{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T14:11:09Z","timestamp":1785507069027,"version":"3.56.0"},"reference-count":32,"publisher":"MDPI AG","issue":"15","license":[{"start":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T00:00:00Z","timestamp":1785456000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Ministerio Colombiano de Ciencia, Tecnolog\u00eda e Innovaci\u00f3n","award":["2021\u20131092"],"award-info":[{"award-number":["2021\u20131092"]}]},{"award":["2021\u20131092"],"award-info":[{"award-number":["2021\u20131092"]}],"id":[{"id":"https:\/\/ror.org\/03fd5ne08","id-type":"ROR","asserted-by":"publisher"}]},{"name":"Vicerrector\u00eda de Investigaci\u00f3n, Universidad de Antioquia","award":["MIN2022-53970"],"award-info":[{"award-number":["MIN2022-53970"]}]},{"award":["MIN2022-53970"],"award-info":[{"award-number":["MIN2022-53970"]}],"id":[{"id":"https:\/\/ror.org\/03bp5hc83","id-type":"ROR","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>High-entropy carbide (HEC) coatings have emerged as promising candidates for extreme tribological and high-temperature applications; therefore, the objective of this work is to systematically investigate the correlation between carbon stoichiometry and the microstructural evolution, mechanical response, and thermal stability of (TiAlTaZrNb)Cx high-entropy carbide coatings. Here, HEC coatings were synthesized via reactive unbalanced-field pulsed-bias magnetron sputtering, with methane flow rates precisely tuned to yield carbon concentrations ranging from 24 to 55 at.%. XRD and Raman analyses reveal a transition from a dense, columnar FCC NaCl-type solid solution with a (200) preferential orientation to a (111)-textured matrix containing secondary carbides (TiC, TaC) and sp2-bonded free carbon at elevated carbon levels. Nanohardness and elastic modulus reach an optimal plateau at ~35 at.% C (29 GPa and 350 GPa, respectively), followed by a decline to ~20 GPa and 223 GPa at 55 at.% C due to the percolation of soft carbon-rich phases. Remarkably, increasing carbon content drastically enhances tribological performance: the coefficient of friction decreases from 0.40 to 0.20, and the specific wear rate drops from 35 \u00d7 10\u22126 to 1.7 \u00d7 10\u22126 mm3\/(N\u00b7m), consistent with a solid-lubrication mechanism inferred from as-deposited Raman trends and wear-track compositional analysis, though direct post-wear spectroscopic validation remains a priority for future work. Thermal stability assessments at 600 \u00b0C at an intermediate low pressure demonstrate excellent microstructural and mechanical retention for low-to-intermediate carbon compositions, with oxidation confined to a ~200 nm surface layer attributed to the formation of stable titanium and tantalum oxides and oxycarbides, which possibly forms an oxygen diffusion barrier at that temperature. An optimal carbon content of ~35 at.% C delivers a superior synergy of high hardness, exceptional wear resistance, and robust thermal stability, establishing (TiAlTaZrNb)Cx as a highly tunable coating system for next-generation protective applications. This work provides the first systematic composition\u2013performance map for this quinary HEC system across a broad stoichiometric range, demonstrating that carbon stoichiometry serves as a master variable to tailor the balance between mechanical integrity and tribological functionality.<\/jats:p>","DOI":"10.3390\/ma19153243","type":"journal-article","created":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T13:23:20Z","timestamp":1785504200000},"page":"3243","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Influence of Carbon Content on the Microstructure, Mechanical Properties, Tribological Behavior, and Thermal Stability of (TiAlTaZrNb)Cx High-Entropy Carbide Coatings"],"prefix":"10.3390","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9800-7259","authenticated-orcid":false,"given":"Gilberto","family":"Bejarano Gait\u00e1n","sequence":"first","affiliation":[{"name":"Centro de Investigaci\u00f3n, Innovaci\u00f3n y Desarrollo de Materiales CIDEMAT, Facultad de Ingenier\u00eda, Universidad de Antioquia, Calle 67 No. 53-108, Medell\u00edn 050010, Colombia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0731-4291","authenticated-orcid":false,"given":"Daniela Mar\u00eda","family":"Chim\u00e1","sequence":"additional","affiliation":[{"name":"Centro de Investigaci\u00f3n, Innovaci\u00f3n y Desarrollo de Materiales CIDEMAT, Facultad de Ingenier\u00eda, Universidad de Antioquia, Calle 67 No. 53-108, Medell\u00edn 050010, Colombia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8013-3775","authenticated-orcid":false,"given":"Juan Manuel","family":"Meza","sequence":"additional","affiliation":[{"name":"Design of Advanced Composites, Departamento de Materiales y Minerales, Facultad de Minas, Universidad Nacional de Colombia Sede Medell\u00edn, Calle 75# 79A-51, Bloque M17, Oficina 407, Medell\u00edn 050034, Colombia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6343-7523","authenticated-orcid":false,"given":"Aleksei","family":"Obrosov","sequence":"additional","affiliation":[{"name":"Department of Physical Metallurgy and Materials Technology, Brandenburg University of Technology Cottbus-Senftenberg, 03046 Cottbus, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9675-3004","authenticated-orcid":false,"given":"Sabine","family":"Wei\u00df","sequence":"additional","affiliation":[{"name":"Department of Physical Metallurgy and Materials Technology, Brandenburg University of Technology Cottbus-Senftenberg, 03046 Cottbus, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2026,7,31]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"448","DOI":"10.1016\/j.actamat.2016.08.081","article-title":"A critical review of high entropy alloys and related concepts","volume":"122","author":"Miracle","year":"2017","journal-title":"Acta Mater."},{"key":"ref_2","first-page":"97","article-title":"Effects of Fabrication Techniques on the Mechanical Properties of High Entropy Alloys: A Review","volume":"7","author":"Salifu","year":"2024","journal-title":"Int. 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