I and HMT exhibited an excellent result: the degree of protection of LCS against corrosion was 99.5%. Substance I and its mixture with HMT protect steels not only in pure HCl solutions, but also in environments contaminated with hydrogen sulfide, which is especially important for the acid stimulation of wells in oil production.<\/jats:p>","DOI":"10.3390\/ma18020464","type":"journal-article","created":{"date-parts":[[2025,1,20]],"date-time":"2025-01-20T10:32:15Z","timestamp":1737369135000},"page":"464","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Complex Inhibitor Protection of Some Steels in Hydrochloric Acid Solutions by 1,2,4-Triazole Derivatives"],"prefix":"10.3390","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7344-1961","authenticated-orcid":false,"given":"Yaroslav G.","family":"Avdeev","sequence":"first","affiliation":[{"name":"A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow 119071, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tatyana A.","family":"Nenasheva","sequence":"additional","affiliation":[{"name":"A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow 119071, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrey Y.","family":"Luchkin","sequence":"additional","affiliation":[{"name":"A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow 119071, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrey I.","family":"Marshakov","sequence":"additional","affiliation":[{"name":"A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow 119071, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yurii I.","family":"Kuznetsov","sequence":"additional","affiliation":[{"name":"A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow 119071, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,1,20]]},"reference":[{"key":"ref_1","first-page":"413","article-title":"Organic Inhibitors of Metal Corrosion in Acid Solutions. I. Mechanism of Protective Action, Russ","volume":"97","author":"Avdeev","year":"2023","journal-title":"J. Phys. Chem. A"},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Richardson, J.A., and Bhuiyan, M.S.H. (2017). Corrosion in Hydrogen Halides and Hydrohalic Acids. Reference Module in Materials Science and Materials Engineering, Elsevier.","DOI":"10.1016\/B978-0-12-803581-8.10372-8"},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Lyon, S., Richardson, T., Cottis, B., Lindsay, R., Scantlebury, D., Stott, H., and Graham, M. (2010). 2.22\u2014Corrosion in Hydrogen Halides and Hydrohalic Acids. Shreir\u2019s Corrosion, Elsevier.","DOI":"10.1016\/B978-044452787-5.00197-9"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"012134","DOI":"10.1088\/1742-6596\/1732\/1\/012134","article-title":"Metal Material Resistant to Hydrochloric Acid Corrosion","volume":"1732","author":"Fan","year":"2021","journal-title":"J. Phys. Conf. Ser."},{"key":"ref_5","doi-asserted-by":"crossref","unstructured":"Guo, B., Liu, X., and Tan, X. (2017). Chapter 13\u2014Acidizing. Petroleum Production Engineering, Gulf Professional Publishing. [2nd ed.].","DOI":"10.1016\/B978-0-12-809374-0.00013-1"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"012018","DOI":"10.1088\/1757-899X\/217\/1\/012018","article-title":"A Comparative Study of Different Acids used for Sandstone Acid Stimulation: A Literature Review","volume":"217","author":"Hong","year":"2017","journal-title":"IOP Conf. Ser. Mater. Sci. Eng."},{"key":"ref_7","first-page":"1261","article-title":"Corrosive electrolytes","volume":"9","author":"Verma","year":"2020","journal-title":"Int. J. Corros. Scale Inhib."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"165","DOI":"10.1179\/000705984798273100","article-title":"Application of Inhibitors for Acid Media","volume":"19","author":"Schmitt","year":"1984","journal-title":"Br. Corros. J."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.corsci.2014.04.044","article-title":"Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: A review","volume":"86","author":"Jackson","year":"2014","journal-title":"Corros. Sci."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1016\/j.jiec.2014.09.033","article-title":"Effect of halide ions on the corrosion inhibition efficiency of different organic species\u2014A review","volume":"21","author":"Umoren","year":"2015","journal-title":"J. Ind. Eng. Chem."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"565","DOI":"10.1016\/j.molliq.2018.02.045","article-title":"Organic corrosion inhibitors for industrial cleaning of ferrous and non-ferrous metals in acidic solutions: A review","volume":"256","author":"Goyal","year":"2018","journal-title":"J. Mol. Liq."},{"key":"ref_12","doi-asserted-by":"crossref","unstructured":"Gapsari, F., Madurani, K.A., Simanjuntak, F.M., Andoko, A., Wijaya, H., and Kurniawan, F. (2019). Corrosion Inhibition of Honeycomb Waste Extracts for 304 Stainless Steel in Sulfuric Acid Solution. Materials, 12.","DOI":"10.3390\/ma12132120"},{"key":"ref_13","doi-asserted-by":"crossref","unstructured":"Chen, Y., Chen, Z., and Zhuo, Y. (2022). Newly Synthesized Morpholinyl Mannich Bases as Corrosion Inhibitors for N80 Steel in Acid Environment. Materials, 15.","DOI":"10.3390\/ma15124218"},{"key":"ref_14","doi-asserted-by":"crossref","unstructured":"Sheit, H.M.K., Kani, S.M., Sathiq, M.A., Abuthahir, S.S.S., Subhapriya, P., Nivedhitha, K.S., Umarfarooq, M.A., Badruddin, I.A., Kamangar, S., and Shaik, A.S. (2024). Experimental Studies on the Effect of Expired Amiodarone Drug (EAD) as a Corrosion Inhibitor on Mild Steel in 1 M HCl. Materials, 17.","DOI":"10.3390\/ma17030751"},{"key":"ref_15","doi-asserted-by":"crossref","unstructured":"Li, D., Song, W., Zhang, J., Yin, C., Zhao, M., Chao, H., Zhang, J., Lei, Z., Fan, L., and Liu, W. (2023). Corrosion Inhibition Mechanism of Ultra-High-Temperature Acidizing Corrosion Inhibitor for 2205 Duplex Stainless Steel. Materials, 16.","DOI":"10.3390\/ma16062358"},{"key":"ref_16","doi-asserted-by":"crossref","unstructured":"Bin-Hudayb, N.S., Badr, E.E., and Hegazy, M.A. (2020). Adsorption and Corrosion Performance of New Cationic Gemini Surfactants Derivatives of Fatty Amido Ethyl Aminium Chloride with Ester Spacer for Mild Steel in Acidic Solutions. Materials, 13.","DOI":"10.3390\/ma13122790"},{"key":"ref_17","doi-asserted-by":"crossref","unstructured":"Yang, W., Wang, Q., Xu, K., Yin, Y., Bao, H., Li, X., Niu, L., and Chen, S. (2017). Enhanced Corrosion Resistance of Carbon Steel in Hydrochloric Acid Solution by Eriobotrya Japonica Thunb. Leaf Extract: Electrochemical Study. Materials, 10.","DOI":"10.3390\/ma10080956"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"2918","DOI":"10.3390\/ma8062918","article-title":"A Novel Schiff Base of 3-acetyl-4-hydroxy-6-methyl-(2H)pyran-2-one and 2,2\u2032-(ethylenedioxy)diethylamine as Potential Corrosion Inhibitor for Mild Steel in Acidic Medium","volume":"8","author":"Asegbeloyin","year":"2015","journal-title":"Materials"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"245t","DOI":"10.5006\/0010-9312-20.8.245t","article-title":"Hydrogen Absorption by and Dissolution Rate of Low-Carbon Steel in Sulfuric, Hydrochloric, Phosphoric and Nitric Acids","volume":"20","author":"Hudson","year":"1964","journal-title":"Corrosion"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"1007","DOI":"10.1016\/0013-4686(66)80039-7","article-title":"Permeation of hydrogen through steel by electrochemical transfer\u2014I. Influence of catalytic poisons","volume":"11","author":"Radhakrishnan","year":"1966","journal-title":"Electrochim. Acta"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"889","DOI":"10.1016\/0013-4686(67)80125-7","article-title":"Hydrogen permeation through iron and steel by electrochemical transfer\u2014II. Influence of metallurgical factors on hydrogen permeation","volume":"12","author":"Radhakrishnan","year":"1967","journal-title":"Electrochim. Acta"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1025","DOI":"10.1149\/1.2423335","article-title":"The Hydrogen Evolution Kinetics and Hydrogen Entry into a-Iron","volume":"112","author":"Bockris","year":"1965","journal-title":"J. Electrochem. Soc."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"284","DOI":"10.5006\/1.3280469","article-title":"Effect of Chloride Ions on Adsorption and Permeation of Hydrogen in Iron","volume":"53","author":"Allam","year":"1997","journal-title":"Corrosion"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"3676598","DOI":"10.1155\/2018\/3676598","article-title":"Electrochemical Determination of Hydrogen Entry to HSLA Steel during Pickling","volume":"2018","author":"Aromaa","year":"2018","journal-title":"Adv. Mater. Sci. Eng."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"1739","DOI":"10.1016\/0010-938X(95)00068-U","article-title":"The effect of molecular structure on hydrogen permeation and the corrosion inhibition of mild steel in acidic solutions","volume":"37","author":"Muralidharan","year":"1995","journal-title":"Corros. Sci."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"898","DOI":"10.1016\/j.matpr.2020.07.027","article-title":"The inhibitive effect of cloxacillin on mild steel corrosion in 2 N Sulphuric acid medium","volume":"36","author":"Vivekanand","year":"2021","journal-title":"Mater. Today Proc."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1007\/BF00242066","article-title":"Inhibiting and accelerating effects of aminophenols on the corrosion and permeation of hydrogen through mild steel in acidic solutions","volume":"24","author":"Rengamani","year":"1994","journal-title":"J. Appl. Electrochem."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"204","DOI":"10.1179\/000705900101501254","article-title":"Corrosion and hydrogen permeation inhibition for mild steel in HCl by isomers of organic compounds","volume":"35","author":"Holze","year":"2000","journal-title":"Br. Corros. J."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"e20230197","DOI":"10.1590\/1980-5373-mr-2023-0197","article-title":"Combining Electrochemical and Theoretical Analysis to Evaluate Hydrogen Permeation Inhibitors During Free Corrosion","volume":"27","author":"Carvalho","year":"2024","journal-title":"Mater. Res."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"1324","DOI":"10.1016\/j.jmrt.2021.12.068","article-title":"Inhibition effects of ionic and non-ionic derivatives of imidazole compounds on hydrogen permeation during carbon steel pickling","volume":"16","author":"Silva","year":"2022","journal-title":"J. Mater. Res. Technol."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1007\/BF02704314","article-title":"Effect of piperidones on hydrogen permeation and corrosion inhibition of mild steel in acidic solutions","volume":"112","author":"Muralidharan","year":"2000","journal-title":"J. Chem. Sci."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"475","DOI":"10.5006\/1.3280490","article-title":"Influence of Heterocyclic Anils on Corrosion Inhibition and Hydrogen Permeation Through Mild Steel in Acid Chloride Environments","volume":"53","author":"Quraishi","year":"1997","journal-title":"Corrosion"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"178","DOI":"10.5006\/0010-9312-36.4.178","article-title":"Effect of Anions and Organic Corrosion Inhibitors on the Rate of Hydrogen Penetration of Iron","volume":"36","author":"Saito","year":"1980","journal-title":"Corrosion"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"996","DOI":"10.5006\/1.3284822","article-title":"Macrocyclic Compounds as Corrosion Inhibitors","volume":"54","author":"Quraishi","year":"1998","journal-title":"Corrosion"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"1253","DOI":"10.1007\/BF00249927","article-title":"Influence of substituted benzothiazoles on corrosion in acid solution","volume":"26","author":"Quraishi","year":"1996","journal-title":"J. Appl. Electrochem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"1265","DOI":"10.1023\/A:1018440105425","article-title":"Inhibition of corrosion and hydrogen embrittlement of a HSLA steel in 0.5m H2SO4 by nitrile compounds","volume":"27","author":"Agrawal","year":"1997","journal-title":"J. Appl. Electrochem."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"129647","DOI":"10.1155\/2011\/129647","article-title":"A Comparative Study of the Inhibitory Effect of the Extracts of Ocimum sanctum, Aegle marmelos, and Solanum trilobatum on the Corrosion of Mild Steel in Hydrochloric Acid Medium","volume":"2011","author":"Shyamala","year":"2011","journal-title":"Int. J. Corros."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"852827","DOI":"10.1155\/2012\/852827","article-title":"The Inhibitory Action of the Extracts of Adathoda vasica, Eclipta alba, and Centella asiatica on the Corrosion of Mild Steel in Hydrochloric Acid Medium: A Comparative Study","volume":"2012","author":"Shyamala","year":"2012","journal-title":"Int. J. Corros."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"541","DOI":"10.5006\/1.3278490","article-title":"Development of Novel Acidizing Inhibitors for Carbon Steel Corrosion in 15% Boiling Hydrochloric Acid","volume":"64","author":"Muralidharan","year":"2008","journal-title":"Corrosion"},{"key":"ref_40","doi-asserted-by":"crossref","unstructured":"Avdeev, Y.G., Nenasheva, T.A., Luchkin, A.Y., Marshakov, A.I., and Kuznetsov, Y.I. (2022). Effect of Quaternary Ammonium Salts and 1,2,4-Triazole Derivatives on Hydrogen Absorption by Mild Steel in Hydrochloric Acid Solution. Materials, 15.","DOI":"10.3390\/ma15196989"},{"key":"ref_41","doi-asserted-by":"crossref","unstructured":"Avdeev, Y.G., Nenasheva, T.A., Luchkin, A.Y., Marshakov, A.I., and Kuznetsov, Y.I. (2023). Thin 1,2,4-Triazole Films for the Inhibition of Carbon Steel Corrosion in Sulfuric Acid Solution. Coatings, 13.","DOI":"10.3390\/coatings13071221"},{"key":"ref_42","doi-asserted-by":"crossref","unstructured":"Avdeev, Y.G., Nenasheva, T.A., Luchkin, A.Y., Marshakov, A.I., and Kuznetsov, Y.I. (2023). Thin Films of a Complex Polymer Compound for the Inhibition of Iron Alloy Corrosion in a H3PO4 Solution. Polymers, 15.","DOI":"10.3390\/polym15214280"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"1026","DOI":"10.1016\/j.molliq.2015.08.031","article-title":"Thermodynamic, electrochemical and quantum chemical evaluation of some triazole Schiff bases as mild steel corrosion inhibitors in acid media","volume":"211","author":"Chaitra","year":"2015","journal-title":"J. Mol. Liq."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"122420","DOI":"10.1016\/j.matchemphys.2019.122420","article-title":"Towards a deeper understanding of the inhibition mechanism of a new 1,2,3-triazole derivative for mild steel corrosion in the hydrochloric acid solution using coupled experimental and theoretical methods","volume":"241","author":"Boutouil","year":"2020","journal-title":"Mater. Chem. Phys."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"124604","DOI":"10.1016\/j.colsurfa.2020.124604","article-title":"Exploring the potential of a new 1,2,4-triazole derivative for corrosion protection of carbon steel in HCl: A computational and experimental evaluation","volume":"597","author":"Naciri","year":"2020","journal-title":"Colloid. Surf. A"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"113508","DOI":"10.1016\/j.molliq.2020.113508","article-title":"Corrosion inhibition property of azomethine functionalized triazole derivatives in 1 molL\u22121 HCl medium for mild steel: Experimental and theoretical exploration","volume":"313","author":"Murmu","year":"2020","journal-title":"J. Mol. Liq."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"100242","DOI":"10.1016\/j.cdc.2019.100242","article-title":"Performance and computational studies of new soluble triazole as corrosion inhibitor for carbon steel in HCl","volume":"22","author":"Rouifi","year":"2019","journal-title":"Chem. Data Collect."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"548","DOI":"10.1134\/S2070205117030236","article-title":"3,5-Diaryl-4-amino-1,2,4-triazole Derivatives as Effective Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution: Correlation between Anti-corrosion Activity and Chemical Structure","volume":"53","author":"Tourabi","year":"2017","journal-title":"Prot. Met. Phys. Chem. Surf."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"112631","DOI":"10.1016\/j.molliq.2020.112631","article-title":"The effect of the alkyl chain length on corrosion inhibition performances of 1,2,4-triazole-based compounds for mild steel in 1.0 M HCl: Insights from experimental and theoretical studies","volume":"303","author":"Aslam","year":"2020","journal-title":"J. Mol. Liq."},{"key":"ref_50","doi-asserted-by":"crossref","unstructured":"Alkadir Aziz, I.A., Annon, I.A., Abdulkareem, M.H., Hanoon, M.M., Alkaabi, M.H., Shaker, L.M., Alamiery, A.A., Wan Isahak, W.N.R., and Takriff, M.S. (2021). Insights into Corrosion Inhibition Behavior of a 5-Mercapto-1,2,4-triazole Derivative for Mild Steel in Hydrochloric Acid Solution: Experimental and DFT Studies. Lubricants, 9.","DOI":"10.3390\/lubricants9120122"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1016\/j.corsci.2019.01.019","article-title":"Green synthesis of 1-benzyl-4-phenyl-1H-1,2,3-triazole, its application as corrosion inhibitor for mild steel in acidic medium and new approach of classical electrochemical analyses","volume":"149","author":"Alvarez","year":"2019","journal-title":"Corros. Sci."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"4147","DOI":"10.1039\/D0RA09679B","article-title":"Novel triazole derivatives as ecological corrosion inhibitors for mild steel in 1.0 M HCl: Experimental and theoretical approach","volume":"11","author":"Nahle","year":"2021","journal-title":"RSC Adv."},{"key":"ref_53","doi-asserted-by":"crossref","unstructured":"Avdeev, Y.G., Nenasheva, T.A., Luchkin, A.Y., Marshakov, A.I., and Kuznetsov, Y.I. (2024). Complex Protection of Some Steels in Sulfuric Acid Solutions by 1,2,4-Triazole Derivatives. Materials, 17.","DOI":"10.3390\/ma17194728"},{"key":"ref_54","unstructured":"Ivanov, E.S. (1986). Metal Corrosion Inhibitors in Acidic Media, Metallurgy. (In Russian)."},{"key":"ref_55","unstructured":"Petrukhin, O.M. (1992). Chemical Methods of Analysis, Chemistry. (In Russian)."},{"key":"ref_56","first-page":"90","article-title":"The adsorption and diffusion of electrolytic hydrogen in palladium","volume":"270A","author":"Devanathan","year":"1962","journal-title":"Proc. R. Soc. Ser. A Math. Phys. Sci."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"619","DOI":"10.1149\/1.2426195","article-title":"Mechanism of Hydrogen Evolution on Iron in Acid Solutions by Determination of Permeation Rates","volume":"111","author":"Devanathan","year":"1964","journal-title":"Electrochem. Soc."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"2463","DOI":"10.1149\/1.2097429","article-title":"Analysis of Hydrogen Evolution and Entry into Metals for the Discharge-Recombination Process","volume":"136","author":"Iyer","year":"1989","journal-title":"J. Electrochem. Soc."},{"key":"ref_59","unstructured":"Popov, B.N., Lee, J.-W., and Djukic, M.B. (2018). Handbook of Environmental Degradation of Materials, Elsevier Inc.. [3rd ed.]."},{"key":"ref_60","unstructured":"Reshetnikov, S.M. (1986). Inhibitors of Acid Corrosion of Metals, Chemistry."}],"container-title":["Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1944\/18\/2\/464\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T10:32:15Z","timestamp":1759919535000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1944\/18\/2\/464"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,20]]},"references-count":60,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2025,1]]}},"alternative-id":["ma18020464"],"URL":"https:\/\/doi.org\/10.3390\/ma18020464","relation":{},"ISSN":["1996-1944"],"issn-type":[{"value":"1996-1944","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1,20]]}}}