{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T17:25:21Z","timestamp":1760549121933,"version":"build-2065373602"},"reference-count":32,"publisher":"MDPI AG","issue":"8","license":[{"start":{"date-parts":[[2011,7,26]],"date-time":"2011-07-26T00:00:00Z","timestamp":1311638400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The reaction of 3-aminopropylamide of cholic acid with CS2 produced a bile acid derivative of dithiocarbamic acid which further formed an ammonium salt with another molecule of 3-aminopropylamide of cholic acid. The cationic 3-ammonium propylamide of cholic acid did not react further with CS2 and the formed salt was stable in the reaction mixture, even when excess CS2 was used. When the reaction was carried out in the presence of aqueous sodium hydroxide, only the bile acid derivative of sodium dithiocarbamate was formed. The dithiocarbamate derivatives were characterized by 1H- and 13C-NMR spectroscopy and ESI-TOF mass spectrometry.<\/jats:p>","DOI":"10.3390\/molecules16086306","type":"journal-article","created":{"date-parts":[[2011,7,26]],"date-time":"2011-07-26T11:29:34Z","timestamp":1311679774000},"page":"6306-6312","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Synthesis of Both Ionic Species of Ammonium Dithiocarbamate Derived Cholic Acid Moieties"],"prefix":"10.3390","volume":"16","author":[{"given":"Juha","family":"Koivukorpi","sequence":"first","affiliation":[{"name":"Department of Chemistry, FI-40014 University of Jyv\u00e4skyl\u00e4, Finland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Erkki","family":"Kolehmainen","sequence":"additional","affiliation":[{"name":"Department of Chemistry, FI-40014 University of Jyv\u00e4skyl\u00e4, Finland"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2011,7,26]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"430","DOI":"10.1021\/ac50161a007","article-title":"Reaction of carbon disulfide with primary and secondary aliphatic amines as analytical tool","volume":"28","author":"Critchfield","year":"1956","journal-title":"Anal. 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