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Herein, we report a facile strategy for preparing a multi-component synergistic anti-corrosion coating, where two-dimensional graphitic carbon nitride (g-C3N4) and high-entropy layered double hydroxides (HE-LDHs) are integrated into a waterborne epoxy matrix via magnetic-ultrasonic synergistic dispersion. The resulting HE-LDHs\/g-C3N4-epoxy coating exhibits exceptional corrosion resistance for Q235 steel. Electrochemical impedance spectroscopy (EIS) and polarization curves showed that when the mass ratio of g-C3N4 to HE-LDHs was 1:1, the resulting coating (PCN-LDH-1.0) maintained a coating resistance of 5.48 \u00d7 105 \u03a9\u00b7m2 after 28 days of immersion in 3.5% NaCl solution, which was five orders of magnitude higher than that of pure waterborne epoxy coating. Meanwhile, the corrosion current density was reduced by four orders of magnitude, from 5.83 \u00d7 10\u22121 A\u00b7m\u22122 to 1.68 \u00d7 10\u22125 A\u00b7m\u22122. After 30 days of salt spray testing, no rust, blistering or adhesion loss was observed on the coating surface. These enhanced performances by addition of g-C3N4 and HE-LDHs were attributed to the combined effects of the tortuous diffusion pathways. Additionally, the PCN-LDH-1.0 coating retained excellent mechanical properties, including a pencil hardness of 3H and the highest adhesion grade. This study provides a facile method for preparing high-performance waterborne anti-corrosion coatings.<\/jats:p>","DOI":"10.3390\/ma19122576","type":"journal-article","created":{"date-parts":[[2026,6,15]],"date-time":"2026-06-15T08:57:58Z","timestamp":1781513878000},"page":"2576","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Enhanced Corrosion Resistance of Waterborne Epoxy Coatings by High-Entropy Layered Double Hydroxides\/Graphitic Carbon Nitride Fillers"],"prefix":"10.3390","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3953-8065","authenticated-orcid":false,"given":"Shaolei","family":"Song","sequence":"first","affiliation":[{"name":"School of Civil Engineering, Xuzhou University of Technology, Xuzhou 221018, China"},{"name":"Analysis and Testing Center, Xuzhou University of Technology, Xuzhou 221018, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Civil Engineering, Xuzhou University of Technology, Xuzhou 221018, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peiqi","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Civil Engineering, Xuzhou University of Technology, Xuzhou 221018, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenchang","family":"Liang","sequence":"additional","affiliation":[{"name":"School of Civil Engineering, Xuzhou University of Technology, Xuzhou 221018, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanyuan","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Materials and Chemical Engineering, Xuzhou University of Technology, Xuzhou 221018, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4308-1210","authenticated-orcid":false,"given":"Dongjiang","family":"Pan","sequence":"additional","affiliation":[{"name":"School of Civil Engineering, Xuzhou University of Technology, Xuzhou 221018, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qing","family":"Guo","sequence":"additional","affiliation":[{"name":"School of Civil Engineering, Xuzhou University of Technology, Xuzhou 221018, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Lei","sequence":"additional","affiliation":[{"name":"School of Civil Engineering, Xuzhou University of Technology, Xuzhou 221018, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Li","sequence":"additional","affiliation":[{"name":"School of Civil Engineering, Xuzhou University of Technology, Xuzhou 221018, China"},{"name":"Analysis and Testing Center, Xuzhou University of Technology, Xuzhou 221018, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2026,6,15]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"105448","DOI":"10.1016\/j.porgcoat.2019.105448","article-title":"Graphic C3N4-assisted dispersion of graphene to improve the corrosion resistance of waterborne epoxy coating","volume":"139","author":"Chen","year":"2020","journal-title":"Prog. Org. Coat."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"137624","DOI":"10.1016\/j.cej.2022.137624","article-title":"Developing epoxy-based anti-corrosion functional nanocomposite coating with CaFe-Tolyl-triazole layered double hydroxide@g-C3N4 as nanofillers on Q235 steel substrate against NaCl corrosive environment","volume":"450","author":"Tabish","year":"2022","journal-title":"Chem. Eng. J."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"52356","DOI":"10.1002\/app.52356","article-title":"Enhanced anti-aging and anti-corrosion performance of waterborne epoxy coating layers over the dual effects of g-C3N4 photocatalysis","volume":"139","author":"Ma","year":"2022","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"107276","DOI":"10.1016\/j.porgcoat.2022.107276","article-title":"Benzotriazole corrosion inhibitor loaded nanocontainer based on g-C3N4 and hollow polyaniline spheres towards enhancing anticorrosion performance of waterborne epoxy coatings","volume":"174","author":"Li","year":"2023","journal-title":"Prog. Org. Coat."},{"key":"ref_5","doi-asserted-by":"crossref","unstructured":"Hao, J.-H., Yang, K., Wu, J.-Y., Wu, M.-Z., and Li, Y. (2025). Overview of recent developments in composite epoxy resin in organic coating on steel (2020\u20132024). Materials, 18.","DOI":"10.3390\/ma18071531"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"150444","DOI":"10.1016\/j.cej.2024.150444","article-title":"Integrated comprehensive protection coating achieved by ligand engineering modulated MXene@LDH heterojunction with anti-corrosion, electromagnetic wave absorption and fire safety","volume":"486","author":"Liu","year":"2024","journal-title":"Chem. Eng. J."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"131306","DOI":"10.1016\/j.surfcoat.2024.131306","article-title":"Synthesis of PDA-rGO\/MoO3 nanohybrids for distinguishable anticorrosion enhancement of waterborne epoxy coating","volume":"494","author":"Zhou","year":"2024","journal-title":"Surf. Coat. Technol."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"142","DOI":"10.1016\/j.jhazmat.2019.05.063","article-title":"Polydopamine modified polyaniline-graphene oxide composite for enhancement of corrosion resistance","volume":"377","author":"Yang","year":"2019","journal-title":"J. Hazard. Mater."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1016\/j.compositesb.2017.01.046","article-title":"Thermo-mechanical and anti-corrosive properties of MWCNT\/epoxy nanocomposite fabricated by innovative dispersion technique","volume":"113","author":"Kumar","year":"2017","journal-title":"Compos. Part B Eng."},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Ke, K., Meng, K., Rong, J., and Yu, X.-H. (2022). Biphenylene: A two-dimensional graphene-based coating with superior anti-corrosion performance. Materials, 15.","DOI":"10.3390\/ma15165675"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"106986","DOI":"10.1016\/j.porgcoat.2022.106986","article-title":"Mussel-inspired hydrophobic modification of boron nitride nanosheets to enhance the dispersion and anticorrosive performance in polymeric coatings","volume":"170","author":"Sun","year":"2022","journal-title":"Prog. Org. Coat."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"4129","DOI":"10.1021\/am400016y","article-title":"Marine corrosion protective coatings of hexagonal boron nitride thin films on stainless steel","volume":"5","author":"Husain","year":"2013","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"133789","DOI":"10.1016\/j.matlet.2022.133789","article-title":"MXenes and MXene-based nanomaterials for corrosion protection","volume":"335","author":"Sharma","year":"2023","journal-title":"Mater. Lett."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"105692","DOI":"10.1016\/j.mtcomm.2023.105692","article-title":"A hydrophobic high-crystalline g-C3N4\/epoxy resin composite coating with excellent durability and stability for long-term corrosion resistance","volume":"35","author":"Li","year":"2023","journal-title":"Mater. Today Commun."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"4223","DOI":"10.1007\/s10853-023-08300-1","article-title":"Synthesis of N-deficient g-C3N4\/epoxy composite coating for enhanced photocatalytic corrosion resistance and water purification","volume":"58","author":"Guo","year":"2023","journal-title":"J. Mater. Sci."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"100476","DOI":"10.1016\/j.ijoes.2024.100476","article-title":"Constructing non-covalently assembled g-C3N4@GO nanofillers to enhance the anti-corrosion performance of waterborne epoxy coatings","volume":"19","author":"He","year":"2024","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"104405","DOI":"10.1016\/j.reactfunctpolym.2019.104405","article-title":"Co-modification of polydopamine and KH560 on g-C3N4 nanosheets for enhancing the corrosion protection property of waterborne epoxy coating","volume":"146","author":"Xia","year":"2020","journal-title":"React. Funct. Polym."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"109028","DOI":"10.1016\/j.porgcoat.2024.109028","article-title":"Development on the anticorrosion of two-dimensional nanocontainer enhanced waterborne epoxy coatings based on mesoporous polypyrrole coated layered g-C3N4","volume":"200","author":"Gou","year":"2025","journal-title":"Prog. Org. Coat."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"11159","DOI":"10.1016\/j.ceramint.2024.12.534","article-title":"Synergistic anti-corrosion of self-healing microcapsule hybridized by MgAl LDHs-NO2: A combined experimental and DFT approach","volume":"51","author":"Zhu","year":"2025","journal-title":"Ceram. Int."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"111995","DOI":"10.1016\/j.corsci.2024.111995","article-title":"Insights into the hydrophobic coating with integrated high-efficiency anti-corrosion, anti-biofouling and self-healing properties based on anti-bacterial nano LDH materials","volume":"231","author":"Wang","year":"2024","journal-title":"Corros. Sci."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"2674","DOI":"10.1016\/j.jma.2024.07.002","article-title":"Maximizing the potential applications of plasma electrolytic oxidation coatings produced on Mg-based alloys in anti-corrosion, antibacterial, and photocatalytic targeting through harnessing the LDH\/PEO dual structure","volume":"12","author":"Nikoomanzari","year":"2024","journal-title":"J. Magn. Alloy."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"109381","DOI":"10.1016\/j.porgcoat.2025.109381","article-title":"Kaolin-supported NiCo-LDH nanocontainers for self-healing and anti-corrosion epoxy coatings","volume":"206","author":"Cao","year":"2025","journal-title":"Prog. Org. Coat."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"165625","DOI":"10.1016\/j.apsusc.2025.165625","article-title":"CoBi LDH based coating with integrated enhancement of anti-corrosion anti-fouling and photothermal self-healing properties","volume":"723","author":"Fang","year":"2026","journal-title":"Appl. Surf. Sci."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"109987","DOI":"10.1016\/j.porgcoat.2026.109987","article-title":"Fabrication of LDH-MoO42\u2212-Si coatings with enhanced anti-corrosion and self-repairing properties","volume":"213","author":"Fang","year":"2026","journal-title":"Prog. Org. Coat."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"186414","DOI":"10.1016\/j.jallcom.2026.186414","article-title":"Tailoring Lewis acidity via electron-deficient regions in NiFe LDH coupled with an anti-corrosion coating for efficient seawater oxygen evolution","volume":"1055","author":"Li","year":"2026","journal-title":"J. Alloys Compd."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"2401034","DOI":"10.1002\/smll.202401034","article-title":"Rational design strategy for high-valence metal-driven electronically modulated high-entropy Co-Ni-Fe-Cu-Mo (Oxy) hydroxide as superior multifunctional electrocatalysts","volume":"20","author":"Khan","year":"2024","journal-title":"Small"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"120408","DOI":"10.1016\/j.apcata.2025.120408","article-title":"Fabrication of FeCoNi LDH medium entropy hydroxide nanosheet for catalyzing oxygen evolution reaction","volume":"704","author":"Yue","year":"2025","journal-title":"Appl. Catal. A Gen."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"19558","DOI":"10.1021\/acsanm.5c03590","article-title":"Tuning layered double hydroxides from trimetallic to high-entropy nanomaterials for enhanced oxygen evolution in alkaline environments","volume":"8","author":"Pitchai","year":"2025","journal-title":"ACS Appl. Nano Mater."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1016\/j.jmst.2019.09.018","article-title":"Sulfur-doped g-C3N4\/rGO porous nanosheets for highly efficient photocatalytic degradation of refractory contaminants","volume":"41","author":"Zheng","year":"2020","journal-title":"J. Mater. Sci. Technol."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"109453","DOI":"10.1016\/j.compositesb.2021.109453","article-title":"Constructing hierarchical structure based on LDH anchored boron-doped g-C3N4 assembled with MnO2 nanosheets towards reducing toxicants generation and fire hazard of epoxy resin","volume":"229","author":"Wang","year":"2022","journal-title":"Compos. Part B Eng."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"112654","DOI":"10.1016\/j.corsci.2024.112654","article-title":"Develop a durable self-healing anticorrosion coating through a combined approach of passive Cl\u2212 blocking and active Cl\u2212 capture","volume":"244","author":"Liu","year":"2025","journal-title":"Corros. Sci."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"112353","DOI":"10.1016\/j.diamond.2025.112353","article-title":"Tailoring 2D PDA-Ti3C2 nanosheets doped ZnAl-layered double hydroxides (LDH) as smart anti-corrosion nanoreservoir for boosting the active\/barrier function of epoxy coatings","volume":"155","author":"Ren","year":"2025","journal-title":"Diam. Relat. Mater."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"105634","DOI":"10.1016\/j.porgcoat.2020.105634","article-title":"Phosphorylated polymer\/anionic surfactant doped polypyrrole in waterborne epoxy matrix toward enhanced mechanical and chemical resistance","volume":"143","author":"Wang","year":"2020","journal-title":"Prog. Org. Coat."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.corsci.2011.10.003","article-title":"Zn\u2013Al layered double hydroxides as chloride nanotraps in active protective coatings","volume":"55","author":"Tedim","year":"2012","journal-title":"Corros. Sci."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1016\/j.jechem.2020.12.029","article-title":"Ultrathin defective high-entropy layered double hydroxides for electrochemical water oxidation","volume":"60","author":"Gu","year":"2021","journal-title":"J. Energy Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"1734","DOI":"10.1039\/C6EE00377J","article-title":"Effect of interlayer anions on [NiFe]-LDH nanosheet water oxidation activity","volume":"9","author":"Hunter","year":"2016","journal-title":"Energy Environ. Sci."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"116724","DOI":"10.1016\/j.inoche.2026.116724","article-title":"LDH\/MOF composites: Synthesis, structural engineering and applications in energy and environment sectors","volume":"189","author":"Anwar","year":"2026","journal-title":"Inorg. Chem. Commun."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"8908","DOI":"10.1038\/s41598-018-27171-0","article-title":"One-step synthesis of Nickle Iron-layered double hydroxide\/reduced graphene oxide\/carbon nanofibres composite as electrode materials for asymmetric supercapacitor","volume":"8","author":"Wang","year":"2018","journal-title":"Sci. Rep."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"3689","DOI":"10.1016\/j.jma.2025.04.012","article-title":"A multi-level biomimetic LDH coatings with super hydrophobicity, corrosion resistance, anti-icing and anti-fouling properties on magnesium alloy","volume":"13","author":"Dai","year":"2025","journal-title":"J. Magnes. Alloy."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"107940","DOI":"10.1016\/j.porgcoat.2023.107940","article-title":"Intelligent anti-corrosion coating with multiple protections using active nanocontainers of Zn-Al LDH equipped with ZIF-8 encapsulated environment-friendly corrosion inhibitors","volume":"185","author":"Bai","year":"2023","journal-title":"Prog. Org. Coat."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"16","DOI":"10.1016\/j.carbon.2013.03.050","article-title":"The effect of graphene dispersion on the mechanical properties of graphene\/epoxy composites","volume":"60","author":"Tang","year":"2013","journal-title":"Carbon"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"121892","DOI":"10.1016\/j.ces.2025.121892","article-title":"Reinforced polyvinyl alcohol\/polyvinylpyrrolidone fertilizer coatings via tortuous diffusion and hydrogen bonding from layered double hydroxides","volume":"315","author":"Wang","year":"2025","journal-title":"Chem. Eng. Sci."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"140416","DOI":"10.1016\/j.colsurfa.2026.140416","article-title":"Investigation on outstanding corrosion protection property of waterborne epoxy coating enabled by nanocrystalline cellulose-dispersed g-C3N4 nanosheets","volume":"742","author":"Xia","year":"2026","journal-title":"Colloids Surf. A"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"2109","DOI":"10.1002\/pc.23390","article-title":"Mechanical, thermal, and viscoelastic response of novel in situ CTBN\/POSS\/epoxy hybrid composite system","volume":"37","author":"Konnola","year":"2016","journal-title":"Polym. Compos."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"371","DOI":"10.1016\/j.corsci.2008.11.015","article-title":"The role of a zinc phosphate pigment in the corrosion of scratched epoxy-coated steel","volume":"51","author":"Shao","year":"2009","journal-title":"Corros. Sci."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"3569","DOI":"10.1016\/j.corsci.2008.09.008","article-title":"Evaluation of the corrosion resistance of anodized aluminum 6061 using electrochemical impedance spectroscopy (EIS)","volume":"50","author":"Huang","year":"2008","journal-title":"Corros. Sci."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"387","DOI":"10.1016\/j.corsci.2014.07.056","article-title":"Electrochemical investigation of the properties of Co doped ZnO nanoparticle as a corrosion inhibitive pigment for modifying corrosion resistance of the epoxy coating","volume":"88","author":"Rostami","year":"2014","journal-title":"Corros. Sci."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"106391","DOI":"10.1016\/j.surfin.2025.106391","article-title":"Noncovalently functionalized hexagonal boron nitride nanosheets of poly(m-aminophenol) by enhanced corrosion protection of epoxy coating","volume":"65","author":"Fen","year":"2025","journal-title":"Surf. Interfaces"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"136508","DOI":"10.1016\/j.colsurfa.2025.136508","article-title":"2-Methylimidazole-functionalized Ti3C2Tx to improve corrosion resistance of epoxy coating in deep sea","volume":"713","author":"Bai","year":"2025","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"310","DOI":"10.1016\/j.corsci.2015.10.022","article-title":"Corrosion properties of the Mg alloy coated with polypyrrole films","volume":"102","author":"Roncevic","year":"2016","journal-title":"Corros. Sci."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"108808","DOI":"10.1016\/j.porgcoat.2024.108808","article-title":"Long-lasting anti-corrosion of waterborne epoxy resin synergistic modified with g-C3N4 and pH-responsive polypyrrole nanotubes","volume":"197","author":"Gou","year":"2024","journal-title":"Prog. Org. Coat."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"109309","DOI":"10.1016\/j.porgcoat.2025.109309","article-title":"Investigate the performance of functional coatings with physically modified boron nitride composite fillers","volume":"205","author":"Wang","year":"2025","journal-title":"Prog. Org. Coat."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"108800","DOI":"10.1016\/j.porgcoat.2024.108800","article-title":"Improved properties of epoxy composite coatings enabled by multi-dimension filler materials","volume":"197","author":"Wang","year":"2024","journal-title":"Prog. Org. Coat."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"109147","DOI":"10.1016\/j.porgcoat.2025.109147","article-title":"Enhanced anticorrosion of waterborne epoxy coatings by electrochemical exfoliated graphene oxide","volume":"202","author":"Hao","year":"2025","journal-title":"Prog. Org. Coat."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"131865","DOI":"10.1016\/j.colsurfa.2023.131865","article-title":"Two-dimensional lamellar MXene nanosheets\/waterborne epoxy composite coating: Dopamine triggered surface modification and long-term anticorrosion performance","volume":"674","author":"Chen","year":"2023","journal-title":"Colloids Surf. A."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"138521","DOI":"10.1016\/j.colsurfa.2025.138521","article-title":"The development of double-barrier anticorrosion coating by embedding CNTs\/MXene@ZnFe-MoO4 LDH in the waterborne epoxy resin","volume":"728","author":"Zhang","year":"2026","journal-title":"Colloids Surf. A."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"108146","DOI":"10.1016\/j.porgcoat.2023.108146","article-title":"Construction of smart halloysite nanocontainers for active long-term anticorrosion of epoxy coatings","volume":"187","author":"Yang","year":"2024","journal-title":"Prog. Org. Coat."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"131638","DOI":"10.1016\/j.surfcoat.2024.131638","article-title":"Corrosion-resistant and superhydrophobic nickel-based composite coating on magnesium alloy","volume":"496","author":"Xie","year":"2025","journal-title":"Surf. Coat. Technol."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"108139","DOI":"10.1016\/j.porgcoat.2023.108139","article-title":"Effects of g-C3N4 on the corrosion protection performance of polyvinyl butyral coatings","volume":"187","author":"Song","year":"2024","journal-title":"Prog. Org. Coat."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"12758","DOI":"10.1016\/j.diamond.2025.112758","article-title":"RGO\/epoxy composite coatings as a dual barrier: Microstructural insights into superior wear and corrosion resistance","volume":"159","author":"Zhang","year":"2025","journal-title":"Diam. Relat. Mater."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"107235","DOI":"10.1016\/j.surfin.2025.107235","article-title":"Enhanced corrosion resistance of epoxy composite coatings with green graphite and h-BN heterostructure reinforcement","volume":"72","author":"Bandyopadhyay","year":"2025","journal-title":"Surf. Interfaces"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"138611","DOI":"10.1016\/j.conbuildmat.2024.138611","article-title":"Synergistic enhancement of g-C3N4\/CoAl-LDH nanoflower and mineral admixtures on the properties of nano-engineered cementitious composites","volume":"450","author":"Lu","year":"2024","journal-title":"Constr. Build. Mater."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"152","DOI":"10.1016\/j.jcis.2020.06.027","article-title":"Enhanced corrosion resistance and adhesion of epoxy coating by two-dimensional graphite-like g-C3N4 nanosheets","volume":"579","author":"Yan","year":"2022","journal-title":"J. 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