{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T23:50:04Z","timestamp":1785196204562,"version":"3.55.0"},"reference-count":33,"publisher":"MDPI AG","issue":"4","license":[{"start":{"date-parts":[[2023,4,17]],"date-time":"2023-04-17T00:00:00Z","timestamp":1681689600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21346006"],"award-info":[{"award-number":["21346006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["LH2022B022"],"award-info":[{"award-number":["LH2022B022"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["S202210222075"],"award-info":[{"award-number":["S202210222075"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003851","name":"Department of scientific research project in Heilongjiang province","doi-asserted-by":"publisher","award":["21346006"],"award-info":[{"award-number":["21346006"]}],"id":[{"id":"10.13039\/501100003851","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003851","name":"Department of scientific research project in Heilongjiang province","doi-asserted-by":"publisher","award":["LH2022B022"],"award-info":[{"award-number":["LH2022B022"]}],"id":[{"id":"10.13039\/501100003851","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003851","name":"Department of scientific research project in Heilongjiang province","doi-asserted-by":"publisher","award":["S202210222075"],"award-info":[{"award-number":["S202210222075"]}],"id":[{"id":"10.13039\/501100003851","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003851","name":"Innovation and Entrepreneurship Project for College students in Heilongjiang Province","doi-asserted-by":"publisher","award":["21346006"],"award-info":[{"award-number":["21346006"]}],"id":[{"id":"10.13039\/501100003851","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003851","name":"Innovation and Entrepreneurship Project for College students in Heilongjiang Province","doi-asserted-by":"publisher","award":["LH2022B022"],"award-info":[{"award-number":["LH2022B022"]}],"id":[{"id":"10.13039\/501100003851","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003851","name":"Innovation and Entrepreneurship Project for College students in Heilongjiang Province","doi-asserted-by":"publisher","award":["S202210222075"],"award-info":[{"award-number":["S202210222075"]}],"id":[{"id":"10.13039\/501100003851","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Yuguang Lv","award":["21346006"],"award-info":[{"award-number":["21346006"]}]},{"name":"Yuguang Lv","award":["LH2022B022"],"award-info":[{"award-number":["LH2022B022"]}]},{"name":"Yuguang Lv","award":["S202210222075"],"award-info":[{"award-number":["S202210222075"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Micromachines"],"abstract":"<jats:p>The naphthalene derivative fluorescent probe F6 was synthesized and a 1 \u00d7 10\u22123 mol\/L solution of Al3+ and other metals to be tested was prepared for the subsequent experiments. The Al3+ fluorescence system of the naphthalene derivative fluorescent probe F6 was successfully constructed as demonstrated by fluorescence emission spectroscopy. The optimal time, temperature and pH of the reaction were investigated. The selectivity and anti-interference ability of the probe F6 for Al3+ were investigated by fluorescence spectroscopy in a methanol solution. The experiments showed that the probe has high selectivity and anti-interference ability for Al3+. The binding ratio of F6 to Al3+ was 2:1, and the binding constant was calculated to be 1.598 \u00d7 105 M\u22121. The possible mechanism of the binding of the two was speculated. Different concentrations of Al3+ were added to Panax Quinquefolium and Paeoniae Radix Alba. The results showed that the recoveries of Al3+ were 99.75\u2013100.56% and 98.67\u201399.67%, respectively. The detection limit was 8.73 \u00d7 10\u22128 mol\/L. The experiments demonstrated that the formed fluorescence system can be successfully adapted for the determination of Al3+ content in two Chinese herbal medicines, which has good practical application.<\/jats:p>","DOI":"10.3390\/mi14040868","type":"journal-article","created":{"date-parts":[[2023,4,18]],"date-time":"2023-04-18T02:30:03Z","timestamp":1681785003000},"page":"868","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Study of a Fluorescent System Based on the Naphthalene Derivative Fluorescent Probe Bound to Al3+"],"prefix":"10.3390","volume":"14","author":[{"given":"Qiuping","family":"Li","sequence":"first","affiliation":[{"name":"College of Pharmacy, Jiamusi University, Jiamusi 154007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Ma","sequence":"additional","affiliation":[{"name":"College of Pharmacy, Jiamusi University, Jiamusi 154007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianyan","family":"Li","sequence":"additional","affiliation":[{"name":"College of Pharmacy, Jiamusi University, Jiamusi 154007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijuan","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Pharmacy, Jiamusi University, Jiamusi 154007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liansheng","family":"Yu","sequence":"additional","affiliation":[{"name":"College of Pharmacy, Jiamusi University, Jiamusi 154007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuehui","family":"Zhao","sequence":"additional","affiliation":[{"name":"Inspection and Testing Center, Jiamusi 154007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuguang","family":"Lv","sequence":"additional","affiliation":[{"name":"College of Pharmacy, Jiamusi University, Jiamusi 154007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,4,17]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"10414","DOI":"10.1039\/C9RA00447E","article-title":"A highly sensitive and selective fluorescent probe for quantitative detection of Al3+ in food, water, and living cells","volume":"9","author":"Jiang","year":"2019","journal-title":"RSC Adv."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"361","DOI":"10.1007\/s13738-022-02672-y","article-title":"A multifunctional \u201coff\u2013on\u201d fluorescence probe for Al3+, Zn2+ and La3+ detection and cellular imaging applications","volume":"20","author":"Luo","year":"2023","journal-title":"J. Iran. Chem. Soc."},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Xing, Z., Wang, J., Huang, J., Chen, X., Zong, Z., Fan, C., and Huang, G. (2022). A Significant Fluorescence Turn-On Probe for the Recognition of Al3+ and Its Application. Molecules, 27.","DOI":"10.3390\/molecules27082569"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"112492","DOI":"10.1016\/j.jphotochem.2020.112492","article-title":"Quinoline-ampyrone functionalized azo dyes as colorimetric and fluorescent enhancement probes for selective aluminium and cobalt ion detection in semi-aqueous media","volume":"394","author":"Bartwal","year":"2020","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"566","DOI":"10.1016\/j.saa.2017.10.029","article-title":"Novel rhodamine Schiff base type naked-eye fluorescent probe for sensing Fe3+ and the application in cell","volume":"191","author":"Chen","year":"2018","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"168","DOI":"10.1038\/nchembio.69","article-title":"Synthetic fluorescent sensors for studying the cell biology of metals","volume":"4","author":"Domaille","year":"2008","journal-title":"Nat. Chem. Biol."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"109210","DOI":"10.1016\/j.optmat.2019.109210","article-title":"Two pyridine-derived Schiff-bases as turn-on fluorescent sensor for detection of aluminium ion","volume":"95","author":"Peng","year":"2019","journal-title":"Opt. Mater."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"119288","DOI":"10.1016\/j.saa.2020.119288","article-title":"2-Aminophenols based Schiff bases as fluorescent probes for selective detection of cyanide and aluminium ions\u2013Effect of substituents","volume":"249","author":"Poongodi","year":"2021","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"7343","DOI":"10.1039\/C4AY01330A","article-title":"Design and synthesis of a chemosensor for the detection of Al3+ based on ESIPT","volume":"6","author":"Qin","year":"2014","journal-title":"Anal. Methods"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1016\/S0010-8545(96)90020-X","article-title":"Aluminum and Alzheimer\u2019s disease: Model studies","volume":"149","author":"Fasman","year":"1996","journal-title":"Coord. Chem. Rev."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"129125","DOI":"10.1016\/j.molstruc.2020.129125","article-title":"Synthesis of calix [4] arenes bearing thiosemicarbazone moieties with naphthalene groups: Highly selective turn off\/on fluorescent sensor for Cu (II) recognition","volume":"1225","author":"Moris","year":"2021","journal-title":"J. Mol. Struct."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"100062","DOI":"10.1016\/j.jics.2021.100062","article-title":"Selective sensing of Cu2+ ion by naphthalene based Schiff base","volume":"98","author":"Ghosh","year":"2021","journal-title":"J. Indian Chem. Soc."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"131775","DOI":"10.1016\/j.molstruc.2021.131775","article-title":"A new tetramine bis (2-naphthol)-derivative fluorescent chemosensor for aluminum ion (Al3+)","volume":"1250","author":"Golbedaghi","year":"2022","journal-title":"J. Mol. Struct."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"2449","DOI":"10.1021\/ol026004l","article-title":"Fluorescent sensing of pyrophosphate and bis-carboxylates with charge neutral PET chemosensors","volume":"4","author":"Gunnlaugsson","year":"2002","journal-title":"Org. Lett."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"1692","DOI":"10.1002\/slct.202004264","article-title":"Naphthalimide assemblies for simultaneous detection of ferrous ion and H2O2 to prevent fenton reaction","volume":"6","author":"Kaur","year":"2021","journal-title":"ChemistrySelect"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"132926","DOI":"10.1016\/j.molstruc.2022.132926","article-title":"A nonsymmetric salamo-based turn-off fluorescent probe for the detection of Cu2+ and its structurally rare dinuclear Cu (II) complex","volume":"1261","author":"Li","year":"2022","journal-title":"J. Mol. Struct."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"2937","DOI":"10.1007\/s10570-014-0260-0","article-title":"Coloring properties of novel 1, 4-distyrylbenzene and 4, 4\u2032-distyrylbiphenyl fluorescent brighteners and their arrangement in cotton and polyester fiber","volume":"21","author":"Zhao","year":"2014","journal-title":"Cellulose"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1016\/j.molcata.2015.01.031","article-title":"Mechanism and kinetics of Horner\u2013Wadsworth\u2013Emmons reaction in liquid\u2013liquid phase-transfer catalytic system","volume":"400","author":"Zhao","year":"2015","journal-title":"J. Mol. Catal. A Chem."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"112299","DOI":"10.1016\/j.jphotochem.2019.112299","article-title":"A bifunctional probe based on naphthalene derivative for absorbance-ratiometic detection of Ag+ and fluorescence \u201cturn-on\u201d sensing of Zn2+ and its practical application in water samples, walnut and living cells","volume":"390","author":"Li","year":"2020","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"109214","DOI":"10.1016\/j.dyepig.2021.109214","article-title":"Recent advances of cyclotriphosphazene derivatives as fluorescent dyes","volume":"188","author":"Liu","year":"2021","journal-title":"Dyes Pigment."},{"key":"ref_21","doi-asserted-by":"crossref","unstructured":"Bhardwaj, V., Bhardwaj, K., and Sahoo, S.K. (2023). \u2018AIE+ ESIPT\u2019Active 2-hydroxy-naphthalene Hydrazone for the Fluorescence Turn-on Sensing of Al3+. J. Fluoresc., 1\u20138.","DOI":"10.1007\/s10895-022-03138-3"},{"key":"ref_22","doi-asserted-by":"crossref","unstructured":"Yarullin, D.N., Zavalishin, M.N., Gamov, G.A., Lukanov, M.M., Ksenofontov, A.A., Bumagina, N.A., and Antina, E.V. (2023). Prediction of Sensor Ability Based on Chemical Formula: Possible Approaches and Pitfalls. Inorganics, 11.","DOI":"10.3390\/inorganics11040158"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"114408","DOI":"10.1016\/j.jphotochem.2022.114408","article-title":"2-Hydroxy-naphthalene hydrazone based dual-functional chemosensor for ultrasensitive colorimetric detection of Cu2+ and highly selective fluorescence sensing and bioimaging of Al3+","volume":"437","author":"Sharma","year":"2023","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"681","DOI":"10.1039\/c9pp00472f","article-title":"An antipyrine based fluorescent probe for distinct detection of Al3+ and Zn2+ and its AIEE behaviour","volume":"19","author":"Maity","year":"2020","journal-title":"Photochem. Photobiol. Sci."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"21399","DOI":"10.1039\/D0RA02101F","article-title":"A pH tuning single fluorescent probe based on naphthalene for dual-analytes (Mg2+ and Al3+) and its application in cell imaging","volume":"10","author":"Yu","year":"2020","journal-title":"RSC Adv."},{"key":"ref_26","doi-asserted-by":"crossref","unstructured":"Zhang, X., Shen, L.Y., Zhang, Q.L., Yang, X.J., Huang, Y.L., Redshaw, C., and Xu, H. (2021). A simple turn-off Schiff base fluorescent sensor for copper (II) ion and its application in water analysis. Molecules, 26.","DOI":"10.3390\/molecules26051233"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"109227","DOI":"10.1016\/j.inoche.2022.109227","article-title":"Barium-based coordination polymer: A bi-functional fluorescent sensor for Fe3+ and nitroaromatic molecular detection","volume":"137","author":"Li","year":"2022","journal-title":"Inorg. Chem. Commun."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"012001","DOI":"10.1088\/1742-6596\/1504\/1\/012001","article-title":"Development of aminoethylpyridine based N, N, N, O-donor fluorescent probes for the detection of Fe3+ and Hg2+ in aqueous media","volume":"1504","author":"Singh","year":"2020","journal-title":"J. Phys. Conf. Ser."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"117579","DOI":"10.1016\/j.saa.2019.117579","article-title":"A highly selective fluorescent probe for hydrogen polysulfides in living cells based on a naphthalene derivative","volume":"227","author":"Wang","year":"2020","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"108190","DOI":"10.1016\/j.dyepig.2020.108190","article-title":"A fluorescent probe for Gallium (\u2162) ions based on 2-hydroxy-1-naphthaldehyde and L-serine","volume":"175","author":"Yan","year":"2020","journal-title":"Dyes Pigment."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"120021","DOI":"10.1016\/j.ica.2020.120021","article-title":"Salicylimine-based fluorescent chemosensor for magnesium ions in aqueous solution","volume":"514","author":"Azadbakht","year":"2021","journal-title":"Inorg. Chim. Acta"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"146","DOI":"10.1016\/j.saa.2019.01.003","article-title":"AIE active salicylaldehyde-based hydrazone: A novel single-molecule multianalyte (Al3+ or Cu2+) sensor in different solvents","volume":"212","author":"Xu","year":"2019","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"5486","DOI":"10.1039\/c3an00351e","article-title":"A new ditopic ratiometric receptor for detecting zinc and fluoride ions in living cells","volume":"138","author":"Li","year":"2013","journal-title":"Analyst"}],"container-title":["Micromachines"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2072-666X\/14\/4\/868\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T19:17:43Z","timestamp":1760123863000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2072-666X\/14\/4\/868"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,4,17]]},"references-count":33,"journal-issue":{"issue":"4","published-online":{"date-parts":[[2023,4]]}},"alternative-id":["mi14040868"],"URL":"https:\/\/doi.org\/10.3390\/mi14040868","relation":{},"ISSN":["2072-666X"],"issn-type":[{"value":"2072-666X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,4,17]]}}}