{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,20]],"date-time":"2026-09-20T12:32:55Z","timestamp":1789907575305,"version":"4.0.1"},"reference-count":61,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T00:00:00Z","timestamp":1778025600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22078310"],"award-info":[{"award-number":["22078310"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"award":["22078310"],"award-info":[{"award-number":["22078310"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Membranes"],"abstract":"<jats:p>Organic solvent reverse osmosis (OSRO) is an emerging membrane technology for low-energy separation of organic mixtures, yet developing OSRO membranes with both high permeance and robust stability remains challenging. Herein, we present a surface modification strategy using a D-glucamine\/ethanol solution to tailor the physicochemical properties of a crosslinked polyimide-supported polyamide OSRO membrane. D-glucamine, as an amino sugar alcohol compound contains a primary amino group and multiple hydroxyl groups, endowing it with specific chemical reactivity and potential for interface modification. The optimized OSRO membrane exhibited a significantly decreased water contact angle from 52.6\u00b0 of the control membrane to 36.6\u00b0, indicating substantially enhanced surface hydrophilicity. The optimized membrane (TFC-D-0.2) achieves a high water permeance of 12.84 LMH\/MPa with a NaCl rejection of 98.25% and demonstrates excellent operational stability and pressure resistance (2.5~4.0 MPa). The membrane also shows good tolerance to most organic solvents, maintaining &gt;96.5% NaCl rejection after 30 days of immersion in all tested solvents except acetone. In concentrating ethyl cinnamate\/ethanol mixtures over 50 h, the membrane delivers stable performance with an ethanol permeance of ~2.5 L m\u22122 h\u22121 MPa\u22121 and a solute rejection of &gt;88%. This work provides an effective surface modification strategy for developing high-performance OSRO membranes, holding promise for green separation processes in fine chemical industries.<\/jats:p>","DOI":"10.3390\/membranes16050171","type":"journal-article","created":{"date-parts":[[2026,5,7]],"date-time":"2026-05-07T08:01:39Z","timestamp":1778140899000},"page":"171","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["High-Flux Solvent-Resistant Reverse Osmosis Membrane Enabled by D-glucamine Surface Modification"],"prefix":"10.3390","volume":"16","author":[{"given":"Bing","family":"Wang","sequence":"first","affiliation":[{"name":"Key Laboratory of Marine Chemistry Theory and Technology (Ocean University of China), Ministry of Education\/College of Chemistry & Chemical Engineering, Ocean University of China, 238 Songling Road, Qingdao 266100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weijia","family":"Song","sequence":"additional","affiliation":[{"name":"Key Laboratory of Marine Chemistry Theory and Technology (Ocean University of China), Ministry of Education\/College of Chemistry & Chemical Engineering, Ocean University of China, 238 Songling Road, Qingdao 266100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuqi","family":"Sun","sequence":"additional","affiliation":[{"name":"Key Laboratory of Marine Chemistry Theory and Technology (Ocean University of China), Ministry of Education\/College of Chemistry & Chemical Engineering, Ocean University of China, 238 Songling Road, Qingdao 266100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Enlin","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Marine Chemistry Theory and Technology (Ocean University of China), Ministry of Education\/College of Chemistry & Chemical Engineering, Ocean University of China, 238 Songling Road, Qingdao 266100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Can","family":"Li","sequence":"additional","affiliation":[{"name":"Singapore Membrane Technology Centre, Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, Singapore 637141, Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9617-0500","authenticated-orcid":false,"given":"Baowei","family":"Su","sequence":"additional","affiliation":[{"name":"Key Laboratory of Marine Chemistry Theory and Technology (Ocean University of China), Ministry of Education\/College of Chemistry & Chemical Engineering, Ocean University of China, 238 Songling Road, Qingdao 266100, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2026,5,6]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"435","DOI":"10.1038\/532435a","article-title":"Seven chemical separations to change the world","volume":"532","author":"Sholl","year":"2016","journal-title":"Nature"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"276","DOI":"10.1038\/nmat4860","article-title":"From water to organics in membrane separations","volume":"16","author":"Lively","year":"2017","journal-title":"Nat. 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