{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,3]],"date-time":"2026-11-03T06:58:47Z","timestamp":1793689127432,"version":"4.5.1"},"reference-count":74,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2025,8,13]],"date-time":"2025-08-13T00:00:00Z","timestamp":1755043200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"National Natural Science Foundation of China","award":["12175145"],"award-info":[{"award-number":["12175145"]}]},{"name":"National Natural Science Foundation of China","award":["24YF2729800"],"award-info":[{"award-number":["24YF2729800"]}]},{"DOI":"10.13039\/501100013105","name":"Shanghai Rising-Star Program","doi-asserted-by":"publisher","award":["12175145"],"award-info":[{"award-number":["12175145"]}],"id":[{"id":"10.13039\/501100013105","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013105","name":"Shanghai Rising-Star Program","doi-asserted-by":"publisher","award":["24YF2729800"],"award-info":[{"award-number":["24YF2729800"]}],"id":[{"id":"10.13039\/501100013105","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>A series of Ce-doped \u03b1-MnO2 catalysts (CeXMn1\u2212XO2, x = 0.04, 0.07, 0.10) were synthesized by a simple in situ hydrothermal method. It was confirmed by characterization methods such as XRD, Raman, N2 adsorption\u2013desorption and SEM confirmed that the introduction of Ce significantly regulated the microstructure of \u03b1-MnO2, specifically manifested as the reduction in grain size, the increase in defect sites, the increase in Mn-O bond length and altered morphological structure. H2-TPR, O2-TPD and XPS analyses further revealed the strong interaction between Mn and Ce, accompanied by significant electron transfer (Ce3+ + Mn4+ \u2192 Ce4+ + Mn3+), thereby promoting the formation of Mn3+ species. In the test of toluene catalytic oxidation performance, Ce0.07Mn0.93O2 exhibited the most excellent catalytic activity (T100 = 280 \u00b0C), while also having good thermal stability and water resistance. Furthermore, the degradation pathways of toluene were analyzed by TD-GC-MS technology: Toluene \u2192 Benzene \u2192 Benzaldehyde \u2192 Maleic anhydride \u2192 CO2 and H2O.<\/jats:p>","DOI":"10.3390\/ma18163809","type":"journal-article","created":{"date-parts":[[2025,8,13]],"date-time":"2025-08-13T15:53:27Z","timestamp":1755100407000},"page":"3809","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":41,"title":["Preparation of CeXMn1\u2212XO2 Catalysts with Strong Mn-Ce Synergistic Effect for Catalytic Oxidation of Toluene"],"prefix":"10.3390","volume":"18","author":[{"given":"Zhuoxuan","family":"Zhou","sequence":"first","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanxuan","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingkun","family":"Cao","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengqi","family":"He","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rong","family":"Qiao","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0115-2826","authenticated-orcid":false,"given":"Fukun","family":"Bi","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuxin","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Chemical Pharmaceutical, Taizhou Vocation & Technical College, Taizhou 318000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2217-6173","authenticated-orcid":false,"given":"Xiaodong","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China"},{"name":"Shanghai Non-Carbon Energy Conversion and Utilization Institute, Shanghai 200240, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2025,8,13]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"374","DOI":"10.1016\/j.jre.2022.03.007","article-title":"Highly efficient K-doped Mn\u2013Ce catalysts with strong K\u2013Mn\u2013Ce interaction for toluene oxidation","volume":"41","author":"Yang","year":"2023","journal-title":"J. Rare Earths"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"137938","DOI":"10.1016\/j.chemosphere.2023.137938","article-title":"Catalytic removal of toluene using MnO2-based catalysts: A review","volume":"318","author":"Gong","year":"2023","journal-title":"Chemosphere"},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Li, M., and Wang, R. (2024). Combined Catalytic Conversion of NOx and VOCs: Present Status and Prospects. Materials, 18.","DOI":"10.3390\/ma18010039"},{"key":"ref_4","first-page":"144","article-title":"Advances in photocatalytic removal of NOx and VOCs from flue gas","volume":"38","author":"Huang","year":"2024","journal-title":"Energy Environ. Prot."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"64","DOI":"10.20517\/cs.2024.211","article-title":"Single-atom catalysts in the photothermal catalysis: Fundamentals, mechanisms, and applications in VOCs oxidation","volume":"5","author":"Feng","year":"2025","journal-title":"Chem. Synth."},{"key":"ref_6","first-page":"57","article-title":"Synergistic removal of NO and chlorinated organics on CeO2-based catalysts","volume":"2","author":"Li","year":"2023","journal-title":"Environ. Funct. Mater."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"15526","DOI":"10.1021\/acs.est.5c05940","article-title":"Unveiling the Influence Mechanism of Impurity Gases on Cl-Containing Byproducts Formation during VOC Catalytic Oxidation","volume":"59","author":"Bi","year":"2025","journal-title":"Environ. Sci. Technol."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"129402","DOI":"10.1016\/j.fuel.2023.129402","article-title":"Clarify the effect of different metals doping on \u03b1-MnO2 for toluene adsorption and deep oxidation","volume":"355","author":"Jiang","year":"2024","journal-title":"Fuel"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"101715","DOI":"10.1016\/j.apr.2023.101715","article-title":"An efficient Mn1-yCeyOx composite oxide mesoporous catalysts for catalytic combustion of aromatic hydrocarbon","volume":"14","author":"Guo","year":"2023","journal-title":"Atmos. Pollut. Res."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"1025","DOI":"10.1016\/j.apsusc.2017.10.116","article-title":"Low-temperature abatement of toluene over Mn-Ce oxides catalysts synthesized by a modified hydrothermal approach","volume":"433","author":"Du","year":"2018","journal-title":"Appl. Surf. Sci."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"1014","DOI":"10.1016\/j.jre.2022.05.001","article-title":"Hydrogen production from ammonia decomposition over Ni\/CeO2 catalyst: Effect of CeO2 morphology","volume":"41","author":"Chen","year":"2023","journal-title":"J. Rare Earths"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1184","DOI":"10.1021\/jacsau.4c00998","article-title":"Highly Selective CO(2) Conversion to CH(4) by a N-Doped HTiNbO(5)\/NH(2)-UiO-66 Photocatalyst without a Sacrificial Electron Donor","volume":"5","author":"Huang","year":"2025","journal-title":"JACS Au"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"130804","DOI":"10.1016\/j.seppur.2024.130804","article-title":"Strategic defect engineering in TiO2 catalysts through electron beam irradiation: Unraveling enhanced photocatalytic pathways for multicomponent VOCs degradation","volume":"359","author":"Huang","year":"2025","journal-title":"Sep. Purif. Technol."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"50","DOI":"10.20517\/cs.2024.118","article-title":"Insight on reaction pathways of photocatalytic methane conversion","volume":"5","author":"Xiong","year":"2025","journal-title":"Chem. Synth."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"11341","DOI":"10.1021\/acs.est.5c00953","article-title":"Boosting the Photothermal Oxidation of Multicomponent VOCs in Humid Conditions: Synergistic Mechanism of Mn and K in Different Oxygen Activation Pathways","volume":"59","author":"Yang","year":"2025","journal-title":"Environ. Sci. Technol."},{"key":"ref_16","doi-asserted-by":"crossref","unstructured":"Bi, F., Zhang, Y., Zhou, Z., Guo, L., Zhu, Z., Liu, B., and Zhang, X. (2025). Electron Beam Irradiation-Induced Defects Enhance Pt-TiO2 Photothermal Catalytic Degradation in PAEs: A Performance and Mechanism Study. Molecules, 30.","DOI":"10.3390\/molecules30030697"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"523","DOI":"10.1016\/j.jre.2022.04.004","article-title":"Low-temperature catalytic combustion of trichloroethylene over MnO -CeO2 mixed oxide catalysts","volume":"41","author":"Shen","year":"2023","journal-title":"J. Rare Earths"},{"key":"ref_18","doi-asserted-by":"crossref","unstructured":"Sidaraite, R., Baltakys, K., Jaskunas, A., Naslenas, N., Slavinskas, D., Slavinskas, E., and Dambrauskas, T. (2024). Kinetic Study and Catalytic Activity of Cr(3+) Catalyst Supported on Calcium Silicate Hydrates for VOC Oxidation. Materials, 17.","DOI":"10.3390\/ma17143489"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"126636","DOI":"10.1016\/j.seppur.2024.126636","article-title":"Review of irradiation treatments on MOFs and COFs: Synthesis, modification, and application","volume":"339","author":"Ma","year":"2024","journal-title":"Sep. Purif. Technol."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"123473","DOI":"10.1016\/j.jhazmat.2020.123473","article-title":"Catalytic mechanism and pathways of 1,2-dichloropropane oxidation over LaMnO3 perovskite: An experimental and DFT study","volume":"402","author":"Zhang","year":"2021","journal-title":"J. Hazard. Mater."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"177","DOI":"10.1016\/j.cattod.2018.06.039","article-title":"Effect of CeO2 morphologies on toluene catalytic combustion","volume":"332","author":"Feng","year":"2019","journal-title":"Catal. Today"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"5349","DOI":"10.1021\/acs.est.9b01929","article-title":"Ru\/CeO2 Catalyst with Optimized CeO2 Support Morphology and Surface Facets for Propane Combustion","volume":"53","author":"Wang","year":"2019","journal-title":"Environ. Sci. Technol."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.apcatb.2013.08.015","article-title":"Low-temperature carbon monoxide and propane total oxidation by nanocrystalline cobalt oxides","volume":"147","author":"Salek","year":"2014","journal-title":"Appl. Catal. B Environ."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"133788","DOI":"10.1016\/j.cej.2021.133788","article-title":"Designed preparation of nano rod shaped CeO2-MnO catalysts with different Ce\/Mn ratios and its highly efficient catalytic performance for chlorobenzene complete oxidation: New insights into structure\u2013activity correlations","volume":"433","author":"Wan","year":"2022","journal-title":"Chem. Eng. J."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"1346","DOI":"10.1021\/acsestengg.3c00630","article-title":"New Insight into the Antagonism Mechanism between Binary VOCs during Their Degradation over Pd\/ZrO2 Catalysts","volume":"4","author":"Bi","year":"2024","journal-title":"ACS ES&T Eng."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"179","DOI":"10.1016\/j.fuproc.2014.10.008","article-title":"Catalytic destruction of chlorobenzene over mesoporous ACeOx (A=Co, Cu, Fe, Mn, or Zr) composites prepared by inorganic metal precursor spontaneous precipitation","volume":"130","author":"He","year":"2015","journal-title":"Fuel Process. Technol."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"144481","DOI":"10.1016\/j.apsusc.2019.144481","article-title":"MnO2 nanoparticles encapsuled in spheres of Ce-Mn solid solution: Efficient catalyst and good water tolerance for low-temperature toluene oxidation","volume":"504","author":"Luo","year":"2020","journal-title":"Appl. Surf. Sci."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"102292","DOI":"10.1016\/j.mtchem.2024.102292","article-title":"Nitrogen-induced TiO2 electric field polarization for efficient photodegradation of high-concentration ethyl acetate: Mechanisms and reaction pathways","volume":"41","author":"Huang","year":"2024","journal-title":"Mater. Today Chem."},{"key":"ref_29","doi-asserted-by":"crossref","unstructured":"Zhang, Y., Chen, J., Hu, H., Huang, J., Wei, J., Bi, F., and Zhang, X. (2025). Impact of residual ions on catalyst structure and catalytic performance: A review. Chin. Chem. Lett., 111549.","DOI":"10.1016\/j.cclet.2025.111549"},{"key":"ref_30","doi-asserted-by":"crossref","unstructured":"Liu, N., Tian, M., Zhang, Y., Yang, J., Wang, Z., Dai, W., Quan, G., Lei, J., Zhang, X., and Tang, L. (2025). Three-dimensional MIL-88A(Fe)-derived \u03b1-Fe2O3 and graphene composite for efficient photo-Fenton-like degradation of ciprofloxacin. Chin. Chem. Lett., 111063.","DOI":"10.1016\/j.cclet.2025.111063"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"131934","DOI":"10.1016\/j.seppur.2025.131934","article-title":"Degradation of volatile organic pollutants over manganese-based catalysts by defect engineering: A review","volume":"362","author":"Guo","year":"2025","journal-title":"Sep. Purif. Technol."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1016\/j.cattod.2019.05.062","article-title":"MnOx-CeO2 catalyst derived from metal-organic frameworks for toluene oxidation","volume":"355","author":"Sun","year":"2020","journal-title":"Catal. Today"},{"key":"ref_33","doi-asserted-by":"crossref","unstructured":"Figueredo, M.J.M., Cocuzza, C., Bensaid, S., Fino, D., Piumetti, M., and Russo, N. (2021). Catalytic Abatement of Volatile Organic Compounds and Soot over Manganese Oxide Catalysts. Materials, 14.","DOI":"10.3390\/ma14164534"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1016\/j.apsusc.2017.02.218","article-title":"Catalytic combustion of dimethyl ether over \u03b1-MnO2 nanostructures with different morphologies","volume":"409","author":"Cheng","year":"2017","journal-title":"Appl. Surf. Sci."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"4268","DOI":"10.1021\/acs.est.0c08179","article-title":"Recent Progress of Thermocatalytic and Photo\/Thermocatalytic Oxidation for VOCs Purification over Manganese-based Oxide Catalysts","volume":"55","author":"Wu","year":"2021","journal-title":"Environ. Sci. Technol."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"118150","DOI":"10.1016\/j.apcatb.2019.118150","article-title":"Comparative study of \u03b1-, \u03b2-, \u03b3- and \u03b4-MnO2 on toluene oxidation: Oxygen vacancies and reaction intermediates","volume":"260","author":"Yang","year":"2020","journal-title":"Appl. Catal. B Environ."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"132890","DOI":"10.1016\/j.chemosphere.2021.132890","article-title":"Insight into the effects of oxygen vacancy on the toluene oxidation over \u03b1-MnO2 catalyst","volume":"291","author":"Zeng","year":"2022","journal-title":"Chemosphere"},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"125020","DOI":"10.1016\/j.jhazmat.2020.125020","article-title":"Simple strategy for the construction of oxygen vacancies on \u03b1-MnO2 catalyst to improve toluene catalytic oxidation","volume":"409","author":"Chen","year":"2021","journal-title":"J. Hazard. Mater."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"119304","DOI":"10.1016\/j.apcatb.2020.119304","article-title":"Stabilizing platinum atoms on CeO2 oxygen vacancies by metal-support interaction induced interface distortion: Mechanism and application","volume":"278","author":"Jiang","year":"2020","journal-title":"Appl. Catal. B Environ."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"110172","DOI":"10.1016\/j.cclet.2024.110172","article-title":"Constructing frustrated Lewis pairs on porous Ce-based metal-organic frameworks with improved dicyclopentadiene hydrogenation activity","volume":"36","author":"Zhao","year":"2025","journal-title":"Chin. Chem. Lett."},{"key":"ref_41","first-page":"213","article-title":"Recent progress of modified CeO2-based materials for photocatalytic environmental remediation and antibacterial activity","volume":"2","author":"Miao","year":"2023","journal-title":"Environ. Funct. Mater."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"135603","DOI":"10.1016\/j.fuel.2025.135603","article-title":"Recent progress of cerium-based catalysts for the catalytic oxidation of volatile organic compounds: A review","volume":"399","author":"Zhou","year":"2025","journal-title":"Fuel"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"502","DOI":"10.1016\/j.apcatb.2019.01.005","article-title":"Synthesis of CeaMnOx hollow microsphere with hierarchical structure and its excellent catalytic performance for toluene combustion","volume":"245","author":"Zhao","year":"2019","journal-title":"Appl. Catal. B Environ."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"12684","DOI":"10.1021\/acs.est.0c03981","article-title":"Roles of Oxygen Vacancies in the Bulk and Surface of CeO2 for Toluene Catalytic Combustion","volume":"54","author":"Su","year":"2020","journal-title":"Environ. Sci. Technol."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"3435","DOI":"10.1021\/acscatal.8b00456","article-title":"Engineering Crystal Facet of \u03b1-MnO2 Nanowire for Highly Efficient Catalytic Oxidation of Carcinogenic Airborne Formaldehyde","volume":"8","author":"Rong","year":"2018","journal-title":"ACS Catal."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"25954","DOI":"10.1016\/j.ijhydene.2021.03.125","article-title":"Reactivity of Pt\/Ni supported on CeO2-nanorods on methanol steam reforming for H2 production: Steady state and DRIFTS studies","volume":"46","year":"2021","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"124864","DOI":"10.1016\/j.apcatb.2024.124864","article-title":"Promoted deep oxidation of m-xylene and inhibited the generation of carbon-deposited species by Ce modified Co3O4: The key role of modulating internal electron transport pathway","volume":"365","author":"Yan","year":"2025","journal-title":"Appl. Catal. B Environ."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"124745","DOI":"10.1016\/j.apcatb.2024.124745","article-title":"Tight coupling of oxygen vacancies and acidity on \u03b1-MnO2 through cerium doping engineering for efficient removal of multi-component VOCs","volume":"362","author":"Gao","year":"2025","journal-title":"Appl. Catal. B Environ."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"825","DOI":"10.1016\/j.apcatb.2017.11.036","article-title":"Homogeneous introduction of CeOy into MnOx-based catalyst for oxidation of aromatic VOCs","volume":"224","author":"Chen","year":"2018","journal-title":"Appl. Catal. B Environ."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1016\/j.aca.2009.06.059","article-title":"A comparison study on Raman scattering properties of alpha- and beta-MnO2","volume":"648","author":"Gao","year":"2009","journal-title":"Anal. Chim. Acta."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"396","DOI":"10.1016\/j.jcis.2021.01.096","article-title":"Efficient catalytic degradation of toluene at a readily prepared Mn-Cu catalyst: Catalytic performance and reaction pathway","volume":"591","author":"Li","year":"2021","journal-title":"J. Colloid Interface Sci."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"21694","DOI":"10.1021\/jacs.1c11058","article-title":"How Nature Circumvents the Woodward\u2013Hoffmann Rules and Promotes the Forbidden Conrotatory 4n + 2 Electron Electrocyclization of Prinzbach\u2019s Vinylogous Sesquifulvalene","volume":"143","author":"Kukier","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"133081","DOI":"10.1016\/j.chemosphere.2021.133081","article-title":"Reheat treatment under vacuum induces pre-calcined \u03b1-MnO2 with oxygen vacancy as efficient catalysts for toluene oxidation","volume":"289","author":"Fang","year":"2022","journal-title":"Chemosphere"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"596","DOI":"10.1021\/acs.iecr.9b05191","article-title":"HCHO Removal by MnO2(x)\u2013CeO2: Influence of the Synergistic Effect on the Catalytic Activity","volume":"59","author":"Guan","year":"2019","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"703","DOI":"10.1016\/j.cej.2018.12.109","article-title":"Co3O4@PC derived from ZIF-67 as an efficient catalyst for the selective catalytic reduction of NO with NH3 at low temperature","volume":"361","author":"Bai","year":"2019","journal-title":"Chem. Eng. J."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"2960","DOI":"10.1038\/s41467-022-30679-9","article-title":"Unraveling the structure and role of Mn and Ce for NOx reduction in application-relevant catalysts","volume":"13","author":"Gevers","year":"2022","journal-title":"Nat. Commun."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"210","DOI":"10.1016\/j.apcatb.2016.02.055","article-title":"Catalytic decomposition of gaseous ozone over manganese dioxides with different crystal structures","volume":"189","author":"Jia","year":"2016","journal-title":"Appl. Catal. B Environ."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"119512","DOI":"10.1016\/j.apcatb.2020.119512","article-title":"Efficient defect engineering in Co-Mn binary oxides for low-temperature propane oxidation","volume":"282","author":"Li","year":"2021","journal-title":"Appl. Catal. B Environ."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"6736","DOI":"10.1039\/c3ta11566f","article-title":"Effect of giant oxygen vacancy defects on the catalytic oxidation of OMS-2 nanorods","volume":"1","author":"Hou","year":"2013","journal-title":"J. Mater. Chem. A"},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"111009","DOI":"10.1016\/j.cclet.2025.111009","article-title":"Vanadium doping inhibit the Jahn\u2212Teller effect of Mn3+ for high-performance aqueous zinc ion battery","volume":"36","author":"Li","year":"2025","journal-title":"Chin. Chem. Lett."},{"key":"ref_61","first-page":"101361","article-title":"Interfacial structure engineering enhances photo-thermal CO2 hydrogenation over Ni-CeO2 nanocomposites","volume":"17","author":"Xiao","year":"2025","journal-title":"Chem Catal."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"750","DOI":"10.1038\/s41560-024-01541-7","article-title":"Ethylene production via photocatalytic dehydrogenation of ethane using LaMn1\u2212xCuxO3","volume":"9","author":"Song","year":"2024","journal-title":"Nat. Energy"},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"1925","DOI":"10.1016\/S1872-2067(17)62922-X","article-title":"Effects of surface physicochemical properties on NH3-SCR activity of MnO2 catalysts with different crystal structures","volume":"38","author":"Gong","year":"2017","journal-title":"Chin. J. Catal."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"1201","DOI":"10.1557\/s43579-024-00585-w","article-title":"Enhanced syngas (H2\/CO) production by Co\/CeO2 nanorods catalyst through dry reforming of methane","volume":"14","author":"Trimmer","year":"2024","journal-title":"MRS Commun."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"2462","DOI":"10.1021\/acscatal.5b02922","article-title":"Bridging the g-C3N4 Interlayers for Enhanced Photocatalysis","volume":"6","author":"Xiong","year":"2016","journal-title":"ACS Catal."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"123116","DOI":"10.1016\/j.apcatb.2023.123116","article-title":"Differences between atomically-dispersed and particulate Pt supported catalysts on synergistic photothermocatalytic oxidation of VOCs from cooking oil fumes","volume":"339","author":"Feng","year":"2023","journal-title":"Appl. Catal. B Environ."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"6698","DOI":"10.1021\/acscatal.9b01324","article-title":"Revealing the Highly Catalytic Performance of Spinel CoMn2O4 for Toluene Oxidation: Involvement and Replenishment of Oxygen Species Using In Situ Designed-TP Techniques","volume":"9","author":"Dong","year":"2019","journal-title":"ACS Catal."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"363","DOI":"10.1021\/jacsau.4c01146","article-title":"Insight into the Synergistic Effect of Binary Nonmetallic Codoped Co3O4 Catalysts for Efficient Ethyl Acetate Degradation under Humid Conditions","volume":"5","author":"Bi","year":"2025","journal-title":"JACS Au"},{"key":"ref_69","doi-asserted-by":"crossref","unstructured":"Li, L., Liu, Y., Liu, J., Zhou, B., Guo, M., and Liu, L. (2022). Catalytic Degradation of Toluene over MnO2\/LaMnO3: Effect of Phase Type of MnO2 on Activity. Catalysts, 12.","DOI":"10.3390\/catal12121666"},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"167","DOI":"10.1016\/j.cattod.2017.04.053","article-title":"Highly effective self-propagating synthesis of CeO2-doped MnO2 catalysts for toluene catalytic combustion","volume":"297","author":"Li","year":"2017","journal-title":"Catal. Today"},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"159650","DOI":"10.1016\/j.apsusc.2024.159650","article-title":"Constructing oxygen vacancies for \u03b4-MnO2 based monolithic catalyst by Cu intercalation to enhance toluene oxidation","volume":"655","author":"Li","year":"2024","journal-title":"Appl. Surf. Sci."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"6533","DOI":"10.1039\/C8RA10102G","article-title":"Integral structured Co\u2013Mn composite oxides grown on interconnected Ni foam for catalytic toluene oxidation","volume":"9","author":"Jiang","year":"2019","journal-title":"RSC Adv."},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"135521","DOI":"10.1016\/j.fuel.2025.135521","article-title":"Enhanced moisture tolerance and toluene oxidation activity of \u03b4-MnO2 catalysts by Sn doping: Phase transition and surface protection","volume":"398","author":"Li","year":"2025","journal-title":"Fuel"},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"1203","DOI":"10.1016\/j.apcatb.2021.120393","article-title":"The promoting effect of H2O on rod-like MnCeOx derived from MOFs for toluene oxidation: A combined experimental and theoretical investigation","volume":"297","author":"Zhang","year":"2021","journal-title":"Appl. Catal. B Environ."}],"container-title":["Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1944\/18\/16\/3809\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T18:26:55Z","timestamp":1760034415000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1944\/18\/16\/3809"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,8,13]]},"references-count":74,"journal-issue":{"issue":"16","published-online":{"date-parts":[[2025,8]]}},"alternative-id":["ma18163809"],"URL":"https:\/\/doi.org\/10.3390\/ma18163809","relation":{},"ISSN":["1996-1944"],"issn-type":[{"value":"1996-1944","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,8,13]]}}}