{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,7]],"date-time":"2026-02-07T12:37:55Z","timestamp":1770467875249,"version":"3.49.0"},"reference-count":93,"publisher":"MDPI AG","issue":"8","license":[{"start":{"date-parts":[[2025,4,11]],"date-time":"2025-04-11T00:00:00Z","timestamp":1744329600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"INSPIRE POC 488\/1\/1\/2014+\/127725","award":["353\/390028\/23.09.2021"],"award-info":[{"award-number":["353\/390028\/23.09.2021"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>In this work, we have employed an advanced method of solvent vapor annealing to expose spin-cast thin films made from various lamellar and micellar block copolymers to generous amounts of different types of solvent vapors, with the final goal of stimulating the films\u2019 self-assembly into (hierarchically) ordered structures. As revealed by atomic force microscopy measurements, periodic lamellar nanostructures of molecular dimensions based on poly(4-vinylpyridine)-b-polybutadiene and poly(2-vinylpyridine)-b-polybutadiene, as well as micellar structures further packed into either (parallel) stripe-like or honeycomb-resembling configurations based on poly(2-vinylpyridine)-b-poly(tert-butyl methacrylate)-b-poly(methacrylate cyclohexyl), were successfully produced through processing.<\/jats:p>","DOI":"10.3390\/ma18081759","type":"journal-article","created":{"date-parts":[[2025,4,11]],"date-time":"2025-04-11T10:05:51Z","timestamp":1744365951000},"page":"1759","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Self-Assembly of Lamellar\/Micellar Block Copolymers Induced Through Their Rich Exposure to Various Solvent Vapors: An AFM Study"],"prefix":"10.3390","volume":"18","author":[{"given":"Iulia","family":"Babutan","sequence":"first","affiliation":[{"name":"Interdisciplinary Research Institute on Bio-Nano-Sciences, Babe\u0219-Bolyai University, 400271 Cluj-Napoca, Romania"},{"name":"Department of Physics of Condensed Matter and Advanced Technologies, Faculty of Physics, Babe\u0219-Bolyai University, 400084 Cluj-Napoca, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3657-1492","authenticated-orcid":false,"given":"Leonard Ionut","family":"Atanase","sequence":"additional","affiliation":[{"name":"Department of Biomaterials, Faculty of Medicine, \u201cApollonia\u201d University of Iasi, 700511 Iasi, Romania"},{"name":"Academy of Romanian Scientists, 050045 Bucharest, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ioan","family":"Botiz","sequence":"additional","affiliation":[{"name":"Interdisciplinary Research Institute on Bio-Nano-Sciences, Babe\u0219-Bolyai University, 400271 Cluj-Napoca, Romania"},{"name":"Department of Physics of Condensed Matter and Advanced Technologies, Faculty of Physics, Babe\u0219-Bolyai University, 400084 Cluj-Napoca, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2025,4,11]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"32","DOI":"10.1063\/1.882522","article-title":"Block Copolymers\u2014Designer Soft Materials","volume":"52","author":"Bates","year":"1999","journal-title":"Phys. Today"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"434","DOI":"10.1126\/science.1215368","article-title":"Multiblock Polymers: Panacea or Pandora\u2019s Box?","volume":"336","author":"Bates","year":"2012","journal-title":"Science"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"1253","DOI":"10.1021\/acs.macromol.6b02569","article-title":"50th Anniversary Perspective: Polymers with Complex Architectures","volume":"50","author":"Polymeropoulos","year":"2017","journal-title":"Macromolecules"},{"key":"ref_4","doi-asserted-by":"crossref","unstructured":"Feng, H., Lu, X., Wang, W., Kang, N.-G., and Mays, J.W. (2017). Block Copolymers: Synthesis, Self-Assembly, and Applications. Polymers, 9.","DOI":"10.3390\/polym9100494"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"422","DOI":"10.1063\/1.111118","article-title":"Mesoscopic Self-Assembly of Gold Islands on Deblock-Copolymer Films","volume":"64","author":"Morkved","year":"1994","journal-title":"Appl. Phys. Lett."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"731","DOI":"10.1002\/adma.19950070811","article-title":"Noble Metal Loaded Block Lonomers: Micelle Organization, Adsorption of Free Chains and Formation of Thin Films","volume":"7","author":"Spatz","year":"1995","journal-title":"Adv. Mater."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"1401","DOI":"10.1126\/science.276.5317.1401","article-title":"Block Copolymer Lithography: Periodic Arrays of ~1011 Holes in 1 Square Centimeter","volume":"276","author":"Park","year":"1997","journal-title":"Science"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"2126","DOI":"10.1126\/science.290.5499.2126","article-title":"Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates","volume":"290","author":"Schotter","year":"2000","journal-title":"Science"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"2315","DOI":"10.1021\/nl801105s","article-title":"Highly Aligned Ultrahigh Density Arrays of Conducting Polymer Nanorods Using Block Copolymer Templates","volume":"8","author":"Lee","year":"2008","journal-title":"Nano Lett."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1021\/nn304122b","article-title":"Chemically Enhancing Block Copolymers for Block-Selective Synthesis of Self-Assembled Metal Oxide Nanostructures","volume":"7","author":"Kamcev","year":"2013","journal-title":"ACS Nano"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"11010","DOI":"10.1021\/ja064148f","article-title":"Photoinduced Alignment of Nanocylinders by Supramolecular Cooperative Motions","volume":"128","author":"Yu","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"7178","DOI":"10.1021\/ma501803g","article-title":"Pathways toward Photoinduced Alignment Switching in Liquid Crystalline Block Copolymer Films","volume":"47","author":"Sano","year":"2014","journal-title":"Macromolecules"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"672","DOI":"10.1021\/ma5018742","article-title":"Control of Air-Interface-Induced Perpendicular Nanocylinder Orientation in Liquid Crystal Block Copolymer Films by a Surface-Covering Method","volume":"48","author":"Komura","year":"2015","journal-title":"Macromolecules"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"21935","DOI":"10.1021\/acsami.9b06573","article-title":"Printed Thin Diblock Copolymer Films with Dense Magnetic Nanostructure","volume":"11","author":"Xia","year":"2019","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"2395","DOI":"10.1021\/acs.macromol.7b02288","article-title":"Photonic Resins: Designing Optical Appearance via Block Copolymer Self-Assembly","volume":"51","author":"Song","year":"2018","journal-title":"Macromolecules"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"3426","DOI":"10.1021\/acsanm.8b00632","article-title":"Highly Ordered Titanium Dioxide Nanostructures via a Simple One-Step Vapor-Inclusion Method in Block Copolymer Films","volume":"1","author":"Giraud","year":"2018","journal-title":"ACS Appl. Nano Mater."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"894","DOI":"10.1021\/acsanm.7b00300","article-title":"Superparamagnetic Iron Oxide Nanoparticles Stabilized with Multidentate Block Copolymers for Optimal Vascular Contrast in T1-Weighted Magnetic Resonance Imaging","volume":"1","author":"Xiao","year":"2018","journal-title":"ACS Appl. Nano Mater."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"342","DOI":"10.1021\/acsapm.9b00834","article-title":"Aqueous-Phase Synthesis of Hyaluronic Acid-Based Hydrogel Nanoparticles for Molecular Storage and Enzymatic Release","volume":"2","author":"Lee","year":"2020","journal-title":"ACS Appl. Polym. Mater."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"7778","DOI":"10.1021\/acsapm.2c01327","article-title":"H2O2-Responsive Nanocarriers Prepared by RAFT-Mediated Polymerization-Induced Self-Assembly of N-(2-(Methylthio)Ethyl)Acrylamide for Biomedical Applications","volume":"4","author":"Phan","year":"2022","journal-title":"ACS Appl. Polym. Mater."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"2503","DOI":"10.1021\/acsapm.9b00616","article-title":"Redox-Driven Disassembly of Polymer\u2013Chlorambucil Polyprodrug: Delivery of Anticancer Nitrogen Mustard and DNA Alkylation","volume":"1","author":"Saha","year":"2019","journal-title":"ACS Appl. Polym. Mater."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"3154","DOI":"10.1021\/acs.chemmater.8b04936","article-title":"Engineering Self-Assembly of a High-\u03c7 Block Copolymer for Large-Area Fabrication of Transistors Based on Functional Graphene Nanoribbon Arrays","volume":"31","author":"Garnier","year":"2019","journal-title":"Chem. Mater."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"4018","DOI":"10.1021\/acsnano.8b08013","article-title":"Contrasting Chemistry of Block Copolymer Films Controls the Dynamics of Protein Self-Assembly at the Nanoscale","volume":"13","author":"Stel","year":"2019","journal-title":"ACS Nano"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"4458","DOI":"10.1021\/acs.nanolett.9b01248","article-title":"Synthesis, Simulation, and Self-Assembly of a Model Amphiphile To Push the Limits of Block Polymer Nanopatterning","volume":"19","author":"Barreda","year":"2019","journal-title":"Nano Lett."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"4351","DOI":"10.1021\/acsnano.7b09122","article-title":"Computational Design of High-\u03c7 Block Oligomers for Accessing 1 Nm Domains","volume":"12","author":"Chen","year":"2018","journal-title":"ACS Nano"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"176","DOI":"10.1021\/acs.chemmater.6b02967","article-title":"Nanopatterning via Solvent Vapor Annealing of Block Copolymer Thin Films","volume":"29","author":"Jin","year":"2017","journal-title":"Chem. Mater."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"187","DOI":"10.1146\/annurev-chembioeng-061114-123209","article-title":"Defects in the Self-Assembly of Block Copolymers and Their Relevance for Directed Self-Assembly","volume":"6","author":"Li","year":"2015","journal-title":"Annu. Rev. Chem. Biomol. Eng."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"1105","DOI":"10.1063\/1.1627324","article-title":"Phase Behavior in Thin Films of Cylinder-Forming ABA Block Copolymers: Experiments","volume":"120","author":"Knoll","year":"2004","journal-title":"J. Chem. Phys."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"800","DOI":"10.1209\/epl\/i2004-10126-5","article-title":"Pattern Coarsening in a 2D Hexagonal System","volume":"67","author":"Harrison","year":"2004","journal-title":"Europhys. Lett."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"061803","DOI":"10.1103\/PhysRevE.71.061803","article-title":"Ordering Mechanisms in Two-Dimensional Sphere-Forming Block Copolymers","volume":"71","author":"Vega","year":"2005","journal-title":"Phys. Rev. E"},{"key":"ref_30","doi-asserted-by":"crossref","unstructured":"Handrea-Dragan, M., and Botiz, I. (2021). Multifunctional Structured Platforms: From Patterning of Polymer-Based Films to Their Subsequent Filling with Various Nanomaterials. Polymers, 13.","DOI":"10.3390\/polym13030445"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1852","DOI":"10.1103\/PhysRevLett.62.1852","article-title":"Neutron Reflectivity Studies of the Surface-Induced Ordering of Deblock Copolymer Films","volume":"62","author":"Anastasiadis","year":"1989","journal-title":"Phys. Rev. Lett."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1016\/0001-8686(76)80009-7","article-title":"Block and Graft Copolymer Micelles in Solution","volume":"6","author":"Tuzar","year":"1976","journal-title":"Adv. Colloid Interface Sci."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"1107","DOI":"10.1016\/S0079-6700(03)00015-7","article-title":"Micellization of Block Copolymers","volume":"28","author":"Riess","year":"2003","journal-title":"Prog. Polym. Sci."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1007\/12_048","article-title":"Block Copolymer Micelles","volume":"190","author":"Gohy","year":"2005","journal-title":"Adv. Polym. Sci."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1016\/j.jcis.2019.04.065","article-title":"Micellization of Poly(2-Vinylpyrridine)-b-Poly(Cyclohexyl Methacrylate) (P2VP-b-PCHMA) Block Copolymers and Their Interpolymer Complex Formation in Non-Aqueous Medium","volume":"549","author":"Atanase","year":"2019","journal-title":"J. Colloid Interface Sci."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"364","DOI":"10.1039\/D2TC03971K","article-title":"Prominent Processing Techniques to Manipulate Semiconducting Polymer Microstructures","volume":"11","author":"Botiz","year":"2023","journal-title":"J. Mater. Chem. C"},{"key":"ref_37","first-page":"1615","article-title":"Solvent Vapor Annealed Block Copolymer Films on Organosilane Self-Assembled Monolayers","volume":"23","author":"Harant","year":"2005","journal-title":"J. Vac. Sci. Technol. B Microelectron. Nanometer Struct. Process. Meas. Phenom."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"7301","DOI":"10.1021\/ma0497761","article-title":"Morphology Development of Ultrathin Symmetric Diblock Copolymer Film via Solvent Vapor Treatment","volume":"37","author":"Xuan","year":"2004","journal-title":"Macromolecules"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"1703","DOI":"10.1557\/PROC-0961-O17-03","article-title":"Directed Self-Assembly of Thin Block Copolymer Films under Controlled Atmosphere","volume":"961","author":"Kim","year":"2006","journal-title":"MRS Proc."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"7567","DOI":"10.1021\/ma401112y","article-title":"Directed Block Copolymer Thin Film Self-Assembly: Emerging Trends in Nanopattern Fabrication","volume":"46","author":"Luo","year":"2013","journal-title":"Macromolecules"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"5399","DOI":"10.1021\/ma400735a","article-title":"Solvent Vapor Annealing of Block Polymer Thin Films","volume":"46","author":"Sinturel","year":"2013","journal-title":"Macromolecules"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"1181","DOI":"10.1021\/ma061163w","article-title":"Solvent Annealed Thin Films of Asymmetric Polyisoprene\u2212Polylactide Diblock Copolymers","volume":"40","author":"Cavicchi","year":"2007","journal-title":"Macromolecules"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"1351","DOI":"10.1021\/nl104496r","article-title":"Gradient Solvent Vapor Annealing of Block Copolymer Thin Films Using a Microfluidic Mixing Device","volume":"11","author":"Albert","year":"2011","journal-title":"Nano Lett."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"2540","DOI":"10.1002\/adma.200802855","article-title":"Solvent-Vapor-Induced Tunability of Self-Assembled Block Copolymer Patterns","volume":"21","author":"Jung","year":"2009","journal-title":"Adv. Mater."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"2046","DOI":"10.1021\/nl070924l","article-title":"Orientation-Controlled Self-Assembled Nanolithography Using a Polystyrene\u2212Polydimethylsiloxane Block Copolymer","volume":"7","author":"Jung","year":"2007","journal-title":"Nano Lett."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"657","DOI":"10.1103\/PhysRevLett.75.657","article-title":"Mechanisms of Chain Diffusion in Lamellar Block Copolymers","volume":"75","author":"Lodge","year":"1995","journal-title":"Phys. Rev. Lett."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"525","DOI":"10.1146\/annurev.pc.41.100190.002521","article-title":"Block Copolymer Thermodynamics: Theory and Experiment","volume":"41","author":"Bates","year":"1990","journal-title":"Annu. Rev. Phys. Chem."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"1602","DOI":"10.1021\/ma60078a047","article-title":"Theory of Microphase Separation in Block Copolymers","volume":"13","author":"Leibler","year":"1980","journal-title":"Macromolecules"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"035501","DOI":"10.1103\/PhysRevLett.89.035501","article-title":"Phase Behavior in Thin Films of Cylinder-Forming Block Copolymers","volume":"89","author":"Knoll","year":"2002","journal-title":"Phys. Rev. Lett."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"8052","DOI":"10.1021\/nn302641z","article-title":"Morphology Control in Block Copolymer Films Using Mixed Solvent Vapors","volume":"6","author":"Gotrik","year":"2012","journal-title":"ACS Nano"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"993","DOI":"10.1039\/b719946e","article-title":"The Influence of Protic Non-Solvents Present in the Environment on Structure Formation of Poly(\u03b3-Benzyl-L-Glutamate in Organic Solvents","volume":"4","author":"Botiz","year":"2008","journal-title":"Soft Matter"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"125881","DOI":"10.1016\/j.polymer.2023.125881","article-title":"Self-Assembly of Block Copolymers on Surfaces Exposed to Space-Confined Solvent Vapor Annealing","volume":"273","author":"Babutan","year":"2023","journal-title":"Polymer"},{"key":"ref_53","doi-asserted-by":"crossref","unstructured":"Babutan, I., Todor-Boer, O., Atanase, L.I., Vulpoi, A., and Botiz, I. (2023). Crystallization of Poly(Ethylene Oxide)-Based Triblock Copolymers in Films Swollen-Rich in Solvent Vapors. Coatings, 13.","DOI":"10.3390\/coatings13050918"},{"key":"ref_54","doi-asserted-by":"crossref","unstructured":"Babutan, I., Todor-Boer, O., Atanase, L.I., Vulpoi, A., and Botiz, I. (2023). Self-Assembly of Block Copolymers in Thin Films Swollen-Rich in Solvent Vapors. Polymers, 15.","DOI":"10.3390\/polym15081900"},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1016\/j.cis.2006.05.016","article-title":"Aggregation of Water-Soluble Block Copolymers in Aqueous Solutions: Recent Trends","volume":"123\u2013126","author":"Nakashima","year":"2006","journal-title":"Adv. Colloid Interface Sci."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"731","DOI":"10.1007\/s11814-010-0216-5","article-title":"Polymeric Nanoparticles, Micelles and Polymersomes from Amphiphilic Block Copolymer","volume":"27","author":"Cho","year":"2000","journal-title":"Korean J. Chem. Eng."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"465","DOI":"10.1080\/1385772X.2012.688328","article-title":"Polymeric Micelles: Authoritative Aspects for Drug Delivery","volume":"15","author":"Kulthe","year":"2012","journal-title":"Des. Monomers Polym."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1155\/2013\/340315","article-title":"Polymeric Micelles, a Promising Drug Delivery System to Enhance Bioavailability of Poorly Water-Soluble Drugs","volume":"340315","author":"Xu","year":"2013","journal-title":"J. Drug Deliv."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"17028","DOI":"10.1039\/C3RA47370H","article-title":"Polymeric Micelles as Drug Delivery Vehicles","volume":"4","author":"Ahmad","year":"2014","journal-title":"RSC Adv."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"3254","DOI":"10.1021\/ma7026148","article-title":"Multiple Morphologies, Phase Transitions, and Cross-Linking of Crew-Cut Aggregates of Polybutadiene-Block-Poly(2-Vinylpyridine) Diblock Copolymers","volume":"41","author":"Walther","year":"2008","journal-title":"Macromolecules"},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"20120306","DOI":"10.1098\/rsta.2012.0306","article-title":"Pattern Transfer Using Block Copolymers","volume":"371","author":"Gu","year":"2013","journal-title":"Phil. Trans. R. Soc. A"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"5619","DOI":"10.1039\/C6TA10838E","article-title":"Interconnected Ionic Domains Enhance Conductivity in Microphase Separated Block Copolymer Electrolytes","volume":"5","author":"Arges","year":"2017","journal-title":"J. Mater. Chem. A"},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"1343","DOI":"10.1002\/smll.200801409","article-title":"Preparation of Metallic Line Patterns from Functional Block Copolymers","volume":"5","author":"Park","year":"2009","journal-title":"Small"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"9373","DOI":"10.1021\/acs.macromol.7b01590","article-title":"Phase Behavior of Poly(2-Vinylpyridine)-Block-Poly(4-Vinylpyridine) Copolymers Containing Gold Nanoparticles","volume":"50","author":"Lee","year":"2017","journal-title":"Macromolecules"},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"9279","DOI":"10.1021\/ma0715730","article-title":"Quantitative in Situ Coupling of Living Diblock Copolymers for the Preparation of Amphiphilic Coil\u2212Rod\u2212Coil Triblock Copolymer Poly(2-Vinylpyridine)-b-Poly(n-Hexyl Isocyanate)-b-Poly(2-Vinylpyridine)","volume":"40","author":"Rahman","year":"2007","journal-title":"Macromolecules"},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"10892","DOI":"10.1021\/ja961713d","article-title":"Self-Ordering of Diblock Copolymers from Solution","volume":"118","author":"Li","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"659","DOI":"10.1002\/pol.1977.170150313","article-title":"Anionic Polymerization of 2-Vinylpyridine Initiated by Symmetrical Organomagnesium Compounds in Tetrahydrofuran","volume":"15","author":"Soum","year":"1977","journal-title":"J. Polym. Sci. Polym. Chem. Ed."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"19","DOI":"10.1016\/j.colsurfa.2014.01.026","article-title":"Stabilization of Non-Aqueous Emulsions by Poly(2-Vinylpyridine)-b-Poly(Butadiene) Block Copolymers","volume":"458","author":"Atanase","year":"2014","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"4490","DOI":"10.1021\/cg400971g","article-title":"Reversible Nucleation, Growth, and Dissolution of Poly(\u03b3-Benzyl l-Glutamate) Hexagonal Columnar Liquid Crystals by Addition and Removal of a Nonsolvent","volume":"13","author":"Jahanshahi","year":"2013","journal-title":"Cryst. Growth Des."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"1470","DOI":"10.1021\/ma3024602","article-title":"Crystallization of Poly(\u03b3-Benzyl L-Glutamate) in Thin Film Solutions: Structure and Pattern Formation","volume":"46","author":"Jahanshahi","year":"2013","journal-title":"Macromolecules"},{"key":"ref_71","doi-asserted-by":"crossref","unstructured":"B\u0103bu\u021ban, M., and Botiz, I. (2024). Morphological Characteristics of Biopolymer Thin Films Swollen-Rich in Solvent Vapors. Biomimetics, 9.","DOI":"10.3390\/biomimetics9070396"},{"key":"ref_72","doi-asserted-by":"crossref","unstructured":"Cotoarb\u0103, Y., Todor-Boer, O., and Botiz, I. (2025). Crystals of Nonfullerene Acceptors Generated by Rich Exposure to Solvent Vapors. Cryst. Growth Des.","DOI":"10.1021\/acs.cgd.5c00192"},{"key":"ref_73","doi-asserted-by":"crossref","unstructured":"Todor-Boer, O., Farc\u0103u, C., and Botiz, I. (2024). Large Enhancement of Photoluminescence Obtained in Thin Polyfluorene Films of Optimized Microstructure. Polymers, 16.","DOI":"10.3390\/polym16162278"},{"key":"ref_74","unstructured":"Flory, P.J. (1953). Statistical Thermodynamics of Polymer Solutions. Principles of Polymer Chemistry, Cornell University Press."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"1141","DOI":"10.1002\/pen.760271506","article-title":"Thermodynamic Interaction in Polybutadiene\/Solute Systems by Inverse Gas Chromatography","volume":"27","author":"Tseng","year":"1987","journal-title":"Polym. Eng. Sci."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"434","DOI":"10.1246\/bcsj.39.434","article-title":"Studies of Poly-2-Vinylpyridine. II. Solubilities in Various Solvents","volume":"39","author":"Arichi","year":"1966","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"867","DOI":"10.1016\/j.cclet.2010.12.042","article-title":"Facile Fabrication of Porous Pure and Ag Nanoparticle-Doped Poly(4-Vinylpyridine) Films at the Liquid\u2013Liquid Interfaces","volume":"22","author":"Ren","year":"2011","journal-title":"Chin. Chem. Lett."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"87469","DOI":"10.1039\/C6RA07223B","article-title":"Temperature-Responsive Properties of Poly(4-Vinylpyridine) Coatings: Influence of Temperature on the Wettability, Morphology, and Protein Adsorption","volume":"6","author":"Raczkowska","year":"2016","journal-title":"RSC Adv."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"9727","DOI":"10.1021\/ma302159p","article-title":"Helical Phase Driven by Solvent Evaporation in Self-Assembly of Poly(4-Vinylpyridine)-Block-Poly(l-Lactide) Chiral Block Copolymers","volume":"45","author":"Chung","year":"2012","journal-title":"Macromolecules"},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"5601","DOI":"10.1016\/S0032-3861(99)00810-1","article-title":"Preparation and Characterization of a Linear Poly(4-Vinyl Pyridine)-b-Polybutadiene-b-Poly(4-Vinylpyridine) Using a t-Butyllithium\/m-Diisopropenylbenzene Diadduct as a Dicarbanion Initiator","volume":"41","author":"Li","year":"2000","journal-title":"Polymer"},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"1786","DOI":"10.1021\/la902505q","article-title":"Protein Resistance of PNIPAAm Brushes: Application to Switchable Protein Adsorption","volume":"26","author":"Burkert","year":"2010","journal-title":"Langmuir"},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"329","DOI":"10.1016\/0032-3861(88)90342-4","article-title":"Measurement of the Interaction Force Profiles between Block Copolymers of Poly(2-Vinylpyridine)\/Poly(t-Butylstyrene) in a Good Solvent","volume":"29","author":"Ansarifar","year":"1988","journal-title":"Polymer"},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"3789","DOI":"10.1002\/adma.200900756","article-title":"Self-Assembled Nanoscale Ring Arrays from a Polystyrene-b-Polyferrocenylsilane-b-Poly(2-Vinylpyridine)Triblock Terpolymer Thin Film","volume":"21","author":"Chuang","year":"2009","journal-title":"Adv. Mater."},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"7935","DOI":"10.1016\/j.polymer.2004.09.021","article-title":"Ellipsometric Determination of Flory-Huggins Interaction Parameters in Solution","volume":"45","author":"Elbs","year":"2004","journal-title":"Polymer"},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"9631","DOI":"10.1021\/ma301611c","article-title":"Characterization of Block Copolymer Self-Assembly: From Solution to Nanoporous Membranes","volume":"45","author":"Schmidt","year":"2012","journal-title":"Macromolecules"},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"9817","DOI":"10.1021\/acs.langmuir.1c01384","article-title":"Persistent Micelle Corona Chemistry Enables Constant Micelle Core Size with Independent Control of Functionality and Polyelectrolyte Response","volume":"37","author":"Larison","year":"2021","journal-title":"Langmuir"},{"key":"ref_87","doi-asserted-by":"crossref","first-page":"4583","DOI":"10.1016\/j.eurpolymj.2007.08.017","article-title":"Aggregation and Solubilization of Organic Solvents and Petrol\/Gasoline in Water Mediated by Block Copolymers","volume":"43","author":"Cerrada","year":"2007","journal-title":"Eur. Polym. J."},{"key":"ref_88","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1002\/pola.22360","article-title":"Synthesis of Poly(Di[Methylamine]Ethyl Methacrylate)-b-Poly(Cyclohexyl Methacrylate)-b-Poly(Di[Methylamine]Ethyl Methacrylate) Amphiphilic Triblock Copolymers by ATRP: Condensed-Phase and Solution Properties","volume":"46","author":"Haddleton","year":"2008","journal-title":"J. Polym. Sci. Part A Polym. Chem."},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"eadf3902","DOI":"10.1126\/sciadv.adf3902","article-title":"Hydration Layer Structure Modulates Superlubrication by Trivalent La3+ Electrolytes","volume":"9","author":"Han","year":"2023","journal-title":"Sci. Adv."},{"key":"ref_90","doi-asserted-by":"crossref","first-page":"1434","DOI":"10.1126\/science.aar5877","article-title":"Multivalent Counterions Diminish the Lubricity of Polyelectrolyte Brushes","volume":"360","author":"Yu","year":"2018","journal-title":"Science"},{"key":"ref_91","doi-asserted-by":"crossref","first-page":"20210029","DOI":"10.1002\/EXP.20210029","article-title":"Emerging Polymeric Electrospun Fibers: From Structural Diversity to Application in Flexible Bioelectronics and Tissue Engineering","volume":"2","author":"Wan","year":"2022","journal-title":"Exploration"},{"key":"ref_92","doi-asserted-by":"crossref","first-page":"20220167","DOI":"10.1002\/EXP.20220167","article-title":"Conducting Polymer Hydrogels Based on Supramolecular Strategies for Wearable Sensors","volume":"4","author":"Sun","year":"2024","journal-title":"Exploration"},{"key":"ref_93","doi-asserted-by":"crossref","first-page":"1137","DOI":"10.1007\/s40544-021-0586-1","article-title":"Unlocking the Secrets behind Liquid Superlubricity: A State-of-the-Art Review on Phenomena and Mechanisms","volume":"10","author":"Han","year":"2022","journal-title":"Friction"}],"container-title":["Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1944\/18\/8\/1759\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T17:12:59Z","timestamp":1760029979000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1944\/18\/8\/1759"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4,11]]},"references-count":93,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2025,4]]}},"alternative-id":["ma18081759"],"URL":"https:\/\/doi.org\/10.3390\/ma18081759","relation":{},"ISSN":["1996-1944"],"issn-type":[{"value":"1996-1944","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,4,11]]}}}