{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T22:18:23Z","timestamp":1793139503007,"version":"4.5.0"},"reference-count":59,"publisher":"MDPI AG","issue":"11","license":[{"start":{"date-parts":[[2024,11,11]],"date-time":"2024-11-11T00:00:00Z","timestamp":1731283200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Membranes"],"abstract":"<jats:p>This study explores the development of chitosan-based membranes blended with three distinct deep eutectic solvents (DESs) for the pervaporation separation of methanol and methyl tert-butyl ether. DESs were selected for their eco-friendly properties and their potential to enhance membrane performance. The chitosan (CS) membranes, both crosslinked and non-crosslinked, were characterized in terms of morphology, chemical composition, wettability, mechanical resistance, and solvent uptake. Pervaporation tests revealed that incorporating DESs significantly enhanced the membranes\u2019 selective permeability toward methanol, with up to a threefold increase in separation efficiency compared to pristine CS membranes. The membranes demonstrated a strong dependence on feed temperature, with higher temperatures improving permeation flux but reducing separation factor. Crosslinking with glutaraldehyde further increased membrane selectivity by reducing free volume into the polymer matrix. These findings underscore the potential of DESs as green additives for improving the performance of biopolymer membranes, making them promising candidates for efficient and eco-friendly organic\u2013organic separations.<\/jats:p>","DOI":"10.3390\/membranes14110237","type":"journal-article","created":{"date-parts":[[2024,11,11]],"date-time":"2024-11-11T08:01:27Z","timestamp":1731312087000},"page":"237","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Enhancing the Separation Performance of Chitosan Membranes Through the Blending with Deep Eutectic Solvents for the Pervaporation of Polar\/Non-Polar Organic Mixtures"],"prefix":"10.3390","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0536-552X","authenticated-orcid":false,"given":"Francesco","family":"Galiano","sequence":"first","affiliation":[{"name":"Institute on Membrane Technology (CNR-ITM), Via P. Bucci 17\/c, 87036 Rende, CS, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3621-605X","authenticated-orcid":false,"given":"Asma","family":"Msahel","sequence":"additional","affiliation":[{"name":"Laboratory of Water Membrane and Environmental Biotechnology (LMBE), CERTE BP 273, Soliman 8020, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5718-4929","authenticated-orcid":false,"given":"Francesca","family":"Russo","sequence":"additional","affiliation":[{"name":"Institute on Membrane Technology (CNR-ITM), Via P. Bucci 17\/c, 87036 Rende, CS, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Natalia","family":"Rovella","sequence":"additional","affiliation":[{"name":"Institute on Membrane Technology (CNR-ITM), Via P. Bucci 17\/c, 87036 Rende, CS, Italy"},{"name":"Department of Biology, Ecology and Earth Sciences (DiBEST), University of Calabria, Via P. Bucci 12\/b, 87036 Rende, CS, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7326-6278","authenticated-orcid":false,"given":"Alfonso","family":"Policicchio","sequence":"additional","affiliation":[{"name":"Department of Physics, Universit\u00e0 della Calabria, Via P. Bucci, Cubo 31C, 87036 Rende, CS, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3639-4497","authenticated-orcid":false,"given":"Sofiane Ben","family":"Hamouda","sequence":"additional","affiliation":[{"name":"Centre for Research on Microelectronics and Nanotechnology (CRMN) of Sousse, Sousse 4054, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amor","family":"Hafiane","sequence":"additional","affiliation":[{"name":"Laboratory of Water Membrane and Environmental Biotechnology (LMBE), CERTE BP 273, Soliman 8020, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7657-3302","authenticated-orcid":false,"given":"Roberto","family":"Castro-Mu\u00f1oz","sequence":"additional","affiliation":[{"name":"Faculty of Civil and Environmental Engineering, Department of Sanitary Engineering, Gdansk University of Technology, 11\/12 Narutowicza St., 80-233 Gdansk, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3347-0506","authenticated-orcid":false,"given":"Alberto","family":"Figoli","sequence":"additional","affiliation":[{"name":"Institute on Membrane Technology (CNR-ITM), Via P. 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