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Addressing the limitations of traditional co-precipitation methods\u2014such as rapid reaction rates leading to excessive crystal defects and interstitial water content\u2014the research team introduced a synergistic approach combining non-aqueous phase precursor synthesis and controlled water-concentration secondary crystallization. The process involves preparing a PB precursor in a glycerol system, followed by secondary crystallization in a water-\/ethanol-mixed solvent with a precisely regulated water content, achieving the dual objectives of water content reduction and crystal morphology optimization. Systematic characterization revealed that water concentration during secondary synthesis critically influences the material\u2019s crystal structure, morphological features, and water content. The optimized PB50-24 material exhibited a highly regular cubic morphology with a sodium content of 9.2% and a remarkably low interstitial water content of 2.1%. Electrochemical tests demonstrated outstanding performance\u2014an initial charge\u2013discharge capacity of 120 mAh g\u22121 at a 1C rate, the retention of 105 mAh g\u22121 after 100 cycles, and a high rate capability of 86 mAh g\u22121 at 10C, representing significant improvements in cycling stability and rate performance over conventional methods. This work not only establishes a cost-effective, scalable synthesis pathway for Prussian blue materials but also provides theoretical guidance for developing other metal-based Prussian blue analogs, offering substantial value for advancing the industrial application of sodium-ion batteries in next-generation energy storage systems.<\/jats:p>","DOI":"10.3390\/ma18071455","type":"journal-article","created":{"date-parts":[[2025,3,25]],"date-time":"2025-03-25T08:42:35Z","timestamp":1742892155000},"page":"1455","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Synthesis of Low-Defect Iron-Based Prussian Blue with Low Water Content for High-Stability Sodium-Ion Batteries"],"prefix":"10.3390","volume":"18","author":[{"given":"Zhaoyue","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shenglin","family":"Zhong","sequence":"additional","affiliation":[{"name":"Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China"},{"name":"College of Chemistry and Materials Science, Longyan University, Longyan 364012, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bingcheng","family":"Zhou","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Science, Longyan University, Longyan 364012, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Denglian","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zehai","family":"Qiu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Science, Longyan University, Longyan 364012, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruijuan","family":"Zheng","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Science, Longyan University, Longyan 364012, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenhao","family":"Zhao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Science, Longyan University, Longyan 364012, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3034-3798","authenticated-orcid":false,"given":"Jiangcong","family":"Zhou","sequence":"additional","affiliation":[{"name":"Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China"},{"name":"College of Chemistry and Materials Science, Longyan University, Longyan 364012, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,3,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1800561","DOI":"10.1002\/adma.201800561","article-title":"30 years of lithium-ion batteries","volume":"30","author":"Li","year":"2018","journal-title":"Adv. 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