{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T04:56:09Z","timestamp":1787028969201,"version":"build-2736575974"},"reference-count":59,"publisher":"MDPI AG","issue":"1","license":[{"start":{"date-parts":[[2024,1,22]],"date-time":"2024-01-22T00:00:00Z","timestamp":1705881600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"National Natural Science Foundation of China","award":["21462018"],"award-info":[{"award-number":["21462018"]}]},{"name":"National Natural Science Foundation of China","award":["21861025"],"award-info":[{"award-number":["21861025"]}]},{"name":"National Natural Science Foundation of China","award":["20192BAB203003"],"award-info":[{"award-number":["20192BAB203003"]}]},{"name":"National Natural Science Foundation of China","award":["202211318012"],"award-info":[{"award-number":["202211318012"]}]},{"name":"Science Fund of the Technology Office of Jiangxi, China","award":["21462018"],"award-info":[{"award-number":["21462018"]}]},{"name":"Science Fund of the Technology Office of Jiangxi, China","award":["21861025"],"award-info":[{"award-number":["21861025"]}]},{"name":"Science Fund of the Technology Office of Jiangxi, China","award":["20192BAB203003"],"award-info":[{"award-number":["20192BAB203003"]}]},{"name":"Science Fund of the Technology Office of Jiangxi, China","award":["202211318012"],"award-info":[{"award-number":["202211318012"]}]},{"name":"National Training Programs of Innovation and Entrepreneurship for Undergraduates","award":["21462018"],"award-info":[{"award-number":["21462018"]}]},{"name":"National Training Programs of Innovation and Entrepreneurship for Undergraduates","award":["21861025"],"award-info":[{"award-number":["21861025"]}]},{"name":"National Training Programs of Innovation and Entrepreneurship for Undergraduates","award":["20192BAB203003"],"award-info":[{"award-number":["20192BAB203003"]}]},{"name":"National Training Programs of Innovation and Entrepreneurship for Undergraduates","award":["202211318012"],"award-info":[{"award-number":["202211318012"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Micromachines"],"abstract":"<jats:p>A novel fluorescent \u201coff\u201d probe R-\u03b2-D-1 containing a 1,2,3-triazole moiety was obtained by the Click reaction with azidoglucose using H8-BINOL as a substrate, and the structure was characterized by 1H NMR and 13C NMR and ESI-MS analysis. The fluorescence properties of R-\u03b2-D-1 in methanol were investigated, and it was found that R-\u03b2-D-1 could be selectively fluorescently quenched by Bi3+ in the recognition of 19 metal ions and basic cations. The recognition process of Bi3+ by R-\u03b2-D-1 was also investigated by fluorescence spectroscopy, SEM, AFM, etc. The complex pattern of R-\u03b2-D-1 with Bi3+ was determined by Job\u2019s curve as 1 + 1, and the binding constant Ka of R-\u03b2-D-1 and Bi3+ was valued by the Benesi\u2013Hildebrand equation as 1.01 \u00d7 104 M\u22121, indicating that the binding force of R-\u03b2-D-1 and Bi3+ was medium. The lowest detection limit (LOD) of the self-assembled H8-BINOL derivative for Bi3+ was up to 0.065 \u00b5M. The mechanism for the recognition of Bi3+ by the sensor R-\u03b2-D-1 may be the intramolecular charge transfer effect (ICT), which was attributed to the fact that the N-3 of the triazole readily serves as an electron acceptor while the incorporation of Bi3+ serves as an electron donor, and the two readily undergo coordination leading to the quenching of fluorescence. The recognition mechanism and recognition site could be verified by DFT calculation and CDD (Charge Density Difference).<\/jats:p>","DOI":"10.3390\/mi15010163","type":"journal-article","created":{"date-parts":[[2024,1,22]],"date-time":"2024-01-22T03:50:22Z","timestamp":1705895422000},"page":"163","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Self-Assembled Nanotubes Based on Chiral H8-BINOL Modified with 1,2,3-Triazole to Recognize Bi3+ Efficiently by ICT Mechanism"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-7665-5753","authenticated-orcid":false,"given":"Jisheng","family":"Tao","sequence":"first","affiliation":[{"name":"Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fang","family":"Guo","sequence":"additional","affiliation":[{"name":"Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Sun","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials iChEM, Department of Chemistry, Fudan University, Shanghai 200433, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3192-5818","authenticated-orcid":false,"given":"Xiaoxia","family":"Sun","sequence":"additional","affiliation":[{"name":"Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Hu","sequence":"additional","affiliation":[{"name":"College of Chemistry, Nanchang University, Nanchang 330031, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,1,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"9899","DOI":"10.1039\/C4CC04214J","article-title":"A Novel Fluorescence Probe for Estimation of Cysteine\/Histidine in Human Blood Plasma and Recognition of Endogenous Cysteine in Live Hct116 Cells","volume":"50","author":"Agarwalla","year":"2014","journal-title":"Chem. 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