{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,7]],"date-time":"2026-05-07T18:00:50Z","timestamp":1778176850245,"version":"3.51.4"},"reference-count":34,"publisher":"MDPI AG","issue":"3","license":[{"start":{"date-parts":[[2025,3,7]],"date-time":"2025-03-07T00:00:00Z","timestamp":1741305600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Membranes"],"abstract":"<jats:p>To fulfil the goals of the circular economy, the treatment of textile wastewater should be focused on the recovery of valuable components. Monovalent anion-selective electrodialysis (MASED) was applied for the separation of reactive dyes from mineral salts. Standard cation-exchange membranes (CM membranes) and monovalent selective anion-exchange membranes (MVA membranes) were used in the electrodialysis (ED) stack. The separation efficiency was evaluated for model solutions of various reactive dyes (varying in molecular weight and chemical reactivity) containing NaCl. In the course of MASED, the mineral salt was successfully removed from the dye solutions with an efficacy of 97.4\u201399.4%, irrespectively of the composition of the treated solution. The transport of dye molecules through the ion-exchange membranes (IEMs) from diluate to concentrate compartments was irrelevant. Nonetheless, a significant adsorption of dye particles on the membranes was observed. Around 11\u201340% of the initial dye mass was deposited in the ED stack. Dye adsorption intensity was significantly affected by dye reactivity. This study showed the potential of the MASED process for the separation of the reactive dye from the mineral salt on condition that antifouling membrane properties are improved. The obtained streams (the concentrate rich in mineral salt and the diluate containing the reactive dye) can be reused in the dye-house textile operations; however, some loss of dye mass should be included.<\/jats:p>","DOI":"10.3390\/membranes15030085","type":"journal-article","created":{"date-parts":[[2025,3,7]],"date-time":"2025-03-07T07:05:46Z","timestamp":1741331146000},"page":"85","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Suitability of Electrodialysis with Monovalent Selective Anion-Exchange Membranes for Fractionation of Aqueous Mixture Containing Reactive Dye and Mineral Salt"],"prefix":"10.3390","volume":"15","author":[{"given":"Katarzyna","family":"Majewska-Nowak","sequence":"first","affiliation":[{"name":"Faculty of Environmental Engineering, Wroc\u0142aw University of Science and Technology, Wybrze\u017ce Wyspia\u0144skiego 27, 50-370 Wroc\u0142aw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Arif Eftekhar","family":"Ahmed","sequence":"additional","affiliation":[{"name":"Faculty of Environmental Engineering, Wroc\u0142aw University of Science and Technology, Wybrze\u017ce Wyspia\u0144skiego 27, 50-370 Wroc\u0142aw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Martyna","family":"Grzegorzek","sequence":"additional","affiliation":[{"name":"Faculty of Environmental Engineering, Wroc\u0142aw University of Science and Technology, Wybrze\u017ce Wyspia\u0144skiego 27, 50-370 Wroc\u0142aw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Karolina","family":"Baraniec","sequence":"additional","affiliation":[{"name":"NIRAS, Strzegomska 138, 54-429 Wroc\u0142aw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2025,3,7]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1253","DOI":"10.1007\/s10570-023-05649-z","article-title":"Efficient Decolorization of Reactive Dyed Cotton Fabric with a Two-Step NaOH\/Na2S2O4 Process","volume":"31","author":"Wang","year":"2024","journal-title":"Cellulose"},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Majumdar, A., Das, A., Alagirusamy, R., and Kothari, V.K. (2013). Process Control in Dyeing of Textiles. Woodhead Publishing Series in Textiles, Process Control in Textile Manufacturing, Woodhead Publishing.","DOI":"10.1533\/9780857095633"},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Wolela, A.D. (2021). Effect and Role of Salt in Cellulosic Fabric Dyeing. Adv. Res. Text. Eng., 6.","DOI":"10.26420\/advrestexteng.2021.1061"},{"key":"ref_4","doi-asserted-by":"crossref","unstructured":"Singh, V.K., Sett, A., and Karmakar, S. (2024). Waste to Wealth: Facile Activation of Red Mud Waste and Insights into Industrial Reactive Dye Removal from Wastewater. Chem. Eng. J., 481.","DOI":"10.1016\/j.cej.2023.148373"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/j.memsci.2005.06.014","article-title":"Treatment and Reuse of Reactive Dyeing Effluents","volume":"269","author":"Moulin","year":"2006","journal-title":"J. Membr. Sci."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"185","DOI":"10.5004\/dwt.2022.28028","article-title":"A Critical Review on the Treatment of Reactive Dye Wastewater","volume":"257","author":"Fadzli","year":"2022","journal-title":"Desal. Water Treat."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"86","DOI":"10.1080\/19443994.2014.912964","article-title":"Synthetic Reactive Dye Wastewater Treatment by Using Nano-Membrane Filtration","volume":"55","author":"Rashidi","year":"2015","journal-title":"Desal. Water Treat."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"2603","DOI":"10.1007\/s00289-021-03603-2","article-title":"Recent Advances in Dye Removal from Wastewater by Membrane Technology: A Review","volume":"79","author":"Moradihamedani","year":"2022","journal-title":"Polym. Bull."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"2712","DOI":"10.2166\/wpt.2024.142","article-title":"A Review on Progress in Reactive Dye-Containing Wastewater Treatment","volume":"19","author":"Kamati","year":"2024","journal-title":"Water Pract. Technol."},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Zhao, X., Cheng, X., Sun, J., Liu, J., Liu, Z., Wang, Y., and Pan, J. (2023). Zero Liquid Discharge and Resource Treatment of Low-Salinity Mineralized Wastewater Based on Combing Selectrodialysis with Bipolar Membrane Electrodialysis. Separations, 10.","DOI":"10.3390\/separations10040269"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"6025","DOI":"10.1021\/acs.iecr.8b00519","article-title":"Waste Conversion and Resource Recovery from Wastewater by Ion Exchange Membranes: State-of-the-Art and Perspective","volume":"57","author":"Zhao","year":"2018","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_12","doi-asserted-by":"crossref","unstructured":"Sedighi, M., Usefi, M.M.B., Ismail, A.F., and Ghasemi, M. (2023). Environmental Sustainability and Ions Removal Through Electrodialysis Desalination: Operating Conditions and Process Parameters. Desalination, 549.","DOI":"10.1016\/j.desal.2022.116319"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"203","DOI":"10.12989\/mwt.2013.04.3.203","article-title":"Treatment of Organic Dye Solutions by Electrodialysis","volume":"4","year":"2013","journal-title":"Membr. Water Treat."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1016\/j.memsci.2015.06.027","article-title":"Acid Blue 9 Desalting Using Electrodialysis","volume":"493","author":"Xue","year":"2015","journal-title":"J. Membr. Sci."},{"key":"ref_15","first-page":"139","article-title":"Removal of Methylene Blue from Saline Solutions by Adsorption and Electrodialysis","volume":"10","author":"Lafi","year":"2019","journal-title":"Membr. Water Treat."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1016\/j.cep.2018.08.010","article-title":"Treatment of Textile Wastewater by a Hybrid Ultrafiltration\/Electrodialysis Process","volume":"132","author":"Lafi","year":"2018","journal-title":"Chem. Eng. Process."},{"key":"ref_17","doi-asserted-by":"crossref","unstructured":"Ye, W., Liu, R., Chen, X., Chen, Q., Lin, J., Lin, X., Van der Bruggen, B., and Zhao, S. (2020). Loose Nanofiltration-Based Electrodialysis for Highly Efficient Textile Wastewater Treatment. J. Membr. Sci., 608.","DOI":"10.1016\/j.memsci.2020.118182"},{"key":"ref_18","doi-asserted-by":"crossref","unstructured":"Lin, J., Chen, Q., Huang, X., Yan, Z., Lin, X., Ye, W., Arcadio, S., Luis, P., Bi, J., and Van der Bruggen, B. (2021). Integrated Loose Nanofiltration-Electrodialysis Process for Sustainable Resource Extraction from High-Salinity Textile Wastewater. J. Hazard. Mat., 419.","DOI":"10.1016\/j.jhazmat.2021.126505"},{"key":"ref_19","doi-asserted-by":"crossref","unstructured":"R\u00e1p\u00f3, E., and Tonk, S. (2021). Factors Affecting Synthetic Dye Adsorption; Desorption Studies: A Review of Results from the Last Five Years (2017\u20132021). Molecules, 26.","DOI":"10.3390\/molecules26175419"},{"key":"ref_20","first-page":"109","article-title":"Removal of Reactive Dyes from Aqueous Solutions Using Ultrafiltration Membranes","volume":"47","author":"Ahmed","year":"2021","journal-title":"Environ. Prot. Eng."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"532","DOI":"10.5004\/dwt.2023.30169","article-title":"The Separation of Mineral Salt from a Dye-Salt Aqueous Mixture by Electrodialysis","volume":"316","author":"Ahmed","year":"2023","journal-title":"Desal. Water Treat."},{"key":"ref_22","unstructured":"Rautenbach, R., and Albrecht, R. (1989). Membrane Processes, John Wiley&Sons Ltd."},{"key":"ref_23","doi-asserted-by":"crossref","unstructured":"Hyder, A.G., Morales, B.A., Cappelle, M.A., Percival, S.J., Small, L.J., Spoerke, E.D., Rempe, S.B., and Walker, W.S. (2021). Evaluation of Electrodialysis Desalination Performance of Novel Bioinspired and Conventional Ion Exchange Membranes with Sodium Chloride Feed Solutions. Membranes, 11.","DOI":"10.3390\/membranes11030217"},{"key":"ref_24","doi-asserted-by":"crossref","unstructured":"Wei, X., Wang, Y., Yan, H., Wu, K., and Xu, T. (2020). Purification of Methylsulfonylmethane from Mixtures Containing Salt by Conventional Electrodialysis. Membranes, 10.","DOI":"10.3390\/membranes10020023"},{"key":"ref_25","doi-asserted-by":"crossref","unstructured":"Benkhaya, S., M\u2019rabet, S., and Harfi, A.E. (2020). Classifications, Properties, Recent Synthesis and Applications of Azo Dyes. Heliyon, 6.","DOI":"10.1016\/j.heliyon.2020.e03271"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"4847","DOI":"10.1016\/j.watres.2008.09.003","article-title":"Different Binding Mechanisms in Biosorption of Reactive Dyes According to Their Reactivity","volume":"42","author":"Won","year":"2008","journal-title":"Water Res."},{"key":"ref_27","doi-asserted-by":"crossref","unstructured":"Egabaierdi, G., Yu, H.-B., Li, Y., Zhang, X.-Q., Song, H.-O., and Du, M.-X. (2022). Effect of dye aggregation and salting-out on membrane fouling and control measures during nanofiltration of saline dye wastewater. J. Water Proc. Eng., 50.","DOI":"10.1016\/j.jwpe.2022.103285"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"151","DOI":"10.1016\/j.memsci.2018.09.001","article-title":"Effective Dye Purification Using Tight Ceramic Ultrafiltration Membran","volume":"566","author":"Jiang","year":"2018","journal-title":"J. Membr. Sci."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1016\/j.desal.2012.04.010","article-title":"Organic fouling behavior of commercially available hydrocarbon-based anion-exchange membranes by various organic-fouling substances","volume":"296","author":"Tanaka","year":"2012","journal-title":"Desalination"},{"key":"ref_30","doi-asserted-by":"crossref","unstructured":"Cao, R., Duan, F., Ji, W., Ruan, D., Xu, Y., Shi, S., Li, Y., and Cao, H. (2025). Toward improved antifouling properties and monovalent anion selectivity of anion exchange membrane via interfacial polymerization modification. Desalination, 601.","DOI":"10.1016\/j.desal.2025.118562"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"94","DOI":"10.1016\/j.desal.2019.04.027","article-title":"Anion Exchange Membrane Organic Fouling and Mitigation in Salt Valorisation Process from High Salinity Textile Wastewater by Bipolar Membrane Electrodialysis","volume":"465","author":"Berkessa","year":"2019","journal-title":"Desalination"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"60","DOI":"10.1016\/j.desal.2008.01.036","article-title":"Fouling of an Anion Exchange Membrane in the Electrodialysis Desalination Process in the Presence of Organic Foulants","volume":"238","author":"Lee","year":"2009","journal-title":"Desalination"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"218","DOI":"10.1016\/j.jes.2018.07.018","article-title":"Comparative Studies on Fouling of Homogeneous Anion Exchange Membranes by Different Structured Organics in Electrodialysis","volume":"77","author":"Zhao","year":"2019","journal-title":"J. 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