{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T22:54:05Z","timestamp":1785884045296,"version":"3.56.0"},"reference-count":198,"publisher":"MDPI AG","issue":"11","license":[{"start":{"date-parts":[[2026,5,22]],"date-time":"2026-05-22T00:00:00Z","timestamp":1779408000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100007751","name":"AGH University of Science and Technology, The Excellence Initiative\u2014Research University","doi-asserted-by":"publisher","award":["D4-16851"],"award-info":[{"award-number":["D4-16851"]}],"id":[{"id":"10.13039\/501100007751","id-type":"DOI","asserted-by":"publisher"}]},{"award":["D4-16851"],"award-info":[{"award-number":["D4-16851"]}],"id":[{"id":"https:\/\/ror.org\/00bas1c41","id-type":"ROR","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>The catalytic hydrogenation of carbon dioxide (CO2) to methane (CH4), commonly known as the Sabatier reaction, is a promising pathway for carbon capture and utilization (CCU). Nickel-based catalysts are cost-effective alternatives to noble metal systems, especially when supported on activated carbons derived from plant biomass. This review critically examines the basics of CO2 methanation, the role of catalyst composition and support materials, and the growing interest in biomass-derived activated carbons. Special emphasis is placed on synthesis routes, physicochemical properties, catalytic performance, and sustainability aspects. A comparative assessment of catalysts derived from different biomass sources is included, pointing out the most important factors influencing activity, durability, and economic feasibility.<\/jats:p>","DOI":"10.3390\/ma19112194","type":"journal-article","created":{"date-parts":[[2026,5,22]],"date-time":"2026-05-22T16:06:08Z","timestamp":1779465968000},"page":"2194","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Nickel-Based Catalysts for CO2 Methanation Supported on Plant Biomass-Based Activated Carbons\u2014A Comprehensive Review"],"prefix":"10.3390","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-4361-7571","authenticated-orcid":false,"given":"Kamil","family":"Dudek","sequence":"first","affiliation":[{"name":"Faculty of Non-Ferrous Metals, AGH University of Science and Technology, Mickiewicz Avenue 30, 30-059 Cracow, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5085-2645","authenticated-orcid":false,"given":"Piotr","family":"\u017babi\u0144ski","sequence":"additional","affiliation":[{"name":"Faculty of Non-Ferrous Metals, AGH University of Science and Technology, Mickiewicz Avenue 30, 30-059 Cracow, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2026,5,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1029\/2007GB003142","article-title":"Implications of \u201cPeak Oil\u201d for Atmospheric CO2 and Climate","volume":"22","author":"Kharecha","year":"2008","journal-title":"Glob. Biogeochem. Cycles"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1007\/s13280-009-0011-x","article-title":"Climate Change and Peak Oil: The Urgent Need for a Transition to a Non-Carbon-Emitting Society","volume":"39","author":"Carnicer","year":"2010","journal-title":"Ambio"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"797","DOI":"10.1016\/j.enpol.2012.10.046","article-title":"Depletion of Fossil Fuels and Anthropogenic Climate Change\u2014A Review","volume":"52","author":"Tang","year":"2013","journal-title":"Energy Policy"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"609","DOI":"10.1068\/b33063t","article-title":"Global Oil Production: Forecasts and Methodologies","volume":"35","author":"Bentley","year":"2008","journal-title":"Environ. Plan. B Plan. Des."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"36","DOI":"10.1016\/j.reseneeco.2015.01.002","article-title":"Modeling Peak Oil and the Geological Constraints on Oil Production","volume":"40","author":"Okullo","year":"2015","journal-title":"Resour. Energy Econ."},{"key":"ref_6","unstructured":"US Government Printing Office (1987). Multilateral Montreal Protocol on Substances That Deplete the Ozone Layer (with Annex); Concluded at Montreal on 16 September, US Government Printing Office."},{"key":"ref_7","unstructured":"United Nations (1998). Kyoto Protocol of the United Nations Framework Convention on Climate Change, United Nations."},{"key":"ref_8","unstructured":"United Nations (2015). Unfccc Adoption of the Paris Agreement\u2014Paris Agreement Text English, United Nations."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"1335","DOI":"10.1007\/s11090-023-10417-9","article-title":"Recent Trends in Plasma-Assisted CO2 Methanation: A Critical Review of Recent Studies","volume":"43","author":"Ullah","year":"2023","journal-title":"Plasma Chem. Plasma Process."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"2022","DOI":"10.1016\/j.egypro.2017.03.577","article-title":"CO2 Methanation: The Effect of Catalysts and Reaction Conditions","volume":"105","author":"Stangeland","year":"2017","journal-title":"Energy Procedia"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"867","DOI":"10.1007\/s11144-026-03040-0","article-title":"CO2 Methanation: A Review on Optimizing Catalysts and Conditions","volume":"139","author":"Kempi","year":"2026","journal-title":"React. Kinet. Mech. Catal."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"457","DOI":"10.1016\/j.cherd.2023.11.060","article-title":"Advancements in CO2 Methanation: A Comprehensive Review of Catalysis, Reactor Design and Process Optimization","volume":"201","author":"Tommasi","year":"2024","journal-title":"Chem. Eng. Res. Des."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"4","DOI":"10.1007\/s40243-020-0164-x","article-title":"A DFT Investigation of the Mechanisms of CO2 and CO Methanation on Fe (111)","volume":"9","author":"Kwawu","year":"2020","journal-title":"Mater. Renew. Sustain. Energy"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"439","DOI":"10.1007\/s40565-017-0285-0","article-title":"Power-to-Gas Technology in Energy Systems: Current Status and Prospects of Potential Operation Strategies","volume":"5","author":"Liu","year":"2017","journal-title":"J. Mod. Power Syst. Clean. Energy"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"118743","DOI":"10.1016\/j.apenergy.2022.118743","article-title":"Techno-Economic Analysis of Power-to-Gas Plants in a Gas and Electricity Distribution Network System with High Renewable Energy Penetration","volume":"312","author":"Fambri","year":"2022","journal-title":"Appl. Energy"},{"key":"ref_16","doi-asserted-by":"crossref","unstructured":"Maroufmashat, A., and Fowler, M. (2017). Transition of Future Energy System Infrastructure; through Power-to-Gas Pathways. Energies, 10.","DOI":"10.3390\/en10081089"},{"key":"ref_17","doi-asserted-by":"crossref","unstructured":"Zhu, J., Zhang, H., Li, T., Deng, T., Zou, H., Li, Y., and Yang, D. (2024). Liquid CO2-Capture Technologies: A Review. Nanomaterials, 14.","DOI":"10.3390\/nano14231910"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"100118","DOI":"10.1016\/j.nxsust.2025.100118","article-title":"Path of Carbon Dioxide Capture Technologies: An Overview","volume":"6","author":"Shyam","year":"2025","journal-title":"Next Sustain."},{"key":"ref_19","first-page":"100178","article-title":"A Comprehensive Review of Carbon Capture Science and Technologies","volume":"11","author":"Wu","year":"2024","journal-title":"Carbon Capture Sci. Technol."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"100456","DOI":"10.1016\/j.clet.2022.100456","article-title":"Technologies for Carbon Dioxide Capture: A Review Applied to Energy Sectors","volume":"8","author":"Vaz","year":"2022","journal-title":"Clean. Eng. Technol."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"234856","DOI":"10.1016\/j.jpowsour.2024.234856","article-title":"A Review on Fundamentals for Designing Hydrogen Evolution Electrocatalyst","volume":"613","author":"Qadeer","year":"2024","journal-title":"J. Power Sources"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"100613","DOI":"10.1016\/j.rechem.2022.100613","article-title":"Recent Reports on Hydrogen Evolution Reactions and Catalysis","volume":"4","author":"Kumar","year":"2022","journal-title":"Results Chem."},{"key":"ref_23","first-page":"21","article-title":"Single-Atom Catalysts for Electrochemical Hydrogen Evolution Reaction: Recent Advances and Future Perspectives","volume":"12","author":"Pu","year":"2020","journal-title":"Nanomicro Lett."},{"key":"ref_24","first-page":"100892","article-title":"Carbon-Based Electrocatalysts for Hydrogen Evolution Reaction","volume":"26","author":"Ahmed","year":"2025","journal-title":"Energy Convers. Manag. X"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"5363","DOI":"10.1038\/s41467-023-41097-w","article-title":"Metallic W\/WO2 Solid-Acid Catalyst Boosts Hydrogen Evolution Reaction in Alkaline Electrolyte","volume":"14","author":"Chen","year":"2023","journal-title":"Nat. Commun."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1161","DOI":"10.1016\/j.ces.2006.11.020","article-title":"Methanation of Carbon Dioxide by Hydrogen Reduction Using the Sabatier Process in Microchannel Reactors","volume":"62","author":"Brooks","year":"2007","journal-title":"Chem. Eng. Sci."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"2358","DOI":"10.1039\/c2ra00632d","article-title":"A Thermodynamic Analysis of Methanation Reactions of Carbon Oxides for the Production of Synthetic Natural Gas","volume":"2","author":"Gao","year":"2012","journal-title":"RSC Adv."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"323","DOI":"10.1016\/j.biortech.2014.10.069","article-title":"Dynamic Biogas Upgrading Based on the Sabatier Process: Thermodynamic and Dynamic Process Simulation","volume":"178","author":"Ehimen","year":"2015","journal-title":"Bioresour. Technol."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"4451","DOI":"10.1021\/acs.iecr.6b00134","article-title":"Catalytic Performance of \u03b3-Al2O3\u2013ZrO2\u2013TiO2\u2013CeO2 Composite Oxide Supported Ni-Based Catalysts for CO2 Methanation","volume":"55","author":"Abate","year":"2016","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"140","DOI":"10.1007\/s10563-015-9191-5","article-title":"Recent Advances in Catalysts for Methane Combustion","volume":"19","author":"Chen","year":"2015","journal-title":"Catal. Surv. Asia"},{"key":"ref_31","doi-asserted-by":"crossref","unstructured":"Gaikwad, R., Villadsen, S.N.B., Rasmussen, J.P., Grumsen, F.B., Nielsen, L.P., Gildert, G., M\u00f8ller, P., and Fosb\u00f8l, P.L. (2020). Container-Sized CO2 to Methane: Design, Construction and Catalytic Tests Using Raw Biogas to Biomethane. Catalysts, 10.","DOI":"10.3390\/catal10121428"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"206","DOI":"10.1016\/j.apenergy.2017.08.080","article-title":"Active and Stable Ni Based Catalysts and Processes for Biogas Upgrading: The Effect of Temperature and Initial Methane Concentration on CO2 Methanation","volume":"227","author":"Stangeland","year":"2018","journal-title":"Appl. Energy"},{"key":"ref_33","unstructured":"Macrotrends (2026, May 15). Global Nickel Prices (1990\u20132026). Available online: https:\/\/www.macrotrends.net\/3299\/global-nickel-prices."},{"key":"ref_34","unstructured":"(2026, May 15). Statista Average Nickel Prices from 1980 to 2024 with Forecasts to 2027. Available online: https:\/\/www.statista.com\/statistics\/236578\/average-nickel-prices\/."},{"key":"ref_35","unstructured":"(2026, May 15). Daily Metal Prices. Metal Price Charts. Ruthenium Price (USD\/Metric Ton) for the Last 10 Years. Available online: https:\/\/www.dailymetalprice.com\/metalpricecharts.php?c=ru&u=t&d=2400&x=USD."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"5071","DOI":"10.1039\/a904923a","article-title":"CO2 Hydrogenation over Metal\/Zirconia Catalysts","volume":"1","author":"Wambach","year":"1999","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"105460","DOI":"10.1016\/j.jece.2021.105460","article-title":"Recent Trends in Developments of Active Metals and Heterogenous Materials for Catalytic CO2 Hydrogenation to Renewable Methane: A Review","volume":"9","author":"Fan","year":"2021","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"456","DOI":"10.1016\/j.apcatb.2011.10.034","article-title":"High Efficiency Production of Substitute Natural Gas from Biomass","volume":"111\u2013112","author":"Rabou","year":"2012","journal-title":"Appl. Catal. B"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"435","DOI":"10.1016\/S1003-9953(10)60192-2","article-title":"Methanation of Syngas over Coral Reef-like Ni\/Al2O3 Catalysts","volume":"20","author":"Tan","year":"2011","journal-title":"J. Nat. Gas. Chem."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"318","DOI":"10.1016\/S1003-9953(10)60187-9","article-title":"Methanation of Carbon Dioxide on Ni\/ZrO2-Al2O3 Catalysts: Effects of ZrO2 Promoter and Preparation Method of Novel ZrO2-Al2O3 Carrier","volume":"20","author":"Cai","year":"2011","journal-title":"J. Nat. Gas. Chem."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"114215","DOI":"10.1016\/j.cattod.2023.114215","article-title":"CO2 Methanation over Ni Supported on Carbon\u2013ZrO2: An Optimization of the Composite Composition","volume":"422","author":"Quatorze","year":"2023","journal-title":"Catal. Today"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"1933","DOI":"10.1039\/D4RE00084F","article-title":"Optimizing CO2 Methanation: Effect of Surface Basicity and Active Phase Reducibility on Ni-Based Catalysts","volume":"9","author":"Kaydouh","year":"2024","journal-title":"React. Chem. Eng."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"17648","DOI":"10.1039\/D1RA02327F","article-title":"Role of Oxide Support in Ni Based Catalysts for CO2 Methanation","volume":"11","author":"Lee","year":"2021","journal-title":"RSC Adv."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"570","DOI":"10.1016\/j.cattod.2020.01.029","article-title":"Electronic Structure Modulating for Supported Rh Catalysts toward CO2 Methanation","volume":"356","author":"Jiang","year":"2020","journal-title":"Catal. Today"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"5114","DOI":"10.1021\/acs.iecr.1c00028","article-title":"Methanation of CO2 and CO by (Ni,Mg,Al)-Hydrotalcite-Derived and Related Catalysts with Varied Magnesium and Aluminum Oxide Contents","volume":"60","author":"Hilbert","year":"2021","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_46","doi-asserted-by":"crossref","unstructured":"And\u00e9rez-Fern\u00e1ndez, M., Urue\u00f1a-Leal, A., D\u00edez-Rodr\u00edguez, D., and Casares, J.\u00c1. (2025). Catalysis for Methane Synthesis. Hydrogen Production, Storage and Utilization Technologies, De Gruyter.","DOI":"10.1515\/9783111635064-004"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"217","DOI":"10.1007\/s13203-016-0154-1","article-title":"Application of Ni\u2013Al-Hydrotalcite-Derived Catalyst Modified with Fe or Mg in CO2 Methanation","volume":"6","author":"Wang","year":"2016","journal-title":"Appl. Petrochem. Res."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"3902","DOI":"10.1021\/la00022a082","article-title":"Synthesis and Surface Acid\/Base Properties of Magnesium-Aluminum Mixed Oxides Obtained from Hydrotalcites","volume":"10","author":"Shen","year":"1994","journal-title":"Langmuir"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"5","DOI":"10.1016\/j.catcom.2016.04.021","article-title":"Novel Ni-La-Hydrotalcite Derived Catalysts for CO2 Methanation","volume":"83","author":"Wierzbicki","year":"2016","journal-title":"Catal. Commun."},{"key":"ref_50","doi-asserted-by":"crossref","unstructured":"Mohd Ridzuan, N.D., Shaharun, M.S., Anawar, M.A., and Ud-Din, I. (2022). Ni-Based Catalyst for Carbon Dioxide Methanation: A Review on Performance and Progress. Catalysts, 12.","DOI":"10.3390\/catal12050469"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"587","DOI":"10.1016\/S2095-4956(14)60144-3","article-title":"Unique Catalysis of Ni-Al Hydrotalcite Derived Catalyst in CO2 Methanation: Cooperative Effect between Ni Nanoparticles and a Basic Support","volume":"23","author":"He","year":"2014","journal-title":"J. Energy Chem."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"166","DOI":"10.1016\/j.fuproc.2014.01.004","article-title":"CO2 Methanation on Ni\/Ce0.5Zr0.5O2 Catalysts for the Production of Synthetic Natural Gas","volume":"123","author":"Pan","year":"2014","journal-title":"Fuel Process. Technol."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S0926-860X(02)00659-2","article-title":"Reduction Property and Catalytic Activity of Ce1\u2212XNiXO2 Mixed Oxide Catalysts for CH4 Oxidation","volume":"246","author":"Shan","year":"2003","journal-title":"Appl. Catal. A Gen."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"120529","DOI":"10.1016\/j.apcata.2025.120529","article-title":"Enhanced Low-Temperature Activity of CO2 Methanation: Effect of Metal Oxide Support on the Performance of Ni-Based Catalysts","volume":"707","author":"Italiano","year":"2025","journal-title":"Appl. Catal. A Gen."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"103101","DOI":"10.1016\/j.apmt.2026.103101","article-title":"Ni- and MgO-Based Catalysts Derived from Mixed Carbonates of Magnesium and Nickel for CO2 Methanation","volume":"48","author":"Sun","year":"2026","journal-title":"Appl. Mater. Today"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"115572","DOI":"10.1016\/j.cattod.2025.115572","article-title":"CO2 Methanation over BEA Zeolite Catalysts: Effect of MgO and in-Situ Ni Incorporation","volume":"462","author":"Nasser","year":"2026","journal-title":"Catal. Today"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"115233","DOI":"10.1016\/j.jece.2024.115233","article-title":"Understanding the Role of Mn in Ni-Mn\/Al2O3 and Ni3Fe-Mn\/Al2O3 Catalysts for Enhanced CO2 Methanation Activity","volume":"13","author":"Prabhakar","year":"2025","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"160839","DOI":"10.1016\/j.cej.2025.160839","article-title":"Enhanced Low-Temperature Activity for CO2 Methanation over N-Doped NiMn-LDO","volume":"507","author":"Qiang","year":"2025","journal-title":"Chem. Eng. J."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"48","DOI":"10.1016\/j.joei.2021.08.008","article-title":"Preparation of the Mn-Promoted NiO\u2013Al2O3 Nanocatalysts for Low Temperature CO2 Methanation","volume":"99","author":"Tamimi","year":"2021","journal-title":"J. Energy Inst."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"13701","DOI":"10.1002\/anie.201506062","article-title":"Nitrogen-Doped Carbon Nanotube Arrays for High-Efficiency Electrochemical Reduction of CO2: On the Understanding of Defects, Defect Density, and Selectivity","volume":"54","author":"Sharma","year":"2015","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"1085","DOI":"10.1002\/cssc.201600202","article-title":"Revealing the Origin of Activity in Nitrogen-Doped Nanocarbons towards Electrocatalytic Reduction of Carbon Dioxide","volume":"9","author":"Xu","year":"2016","journal-title":"ChemSusChem"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"1966","DOI":"10.1016\/j.rser.2006.03.013","article-title":"Agricultural Residues as Precursors for Activated Carbon Production\u2014A Review","volume":"11","author":"Ioannidou","year":"2007","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_63","doi-asserted-by":"crossref","unstructured":"Asare, K., Mali, A., Hasan, M.F., Agbo, P., Shahbazi, A., and Zhang, L. (2024). Algae Derived Carbon from Hydrothermal Liquefaction as Sustainable Carbon Electrode Material for Supercapacitor. C-J. Carbon Res., 10.","DOI":"10.3390\/c10020051"},{"key":"ref_64","doi-asserted-by":"crossref","unstructured":"Pan, H., Zheng, K., Chen, Z., Wang, Y., Tan, Y., Wang, J., Yao, L., Wang, L., Sun, C., and Yang, J. (2024). Tuning the Electronic Structures of Mo-Based Sulfides\/Selenides with Biomass-Derived Carbon for Hydrogen Evolution Reaction and Sodium-Ion Batteries. Catalysts, 14.","DOI":"10.3390\/catal14090627"},{"key":"ref_65","doi-asserted-by":"crossref","unstructured":"Buaki-Sog\u00f3, M., Zubizarreta, L., Garc\u00eda-Pellicer, M., and Quijano-L\u00f3pez, A. (2020). Sustainable Carbon as Efficient Support for Metal-Based Nanocatalyst: Applications in Energy Harvesting and Storage. Molecules, 25.","DOI":"10.3390\/molecules25143123"},{"key":"ref_66","doi-asserted-by":"crossref","unstructured":"Wang, Z., Liu, L., and Cao, H. (2024). Multistage Porous Carbon Derived from Enzyme-Treated Waste Walnut Green Husk and Polyethylene Glycol for Phase Change Energy Storage. Materials, 17.","DOI":"10.3390\/ma17061379"},{"key":"ref_67","doi-asserted-by":"crossref","unstructured":"Soursos, N., Kottis, T., Premeti, V., Zafeiropoulos, J., Govatsi, K., Sygellou, L., Vakros, J., Manariotis, I.D., Mantzavinos, D., and Lianos, P. (2024). Study of the Suitability of Corncob Biochar as Electrocatalyst for Zn\u2013Air Batteries. Batteries, 10.","DOI":"10.3390\/batteries10060209"},{"key":"ref_68","doi-asserted-by":"crossref","unstructured":"Somyanonthanakun, W., Greszta, A., Roberts, A.J., and Thongmee, S. (2023). Sugarcane Bagasse-Derived Activated Carbon as a Potential Material for Lead Ions Removal from Aqueous Solution and Supercapacitor Energy Storage Application. Sustainability, 15.","DOI":"10.3390\/su15065566"},{"key":"ref_69","doi-asserted-by":"crossref","unstructured":"Subramaniam, M.N., Zheng, J., Wu, Z., Goh, P.S., and Zhang, G. (2024). Visible Light-Driven Organic Pollutant Removal Using Fe-Based Photocatalysts Supported by Wheat Straw Biochar. Catalysts, 14.","DOI":"10.3390\/catal14010043"},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"103622","DOI":"10.1016\/j.surfin.2023.103622","article-title":"Preparation of Activated Carbon-Metal Nanoparticle Composite Materials for the Catalytic Reduction of Organic Pollutants","volume":"44","author":"Boukoussa","year":"2024","journal-title":"Surf. Interfaces"},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"116232","DOI":"10.1016\/j.envres.2023.116232","article-title":"Unusual, Hierarchically Structured Composite of Sugarcane Pulp Bagasse Biochar Loaded with Cu\/Ni Bimetallic Nanoparticles for Dye Removal","volume":"232","author":"Tang","year":"2023","journal-title":"Environ. Res."},{"key":"ref_72","doi-asserted-by":"crossref","unstructured":"Sre\u0144scek-Nazzal, J., Kami\u0144ska, A., Serafin, J., and Michalkiewicz, B. (2024). Chemical Activation of Banana Peel Waste-Derived Biochar Using KOH and Urea for CO2 Capture. Materials, 17.","DOI":"10.3390\/ma17040872"},{"key":"ref_73","doi-asserted-by":"crossref","unstructured":"Plavniece, A., Kaare, K., Simkunait\u0117, D., Balciunaite, A., Jasulaitiene, V., Niaura, G., Volperts, A., Dobele, G., Colmenares-Rausseo, L.C., and Kruusenberg, I. (2024). Manganese- and Nitrogen-Doped Biomass-Based Carbons as Catalysts for the Oxygen Reduction Reaction. Catalysts, 14.","DOI":"10.3390\/catal14020092"},{"key":"ref_74","doi-asserted-by":"crossref","unstructured":"Chen, X., Ma, J., Sun, X., Zhao, C., Li, J., and Li, H. (2023). Pyrolysis Enzymolysis-Treated Pomelo Peel: Porous Carbon Materials with Fe\u2212Nx Sites for High-Performance Supercapacitor and Efficient Oxygen Reduction Applications. Polymers, 15.","DOI":"10.3390\/polym15193879"},{"key":"ref_75","doi-asserted-by":"crossref","unstructured":"Dobele, G., Volperts, A., Plavniece, A., Zhurinsh, A., Upskuviene, D., Balciunaite, A., Niaura, G., Colmenares-Rausseo, L.C., Tamasauskaite-Tamasiunaite, L., and Norkus, E. (2024). Thermochemical Activation of Wood with NaOH, KOH and H3PO4 for the Synthesis of Nitrogen-Doped Nanoporous Carbon for Oxygen Reduction Reaction. Molecules, 29.","DOI":"10.3390\/molecules29102238"},{"key":"ref_76","doi-asserted-by":"crossref","unstructured":"Wu, Y., Hou, Q., Li, F., Sang, Y., Hao, M., Tang, X., Qiu, F., and Zhang, H. (2023). Mitigating Co Metal Particle Agglomeration and Enhancing ORR Catalytic Activity through Nitrogen-Enriched Porous Carbon Derived from Biomass. Catalysts, 13.","DOI":"10.3390\/catal13071118"},{"key":"ref_77","doi-asserted-by":"crossref","unstructured":"Schmies, H., Bengen, N., M\u00fcller-H\u00fclstede, J., Ibitowa, O.A., Wagner, P., and Wark, M. (2023). How Effective Is Graphitization of Biomasses for the Carbon Stability of Pt\/C ORR Catalysts?. Catalysts, 13.","DOI":"10.3390\/catal13020343"},{"key":"ref_78","doi-asserted-by":"crossref","unstructured":"Atchudan, R., Perumal, S., Jebakumar Immanuel Edison, T.N., Sundramoorthy, A.K., Karthik, N., Sangaraju, S., Choi, S.T., and Lee, Y.R. (2023). Biowaste-Derived Heteroatom-Doped Porous Carbon as a Sustainable Electrocatalyst for Hydrogen Evolution Reaction. Catalysts, 13.","DOI":"10.3390\/catal13030542"},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"2298","DOI":"10.1039\/D3CE00117B","article-title":"Ni Nanoparticles Assembled on the Surface of Biomass-Derived Porous Carbon as Competitive Candidates for the Hydrogen Evolution Reaction","volume":"25","author":"Chai","year":"2023","journal-title":"CrystEngComm"},{"key":"ref_80","doi-asserted-by":"crossref","unstructured":"Ibrahim, A., Elsayed, I., and Hassan, E.B. (2024). Upgrading of Rice Straw Bio-Oil Using 1-Butanol over ZrO2-Fe3O4 Bimetallic Nanocatalyst Supported on Activated Rice Straw Biochar to Butyl Esters. Catalysts, 14.","DOI":"10.3390\/catal14100666"},{"key":"ref_81","doi-asserted-by":"crossref","unstructured":"Murillo, H.A., Jui\u00f1a, E., Vizuete, K., Debut, A., Echeverr\u00eda, D., Taco-Vasquez, S., and Ponce, S. (2024). Rapid Waste Motor Oil Conversion into Diesel-Range Hydrocarbons Using Hydrochar as Catalyst: Kinetic Study and Product Characterization. Recycling, 9.","DOI":"10.3390\/recycling9030039"},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"108209","DOI":"10.1016\/j.jece.2022.108209","article-title":"Characteristics of Coconut Shell-Based Activated Carbon as Ni and Pt Catalyst Supports for Hydrotreating Calophyllum Inophyllum Oil into Hydrocarbon-Based Biofuel","volume":"10","author":"Trisunaryanti","year":"2022","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"403","DOI":"10.1016\/j.fuel.2018.03.179","article-title":"Nanostructured Molybdenum Carbide on Biochar for CO2 Reforming of CH4","volume":"225","author":"Li","year":"2018","journal-title":"Fuel"},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"126676","DOI":"10.1016\/j.jenvman.2025.126676","article-title":"Synergistically Engineered Magnetic Biochar-Supported (BiO)2CO3\/Co2P-BN Ternary Photocatalyst for Solar-Assisted Degradation of Tetracycline and Real Effluent Treatment","volume":"392","author":"Dhiman","year":"2025","journal-title":"J. Environ. Manag."},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"11212","DOI":"10.1021\/acssuschemeng.1c03497","article-title":"Direct Conversion of Syngas Produced from Steam Reforming of Toluene into Methane over a Ni\/Biochar Catalyst","volume":"9","author":"Ren","year":"2021","journal-title":"ACS Sustain. Chem. Eng."},{"key":"ref_86","doi-asserted-by":"crossref","unstructured":"Ding, Z., Gao, Y., Hu, L., and Yang, X. (2024). Highly Efficient and Selective Hydrogenation of Biomass-Derived Furfural Using Interface-Active Rice Husk-Based Porous Carbon-Supported NiCu Alloy Catalysts. Molecules, 29.","DOI":"10.3390\/molecules29112638"},{"key":"ref_87","doi-asserted-by":"crossref","unstructured":"Brand\u00e3o, R.D., de Freitas J\u00fanior, A.M., Linares, J.J., Suarez, P.A.Z., Dutra, R.C., Garnier, J., Tonh\u00e1, M.S., Ballesteros-Plata, D., Rodr\u00edguez-Castell\u00f3n, E., and Prauchner, M.J. (2025). Activated Carbon-Supported Pt Catalysts Intended for the Hydroprocessing of Lipid Feedstocks: Effects of Support Surface Composition and Impregnation Protocol. Molecules, 30.","DOI":"10.3390\/molecules30132862"},{"key":"ref_88","doi-asserted-by":"crossref","unstructured":"Pham, X.T., Tran, V.A., Tran, L.T.T., Nguyen, T.N.P., Le, T.H., Hoang, H., Nguyen, T.H., Vu, K.B., and Phung, T.K. (2022). Hierarchical Porous Activated Carbon-Supported Ruthenium Catalysts for Catalytic Cleavage of Lignin Model Compounds. Energies, 15.","DOI":"10.3390\/en15228611"},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"133835","DOI":"10.1016\/j.fuel.2024.133835","article-title":"Biomass Waste-Derived Biochar Catalysts with Ru Loading for Selective and Efficient Transformation of Lignin and Its Model Compound","volume":"383","author":"Qiu","year":"2025","journal-title":"Fuel"},{"key":"ref_90","doi-asserted-by":"crossref","first-page":"118011","DOI":"10.1016\/j.apcata.2021.118011","article-title":"Lignin-Based Activated Carbon-Supported Metal Oxide Catalysts in Lactic Acid Production from Glucose","volume":"612","author":"Kupila","year":"2021","journal-title":"Appl. Catal. A Gen."},{"key":"ref_91","doi-asserted-by":"crossref","unstructured":"Wang, M., Cai, J., Jiao, L., and Bu, Q. (2024). Biomass-Derived Co\/MPC Nanocomposites for Effective Sensing of Hydrogen Peroxide via Electrocatalysis Reduction. Catalysts, 14.","DOI":"10.3390\/catal14090624"},{"key":"ref_92","doi-asserted-by":"crossref","first-page":"26915","DOI":"10.1016\/j.ijhydene.2021.05.193","article-title":"Optimization of the Operating Conditions for Steam Reforming of Slow Pyrolysis Oil over an Activated Biochar-Supported Ni\u2013Co Catalyst","volume":"46","author":"Cortese","year":"2021","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_93","doi-asserted-by":"crossref","first-page":"5445","DOI":"10.1021\/acssuschemeng.1c00837","article-title":"Biochar\/Zinc Oxide Composites as Effective Catalysts for Electrochemical CO2Reduction","volume":"9","author":"Lourenco","year":"2021","journal-title":"ACS Sustain. Chem. Eng."},{"key":"ref_94","doi-asserted-by":"crossref","first-page":"1055","DOI":"10.1016\/j.rser.2014.10.074","article-title":"Recent Advances in Utilization of Biochar","volume":"42","author":"Qian","year":"2015","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_95","doi-asserted-by":"crossref","first-page":"1500867","DOI":"10.1002\/aenm.201500867","article-title":"Generalized Mechanochemical Synthesis of Biomass-Derived Sustainable Carbons for High Performance CO2 Storage","volume":"5","author":"Balahmar","year":"2015","journal-title":"Adv. Energy Mater."},{"key":"ref_96","doi-asserted-by":"crossref","first-page":"70","DOI":"10.1016\/j.chemosphere.2014.12.058","article-title":"Application of Biochar for the Removal of Pollutants from Aqueous Solutions","volume":"125","author":"Tan","year":"2015","journal-title":"Chemosphere"},{"key":"ref_97","doi-asserted-by":"crossref","first-page":"693","DOI":"10.1016\/j.biombioe.2012.06.026","article-title":"Effect of Formation Conditions on Biochars: Compositional and Structural Properties of Cellulose, Lignin, and Pine Biochars","volume":"46","author":"Rutherford","year":"2012","journal-title":"Biomass Bioenergy"},{"key":"ref_98","doi-asserted-by":"crossref","first-page":"1126","DOI":"10.1016\/j.rser.2015.12.185","article-title":"Lignocellulosic Biomass Pyrolysis: A Review of Product Properties and Effects of Pyrolysis Parameters","volume":"57","author":"Kan","year":"2016","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_99","doi-asserted-by":"crossref","first-page":"433","DOI":"10.1016\/j.biortech.2014.08.104","article-title":"Pyrolysis of Coal, Biomass and Their Blends: Performance Assessment by Thermogravimetric Analysis","volume":"171","author":"Ferrara","year":"2014","journal-title":"Bioresour. Technol."},{"key":"ref_100","doi-asserted-by":"crossref","first-page":"11104","DOI":"10.1021\/es302345e","article-title":"Fast and Slow Rates of Naphthalene Sorption to Biochars Produced at Different Temperatures","volume":"46","author":"Chen","year":"2012","journal-title":"Environ. Sci. Technol."},{"key":"ref_101","doi-asserted-by":"crossref","first-page":"123442","DOI":"10.1016\/j.biortech.2020.123442","article-title":"Hydochar and Biochar: Production, Physicochemical Properties and Techno-Economic Analysis","volume":"310","author":"Kumar","year":"2020","journal-title":"Bioresour. Technol."},{"key":"ref_102","doi-asserted-by":"crossref","first-page":"23","DOI":"10.1016\/j.jaap.2012.11.005","article-title":"Fast Pyrolysis of Amazon Tucum\u00e3 (Astrocaryum Aculeatum) Seeds in a Bubbling Fluidized Bed Reactor","volume":"99","author":"Lira","year":"2013","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"ref_103","doi-asserted-by":"crossref","first-page":"348","DOI":"10.1016\/j.biortech.2012.09.061","article-title":"Physicochemical Properties of Bio-Oil and Biochar Produced by Fast Pyrolysis of Stored Single-Pass Corn Stover and Cobs","volume":"125","author":"Shah","year":"2012","journal-title":"Bioresour. Technol."},{"key":"ref_104","doi-asserted-by":"crossref","first-page":"68","DOI":"10.1016\/j.biombioe.2011.01.048","article-title":"Review of Fast Pyrolysis of Biomass and Product Upgrading","volume":"38","author":"Bridgwater","year":"2012","journal-title":"Biomass Bioenergy"},{"key":"ref_105","doi-asserted-by":"crossref","first-page":"651","DOI":"10.1016\/S0196-8904(03)00177-8","article-title":"Pyrolysis of Biomass to Produce Fuels and Chemical Feedstocks","volume":"45","author":"Yaman","year":"2004","journal-title":"Energy Convers. Manag."},{"key":"ref_106","doi-asserted-by":"crossref","first-page":"2237","DOI":"10.1007\/s10311-020-01165-9","article-title":"Biochar Production, Activation and Adsorptive Applications: A Review","volume":"19","author":"Patra","year":"2021","journal-title":"Environ. Chem. Lett."},{"key":"ref_107","doi-asserted-by":"crossref","first-page":"161","DOI":"10.1016\/j.biombioe.2011.12.017","article-title":"Comparison of Kiln-Derived and Gasifier-Derived Biochars as Soil Amendments in the Humid Tropics","volume":"37","author":"Deal","year":"2012","journal-title":"Biomass Bioenergy"},{"key":"ref_108","doi-asserted-by":"crossref","first-page":"236","DOI":"10.1016\/j.biortech.2017.04.012","article-title":"Hydrochar Production from Watermelon Peel by Hydrothermal Carbonization","volume":"241","author":"Chen","year":"2017","journal-title":"Bioresour. Technol."},{"key":"ref_109","doi-asserted-by":"crossref","first-page":"359","DOI":"10.1016\/j.rser.2015.01.050","article-title":"A Comparative Review of Biochar and Hydrochar in Terms of Production, Physico-Chemical Properties and Applications","volume":"45","author":"Kambo","year":"2015","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_110","doi-asserted-by":"crossref","first-page":"264","DOI":"10.1016\/j.biombioe.2013.08.026","article-title":"Chemical Evaluation of Chars Produced by Thermochemical Conversion (Gasification, Pyrolysis and Hydrothermal Carbonization) of Agro-Industrial Biomass on a Commercial Scale","volume":"59","author":"Wiedner","year":"2013","journal-title":"Biomass Bioenergy"},{"key":"ref_111","doi-asserted-by":"crossref","first-page":"1971","DOI":"10.1016\/S0008-6223(01)00026-4","article-title":"Pore Structure and Surface Chemistry of Adsorbents Obtained by Pyrolysis of Sewage Sludge-Derived Fertilizer","volume":"39","author":"Bagreev","year":"2001","journal-title":"Carbon"},{"key":"ref_112","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1016\/S0008-6223(97)00173-5","article-title":"The Role of Carbon Materials in Heterogeneous Catalysis","volume":"36","year":"1998","journal-title":"Carbon"},{"key":"ref_113","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1016\/j.energy.2018.08.161","article-title":"Slow Pyrolysis of By-Product Lignin from Wood-Based Ethanol Production\u2013 A Detailed Analysis of the Produced Chars","volume":"164","author":"Mattila","year":"2018","journal-title":"Energy"},{"key":"ref_114","doi-asserted-by":"crossref","first-page":"137775","DOI":"10.1016\/j.scitotenv.2020.137775","article-title":"Biochar Production and Applications in Agro and Forestry Systems: A Review","volume":"723","author":"Wang","year":"2020","journal-title":"Sci. Total Environ."},{"key":"ref_115","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1016\/j.fuel.2015.10.101","article-title":"Pyrolysis of Eastern Redcedar: Distribution and Characteristics of Fast and Slow Pyrolysis Products","volume":"166","author":"Yang","year":"2016","journal-title":"Fuel"},{"key":"ref_116","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1016\/j.jaap.2016.10.021","article-title":"Characterisation of Malaysian Wood Pellets and Rubberwood Using Slow Pyrolysis and Microwave Technology","volume":"122","author":"Halim","year":"2016","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"ref_117","doi-asserted-by":"crossref","first-page":"137116","DOI":"10.1016\/j.scitotenv.2020.137116","article-title":"Algae as Potential Feedstock for the Production of Biofuels and Value-Added Products: Opportunities and Challenges","volume":"716","author":"Kumar","year":"2020","journal-title":"Sci. Total Environ."},{"key":"ref_118","doi-asserted-by":"crossref","first-page":"527","DOI":"10.1016\/j.renene.2018.08.025","article-title":"Study on Co-Pyrolysis Synergistic Mechanism of Seaweed and Rice Husk by Investigation of the Characteristics of Char\/Coke","volume":"132","author":"Xu","year":"2019","journal-title":"Renew. Energy"},{"key":"ref_119","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1016\/j.energy.2013.01.059","article-title":"Bio-Oil Production through Pyrolysis of Blue-Green Algae Blooms (BGAB): Product Distribution and Bio-Oil Characterization","volume":"52","author":"Hu","year":"2013","journal-title":"Energy"},{"key":"ref_120","doi-asserted-by":"crossref","first-page":"187","DOI":"10.1016\/j.rser.2016.06.003","article-title":"Characterization of Biochars Produced from Pyrolysis of Pelletized Agricultural Residues","volume":"64","author":"Colantoni","year":"2016","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_121","doi-asserted-by":"crossref","first-page":"12809","DOI":"10.1007\/s11356-017-8847-2","article-title":"Characteristics and Mechanisms of Nickel Adsorption on Biochars Produced from Wheat Straw Pellets and Rice Husk","volume":"24","author":"Shen","year":"2017","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_122","doi-asserted-by":"crossref","first-page":"121348","DOI":"10.1016\/j.biortech.2019.121348","article-title":"Characteristics of Tetracycline Adsorption by Cow Manure Biochar Prepared at Different Pyrolysis Temperatures","volume":"285","author":"Zhang","year":"2019","journal-title":"Bioresour. Technol."},{"key":"ref_123","doi-asserted-by":"crossref","first-page":"977","DOI":"10.1016\/j.jclepro.2017.11.013","article-title":"Effect of Pyrolysis Temperature, Heating Rate, and Residence Time on Rapeseed Stem Derived Biochar","volume":"174","author":"Zhao","year":"2018","journal-title":"J. Clean. Prod."},{"key":"ref_124","doi-asserted-by":"crossref","first-page":"218","DOI":"10.1016\/j.jclepro.2017.04.115","article-title":"Cleaner Production of Iron by Using Waste Macadamia Biomass as a Carbon Resource","volume":"158","author":"Kumar","year":"2017","journal-title":"J. Clean. Prod."},{"key":"ref_125","doi-asserted-by":"crossref","first-page":"836","DOI":"10.1016\/j.fuel.2013.01.033","article-title":"Effect of Feedstock Water Content and Pyrolysis Temperature on the Structure and Reactivity of Spruce Wood Char Produced in Fixed Bed Pyrolysis","volume":"107","author":"Burhenne","year":"2013","journal-title":"Fuel"},{"key":"ref_126","doi-asserted-by":"crossref","first-page":"4605","DOI":"10.1021\/ef900268y","article-title":"Pyrolysis of Maize Stalk on the Characterization of Chars Formed under Different Devolatilization Conditions","volume":"23","author":"Fu","year":"2009","journal-title":"Energy Fuels"},{"key":"ref_127","doi-asserted-by":"crossref","first-page":"655","DOI":"10.1016\/j.fuel.2017.11.107","article-title":"Performance of Bio-Char and Energy Analysis on CH4 Combined Reforming by CO2 and H2O into Syngas Production with Assistance of Microwave","volume":"215","author":"Li","year":"2018","journal-title":"Fuel"},{"key":"ref_128","doi-asserted-by":"crossref","first-page":"1357","DOI":"10.1016\/j.scitotenv.2018.12.097","article-title":"Fe-Rich Biomass Derived Char for Microwave-Assisted Methane Reforming with Carbon Dioxide","volume":"657","author":"Li","year":"2019","journal-title":"Sci. Total Environ."},{"key":"ref_129","doi-asserted-by":"crossref","first-page":"116032","DOI":"10.1016\/j.fuel.2019.116032","article-title":"Roles of Alkali\/Alkaline Earth Metals in Steam Reforming of Biomass Tar for Hydrogen Production over Perovskite Supported Ni Catalysts","volume":"257","author":"Zhang","year":"2019","journal-title":"Fuel"},{"key":"ref_130","doi-asserted-by":"crossref","first-page":"5602","DOI":"10.1039\/D0CY00589D","article-title":"A Deactivation Mechanism Study of Phosphorus-Poisoned Diesel Oxidation Catalysts: Model and Supplier Catalysts","volume":"10","author":"Wang","year":"2020","journal-title":"Catal. Sci. Technol."},{"key":"ref_131","doi-asserted-by":"crossref","first-page":"1149","DOI":"10.1007\/BF02632158","article-title":"Poisoning of Nickel-based Catalysts in Fat Hydrogenation","volume":"70","author":"Irandoust","year":"1993","journal-title":"J. Am. Oil Chem. Soc."},{"key":"ref_132","unstructured":"Bartholomew, C.H. (1987). Mechanisms of Nickel Catalyst Poisoning. Studies in Surface Science and Catalysis, Elsevier."},{"key":"ref_133","doi-asserted-by":"crossref","first-page":"3672","DOI":"10.1039\/C4CY00522H","article-title":"Stability and Resistance of Nickel Catalysts for Hydrodeoxygenation: Carbon Deposition and Effects of Sulfur, Potassium, and Chlorine in the Feed","volume":"4","author":"Mortensen","year":"2014","journal-title":"Catal. Sci. Technol."},{"key":"ref_134","doi-asserted-by":"crossref","first-page":"113846","DOI":"10.1016\/j.cattod.2022.07.014","article-title":"Family of Biomass-Derived Ni and Ni\u2013Mn Catalysts of CO2 Methanation","volume":"424","author":"Chernyak","year":"2023","journal-title":"Catal. Today"},{"key":"ref_135","doi-asserted-by":"crossref","first-page":"5027","DOI":"10.1021\/acs.est.7b06487","article-title":"Insight into Multiple and Multilevel Structures of Biochars and Their Potential Environmental Applications: A Critical Review","volume":"52","author":"Xiao","year":"2018","journal-title":"Environ. Sci. Technol."},{"key":"ref_136","doi-asserted-by":"crossref","first-page":"109582","DOI":"10.1016\/j.rser.2019.109582","article-title":"Biochar-Based Adsorbents for Carbon Dioxide Capture: A Critical Review","volume":"119","author":"Dissanayake","year":"2020","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_137","doi-asserted-by":"crossref","first-page":"255","DOI":"10.1016\/j.rser.2017.05.057","article-title":"Biochar Properties and Eco-Friendly Applications for Climate Change Mitigation, Waste Management, and Wastewater Treatment: A Review","volume":"79","author":"Qambrani","year":"2017","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_138","doi-asserted-by":"crossref","first-page":"60","DOI":"10.1016\/j.scitotenv.2018.07.099","article-title":"Impact of Biochar Amendment in Agricultural Soils on the Sorption, Desorption, and Degradation of Pesticides: A Review","volume":"645","author":"Liu","year":"2018","journal-title":"Sci. Total Environ."},{"key":"ref_139","doi-asserted-by":"crossref","first-page":"6237","DOI":"10.1007\/s13399-021-01612-9","article-title":"Construction of Fungus Waste-Derived Porous Carbon as Electrode Materials for Electrochemical Supercapacitor","volume":"13","author":"Li","year":"2023","journal-title":"Biomass Convers. Biorefin."},{"key":"ref_140","doi-asserted-by":"crossref","unstructured":"Meiirkhanuly, Z., Koziel, J.A., Bia\u0142owiec, A., Banik, C., and Brown, R.C. (2019). The-Proof-of-Concept of Biochar Floating Cover Influence on Water PH. Water, 11.","DOI":"10.3390\/w11091802"},{"key":"ref_141","doi-asserted-by":"crossref","first-page":"45519","DOI":"10.1007\/s11356-021-13869-8","article-title":"Biochar-Templated Surface Precipitation and Inner-Sphere Complexation Effectively Removes Arsenic from Acid Mine Drainage","volume":"28","author":"Wang","year":"2021","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_142","doi-asserted-by":"crossref","first-page":"130512","DOI":"10.1016\/j.chemosphere.2021.130512","article-title":"Green and Simple Approach for Low-Cost Bioproducts Preparation and CO2 Capture","volume":"279","author":"Kostas","year":"2021","journal-title":"Chemosphere"},{"key":"ref_143","doi-asserted-by":"crossref","first-page":"130990","DOI":"10.1016\/j.chemosphere.2021.130990","article-title":"Hierarchically Porous Magnetic Biochar as an Efficient Amendment for Cadmium in Water and Soil: Performance and Mechanism","volume":"281","author":"Fu","year":"2021","journal-title":"Chemosphere"},{"key":"ref_144","doi-asserted-by":"crossref","first-page":"105004","DOI":"10.1088\/1402-4896\/ac0f3b","article-title":"Evaluation of Palm Kernel Shell Biochar for the Adsorption of Bacillus Cereus","volume":"96","author":"Ajeng","year":"2021","journal-title":"Phys. Scr."},{"key":"ref_145","doi-asserted-by":"crossref","first-page":"118341","DOI":"10.1016\/j.fuel.2020.118341","article-title":"Steam Reforming of Acetic Acid over Ni\/Biochar Catalyst Treated with HNO3: Impacts of the Treatment on Surface Properties and Catalytic Behaviors","volume":"278","author":"Wang","year":"2020","journal-title":"Fuel"},{"key":"ref_146","doi-asserted-by":"crossref","first-page":"189","DOI":"10.1016\/j.fuproc.2012.05.014","article-title":"Influence of Alkali Metals on the Kinetics of the Thermal Decomposition of Biomass","volume":"104","author":"Saddawi","year":"2012","journal-title":"Fuel Process. Technol."},{"key":"ref_147","doi-asserted-by":"crossref","first-page":"120426","DOI":"10.1016\/j.fuel.2021.120426","article-title":"Co-Presence of Hydrophilic and Hydrophobic Sites in Ni\/Biochar Catalyst for Enhancing the Hydrogenation Activity","volume":"293","author":"Wang","year":"2021","journal-title":"Fuel"},{"key":"ref_148","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1006\/jcat.2002.3637","article-title":"Properties of Carbon-Supported Platinum Catalysts: Role of Carbon Surface Sites","volume":"209","author":"Fraga","year":"2002","journal-title":"J. Catal."},{"key":"ref_149","doi-asserted-by":"crossref","first-page":"153959","DOI":"10.1016\/j.scitotenv.2022.153959","article-title":"Pyrolysis of Cellulose: Correlation of Hydrophilicity with Evolution of Functionality of Biochar","volume":"825","author":"Fan","year":"2022","journal-title":"Sci. Total Environ."},{"key":"ref_150","doi-asserted-by":"crossref","first-page":"119759","DOI":"10.1016\/j.fuel.2020.119759","article-title":"Influence of Activation Conditions on Textural Properties and Performance of Activated Biochars for Pyrolysis Vapors Upgrading","volume":"289","author":"Greco","year":"2021","journal-title":"Fuel"},{"key":"ref_151","doi-asserted-by":"crossref","first-page":"359","DOI":"10.1016\/j.biortech.2016.12.083","article-title":"Biochar as Potential Sustainable Precursors for Activated Carbon Production: Multiple Applications in Environmental Protection and Energy Storage","volume":"227","author":"Tan","year":"2017","journal-title":"Bioresour. Technol."},{"key":"ref_152","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1016\/j.biombioe.2018.04.015","article-title":"Production and Characterization of Activated Carbon from Barley Straw by Physical Activation with Carbon Dioxide and Steam","volume":"115","author":"Arauzo","year":"2018","journal-title":"Biomass Bioenergy"},{"key":"ref_153","doi-asserted-by":"crossref","first-page":"505","DOI":"10.1016\/0008-6223(96)00006-1","article-title":"Effect of Steam and Carbon Dioxide Activation in the Micropore Size Distribution of Activated Carbon","volume":"34","author":"Gonzalez","year":"1996","journal-title":"Carbon"},{"key":"ref_154","doi-asserted-by":"crossref","first-page":"2411","DOI":"10.1039\/C6TA08742F","article-title":"Biomass Derived Carbon for Energy Storage Devices","volume":"5","author":"Wang","year":"2017","journal-title":"J. Mater. Chem. A Mater."},{"key":"ref_155","doi-asserted-by":"crossref","first-page":"276","DOI":"10.1016\/j.chemosphere.2016.01.043","article-title":"Engineered\/Designer Biochar for Contaminant Removal\/Immobilization from Soil and Water: Potential and Implication of Biochar Modification","volume":"148","author":"Rajapaksha","year":"2016","journal-title":"Chemosphere"},{"key":"ref_156","doi-asserted-by":"crossref","first-page":"104473","DOI":"10.1016\/j.jece.2020.104473","article-title":"Treatment of Effluents Containing 2-Chlorophenol by Adsorption onto Chemically and Physically Activated Biochars","volume":"8","author":"Machado","year":"2020","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_157","doi-asserted-by":"crossref","first-page":"14640","DOI":"10.1039\/C6RA27881G","article-title":"Characterization of KOH Modified Biochars from Different Pyrolysis Temperatures and Enhanced Adsorption of Antibiotics","volume":"7","author":"Huang","year":"2017","journal-title":"RSC Adv."},{"key":"ref_158","doi-asserted-by":"crossref","first-page":"122736","DOI":"10.1016\/j.cej.2019.122736","article-title":"Porous Activated Carbons Derived from Waste Sugarcane Bagasse for CO2 Adsorption","volume":"381","author":"Guo","year":"2020","journal-title":"Chem. Eng. J."},{"key":"ref_159","doi-asserted-by":"crossref","first-page":"123205","DOI":"10.1016\/j.cej.2019.123205","article-title":"A Green Trace K2CO3 Induced Catalytic Activation Strategy for Developing Coal-Converted Activated Carbon as Advanced Candidate for CO2 Adsorption and Supercapacitors","volume":"383","author":"Wang","year":"2020","journal-title":"Chem. Eng. J."},{"key":"ref_160","doi-asserted-by":"crossref","first-page":"601","DOI":"10.1016\/S2095-4956(14)60190-X","article-title":"Effects of Thermal Activation Conditions on the Microstructure Regulation of Corncob-Derived Activated Carbon for Hydrogen Storage","volume":"23","author":"Wang","year":"2014","journal-title":"J. Energy Chem."},{"key":"ref_161","doi-asserted-by":"crossref","first-page":"8303","DOI":"10.15376\/biores.15.4.8303-8322","article-title":"Characterization of Ball-Milled Bamboo-Based Activated Carbon Treated with KMnO4 and KOH as Activating Agents","volume":"15","author":"Qanytah","year":"2020","journal-title":"Bioresources"},{"key":"ref_162","doi-asserted-by":"crossref","first-page":"968","DOI":"10.1016\/j.jclepro.2019.04.121","article-title":"Optimized Preparation for Bimodal Porous Carbon from Lentil Processing Waste by Microwave-Assisted K2CO3 Activation: Spectroscopic Characterization and Dye Decolorization Activity","volume":"226","year":"2019","journal-title":"J. Clean. Prod."},{"key":"ref_163","doi-asserted-by":"crossref","first-page":"437","DOI":"10.1016\/j.biombioe.2010.08.061","article-title":"Surface Texture, Chemistry and Adsorption Properties of Acid Blue 9 of Hemp (Cannabis Sativa L.) Bast-Based Activated Carbon Fibers Prepared by Phosphoric Acid Activation","volume":"35","author":"Yang","year":"2011","journal-title":"Biomass Bioenergy"},{"key":"ref_164","first-page":"4720","article-title":"Research Progress of Biochar Activation Technology and Biochar Catalyst","volume":"41","author":"Qing","year":"2021","journal-title":"China Environ. Sci."},{"key":"ref_165","doi-asserted-by":"crossref","unstructured":"Yu, H., Wu, L., Ni, B., and Chen, T. (2023). Research Progress on Porous Carbon-Based Non-Precious Metal Electrocatalysts. Materials, 16.","DOI":"10.3390\/ma16083283"},{"key":"ref_166","doi-asserted-by":"crossref","unstructured":"D\u2019Aniello, M.J. (1982). Noble Metal Recovery from Spent Automotive Catalysts. Proceedings of the SAE International Congress and Exposition, SAE International.","DOI":"10.4271\/820187"},{"key":"ref_167","doi-asserted-by":"crossref","first-page":"289","DOI":"10.1595\/147106713X663988","article-title":"Recovery of Palladium from Spent Activated Carbon-Supported Palladium Catalysts","volume":"57","year":"2013","journal-title":"Platin. Met. Rev."},{"key":"ref_168","doi-asserted-by":"crossref","first-page":"105162","DOI":"10.1016\/j.ijrmhm.2019.105162","article-title":"Process Optimization and Modeling of Recycling Mo (VI) from Spent Mo-Fe2O3\/Al2O3 Catalyst by Roasting with Sodium Carbonate Using Response Surface Methodology (RSM)","volume":"87","author":"He","year":"2020","journal-title":"Int. J. Refract. Met. Hard Mater."},{"key":"ref_169","doi-asserted-by":"crossref","first-page":"22131","DOI":"10.1038\/s41598-021-01726-0","article-title":"Hydrometallurgical Process Development to Recycle Valuable Metals from Spent SCR DeNOX Catalyst","volume":"11","author":"Jeon","year":"2021","journal-title":"Sci. Rep."},{"key":"ref_170","unstructured":"Ganaj Petr (2026, May 15). Available online: https:\/\/www.pexels.com\/photo\/golden-yellow-maple-leaf-in-close-up-photography-4055749\/."},{"key":"ref_171","doi-asserted-by":"crossref","first-page":"101740","DOI":"10.1016\/j.jcou.2021.101740","article-title":"Biochar as Support in Catalytic CO2 Methanation: Enhancing Effect of CeO2 Addition","volume":"53","author":"Renda","year":"2021","journal-title":"J. CO2 Util."},{"key":"ref_172","doi-asserted-by":"crossref","first-page":"115842","DOI":"10.1016\/j.apenergy.2020.115842","article-title":"Effects of Slow-Pyrolysis Conditions on the Products Yields and Properties and on Exergy Efficiency: A Comprehensive Assessment for Wheat Straw","volume":"279","author":"Greco","year":"2020","journal-title":"Appl. Energy"},{"key":"ref_173","doi-asserted-by":"crossref","unstructured":"Di Stasi, C., Renda, S., Greco, G., Gonz\u00e1lez, B., Palma, V., and Many\u00e0, J.J. (2021). Wheat-Straw-Derived Activated Biochar as a Renewable Support of Ni-Ceo2 Catalysts for Co2 Methanation. Sustainability, 13.","DOI":"10.3390\/su13168939"},{"key":"ref_174","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1016\/S1872-5813(22)60038-0","article-title":"Research Progress on the Preparation Process of Biochar-Based Catalyst Support for Dry Reforming of Methane","volume":"51","author":"Chen","year":"2023","journal-title":"Ranliao Huaxue Xuebao\/J. Fuel Chem. Technol."},{"key":"ref_175","doi-asserted-by":"crossref","first-page":"676","DOI":"10.1016\/j.jcou.2019.08.020","article-title":"Reduced Graphene Oxide Supported Ni-Ce Catalysts for CO2 Methanation: The Support and Ceria Promotion Effects","volume":"34","author":"Hu","year":"2019","journal-title":"J. CO2 Util."},{"key":"ref_176","doi-asserted-by":"crossref","first-page":"114","DOI":"10.1016\/j.fuproc.2019.05.008","article-title":"Optimization of Nickel and Ceria Catalyst Content for Synthetic Natural Gas Production through CO2 Methanation","volume":"193","author":"Guilera","year":"2019","journal-title":"Fuel Process. Technol."},{"key":"ref_177","doi-asserted-by":"crossref","first-page":"323","DOI":"10.1016\/j.jechem.2020.06.007","article-title":"Nickel Nanoparticles Supported on Nitrogen\u2013Doped Carbon Nanotubes Are a Highly Active, Selective and Stable CO2 Methanation Catalyst","volume":"54","author":"Merko","year":"2021","journal-title":"J. Energy Chem."},{"key":"ref_178","doi-asserted-by":"crossref","first-page":"7217","DOI":"10.1039\/D0CY01254H","article-title":"The Role of Surface Properties in CO2 Methanation over Carbon-Supported Ni Catalysts and Their Promotion by Fe","volume":"10","author":"Sousa","year":"2020","journal-title":"Catal. Sci. Technol."},{"key":"ref_179","doi-asserted-by":"crossref","first-page":"106250","DOI":"10.1016\/j.biombioe.2021.106250","article-title":"Direct Synthesis of Methane-Rich Gas from Reed Biomass Pyrolysis Volatiles over Its Biochar-Supported Ni Catalysts","volume":"154","author":"Yue","year":"2021","journal-title":"Biomass Bioenergy"},{"key":"ref_180","doi-asserted-by":"crossref","unstructured":"Dudek, K., Ma\u0142ecki, S., Kornaus, K., and \u017babi\u0144ski, P. (2025). The Influence of Starting Plant Material on Ni@C-Type Composites\u2019 Characteristics. Materials, 18.","DOI":"10.3390\/ma18163784"},{"key":"ref_181","doi-asserted-by":"crossref","first-page":"120950","DOI":"10.1016\/j.fuel.2021.120950","article-title":"Trimetallic Ni-Co-Ru Catalyst for the Dry Reforming of Methane: Effect of the Ni\/Co Ratio and the Calcination Temperature","volume":"300","author":"Aramouni","year":"2021","journal-title":"Fuel"},{"key":"ref_182","doi-asserted-by":"crossref","first-page":"121222","DOI":"10.1016\/j.fuel.2021.121222","article-title":"Study on Syngas Methanation over Municipal Solid Waste Char Supported Ni Catalyst","volume":"303","author":"Luo","year":"2021","journal-title":"Fuel"},{"key":"ref_183","doi-asserted-by":"crossref","first-page":"765","DOI":"10.1016\/j.pecs.2011.12.001","article-title":"A Short Overview on Purification and Conditioning of Syngas Produced by Biomass Gasification: Catalytic Strategies, Process Intensification and New Concepts","volume":"38","author":"Richardson","year":"2012","journal-title":"Prog. Energy Combust. Sci."},{"key":"ref_184","doi-asserted-by":"crossref","first-page":"443","DOI":"10.1134\/S0965544123030234","article-title":"Hydrogenation of CO2 over Biochar-Supported Catalysts","volume":"63","author":"Svidersky","year":"2023","journal-title":"Pet. Chem."},{"key":"ref_185","first-page":"100627","article-title":"CO2 Methanation Using Sugarcane Bagasse Biochar\/Nickel Sustainable Catalysts","volume":"25","author":"Gamal","year":"2024","journal-title":"Mater. Today Sustain."},{"key":"ref_186","doi-asserted-by":"crossref","first-page":"115919","DOI":"10.1016\/j.apenergy.2020.115919","article-title":"Experimental Study and Life Cycle Assessment of CO2 Methanation over Biochar Supported Catalysts","volume":"280","author":"Wang","year":"2020","journal-title":"Appl. Energy"},{"key":"ref_187","doi-asserted-by":"crossref","first-page":"326","DOI":"10.1016\/j.apenergy.2016.12.098","article-title":"Life Cycle Assessment of Power-to-Gas: Approaches, System Variations and Their Environmental Implications","volume":"190","author":"Zhang","year":"2017","journal-title":"Appl. Energy"},{"key":"ref_188","doi-asserted-by":"crossref","first-page":"733","DOI":"10.1016\/j.jcou.2019.09.003","article-title":"Biomass Derived N-Doped Biochar as Efficient Catalyst Supports for CO2 Methanation","volume":"34","author":"Wang","year":"2019","journal-title":"J. CO2 Util."},{"key":"ref_189","doi-asserted-by":"crossref","first-page":"612","DOI":"10.1007\/s10562-014-1426-y","article-title":"CeO2 Promoted Mesoporous Ni\/\u03b3-Al2O3 Catalyst and Its Reaction Conditions For CO2 Methanation","volume":"145","author":"Zhou","year":"2015","journal-title":"Catal. Lett."},{"key":"ref_190","doi-asserted-by":"crossref","first-page":"12","DOI":"10.1016\/j.biombioe.2015.11.025","article-title":"Enhancement of Methanation of Bio-Syngas over CeO2-Modified Ni\/Al2O3 Catalysts","volume":"85","author":"Ding","year":"2016","journal-title":"Biomass Bioenergy"},{"key":"ref_191","doi-asserted-by":"crossref","first-page":"838","DOI":"10.1002\/slct.201803369","article-title":"Influence of Mg-promoted Ni-based Catalyst Supported on Coconut Shell Carbon for CO2 Methanation","volume":"4","author":"Li","year":"2019","journal-title":"ChemistrySelect"},{"key":"ref_192","doi-asserted-by":"crossref","first-page":"8552","DOI":"10.1021\/acs.energyfuels.3c00908","article-title":"CO2 Methanation on Ni Catalysts Supported over Activated Carbons Derived from Cork Waste","volume":"37","author":"Mateus","year":"2023","journal-title":"Energy Fuels"},{"key":"ref_193","doi-asserted-by":"crossref","first-page":"408","DOI":"10.1016\/j.cej.2014.05.051","article-title":"Activated Carbons Prepared from Industrial Pre-Treated Cork: Sustainable Adsorbents for Pharmaceutical Compounds Removal","volume":"253","author":"Mestre","year":"2014","journal-title":"Chem. Eng. J."},{"key":"ref_194","unstructured":"Rey, M.D.C.B. (2018). CO2 Conversion to CH4 Using Metallic Catalysts Supported on Zeolites. CO2 + 4H2 CH4 + 2H2O Ni0Ni0Ni0. [Ph.D. Thesis, Universidade De Lisboa Instituto Superior T\u00e9cnico]."},{"key":"ref_195","doi-asserted-by":"crossref","first-page":"2388","DOI":"10.1002\/cctc.201900229","article-title":"Tuning Zeolite Properties towards CO2 Methanation: An Overview","volume":"11","author":"Bacariza","year":"2019","journal-title":"ChemCatChem"},{"key":"ref_196","doi-asserted-by":"crossref","first-page":"17212","DOI":"10.1021\/acs.energyfuels.1c01682","article-title":"Highly Active Ce- And Mg-Promoted Ni Catalysts Supported on Cellulose-Derived Carbon for Low-Temperature CO2 Methanation","volume":"35","author":"Tarifa","year":"2021","journal-title":"Energy Fuels"},{"key":"ref_197","doi-asserted-by":"crossref","first-page":"361056","DOI":"10.1155\/2017\/4361056","article-title":"The Impact of Ce-Zr Addition on Nickel Dispersion and Catalytic Behavior for CO2 Methanation of Ni\/AC Catalyst at Low Temperature","volume":"2017","author":"Le","year":"2017","journal-title":"J. Chem."},{"key":"ref_198","doi-asserted-by":"crossref","unstructured":"Dudek, K., Wojtaszek, K., and \u017babi\u0144ski, P. (2024). Ni-Doped Activated Carbon from Invasive Plants as a Potential Catalyst. Metals, 14.","DOI":"10.3390\/met14070790"}],"container-title":["Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1944\/19\/11\/2194\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,5,22]],"date-time":"2026-05-22T16:10:26Z","timestamp":1779466226000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1944\/19\/11\/2194"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,22]]},"references-count":198,"journal-issue":{"issue":"11","published-online":{"date-parts":[[2026,6]]}},"alternative-id":["ma19112194"],"URL":"https:\/\/doi.org\/10.3390\/ma19112194","relation":{},"ISSN":["1996-1944"],"issn-type":[{"value":"1996-1944","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,22]]}}}