{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T04:57:03Z","timestamp":1787029023953,"version":"build-2736575974"},"reference-count":65,"publisher":"MDPI AG","issue":"2","license":[{"start":{"date-parts":[[2015,1,30]],"date-time":"2015-01-30T00:00:00Z","timestamp":1422576000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Combinations of TiO2 photocatalysts and various adsorbents have been widely studied for the adsorption and photocatalytic decomposition of gaseous pollutants such as volatile organic compounds (VOCs). Herein, a TiO2-zeolite-porous glass composite was prepared using melt-quenching and partial sintering, hydrothermal treatment, and drop coating for preparation of the porous glass support and X-zeolite and their combination with TiO2, respectively. The obtained composite comprised anatase phase TiO2, X-zeolite, and the porous glass support, which were combined at the micro to nanometer scales. The composite had a relatively high specific surface area of approximately 25 m2\/g and exhibited a good adsorption capacity for 2-propanol. These data indicated that utilization of this particular phase-separated glass as the support was appropriate for the formation of the bulk photocatalyst-adsorbent composite. Importantly, the photocatalytic decomposition of adsorbed 2-propanol proceeded under UV light irradiation. The 2-propanol was oxidized to acetone and then trapped by the X-zeolite rather than being released to the atmosphere. Consequently, it was demonstrated that the micrometer-scaled combination of TiO2 and zeolite in the bulk form is very useful for achieving both the removal of gaseous organic pollutants and decreasing the emission of harmful intermediates.<\/jats:p>","DOI":"10.3390\/molecules20022349","type":"journal-article","created":{"date-parts":[[2015,1,30]],"date-time":"2015-01-30T10:08:29Z","timestamp":1422612509000},"page":"2349-2363","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Preparation of a Titania\/X-Zeolite\/Porous Glass Composite Photocatalyst Using Hydrothermal and Drop Coating Processes"],"prefix":"10.3390","volume":"20","author":[{"given":"Atsuo","family":"Yasumori","sequence":"first","affiliation":[{"name":"Department of Materials Science and Technology, Tokyo University of Science, 6-3-1 Niijuku, Katsushika-ku, Tokyo 125-8585, Japan"},{"name":"Photocatalysis International Research Center, Research Institute for Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda-shi, Chiba 278-8510, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sayaka","family":"Yanagida","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Technology, Tokyo University of Science, 6-3-1 Niijuku, Katsushika-ku, Tokyo 125-8585, Japan"},{"name":"Photocatalysis International Research Center, Research Institute for Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda-shi, Chiba 278-8510, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Sawada","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Technology, Tokyo University of Science, 6-3-1 Niijuku, Katsushika-ku, Tokyo 125-8585, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2015,1,30]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"554","DOI":"10.1016\/0021-9517(92)90085-V","article-title":"Heterogeneous photocatalytic oxidation of gas-phase organics for air purification Acetone, 1-butanol, butyraldehyde, formaldehyde, and m-xylene oxidation","volume":"136","author":"Peral","year":"1992","journal-title":"J. Catal."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"341","DOI":"10.1021\/cr00017a016","article-title":"Heterogeneous photocatalysis","volume":"93","author":"Fox","year":"1993","journal-title":"Chem. Rev."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1021\/cr00033a004","article-title":"Environmental Applications of Semiconductor Photocatalysis","volume":"95","author":"Hoffmann","year":"1995","journal-title":"Chem. Rev."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S1389-5567(00)00002-2","article-title":"Titanium dioxide photocatalysis","volume":"1","author":"Fujishima","year":"2000","journal-title":"J. Photchem. Photobiol. C Photochem. Rev."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"645","DOI":"10.1016\/S0360-1323(02)00212-3","article-title":"Photocatalytic oxidation for indoor air purification: A literature review","volume":"38","author":"Zhao","year":"2003","journal-title":"Build. Environ."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"8269","DOI":"10.1143\/JJAP.44.8269","article-title":"TiO2 Photocatalysis: A Historical Overview and Future Prospects","volume":"44","author":"Hashimoto","year":"2005","journal-title":"Jpn. J. Appl. Phys."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"2229","DOI":"10.1016\/j.atmosenv.2009.01.034","article-title":"Photocatalytic purification of volatile organic compounds in indoor air: A literature review","volume":"43","author":"Mo","year":"2009","journal-title":"Atmos. Environ."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"5919","DOI":"10.1021\/cr3002092","article-title":"Titanium Dioxide Photocatalysis in Atmospheric Chemistry","volume":"112","author":"Chen","year":"2012","journal-title":"Chem. Rev."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1177\/1420326X12470282","article-title":"Photocatalytic Oxidation for Maintenance of Indoor Environmental Quality","volume":"22","author":"Yu","year":"2013","journal-title":"Indoor Built Environ."},{"key":"ref_10","unstructured":"(2000). Air Quality Guidelines for Europe, WHO Regional Office for Europe, WHO Regional Publications, European Series. [2nd ed.]."},{"key":"ref_11","doi-asserted-by":"crossref","unstructured":"Pichat, P. (2013). Photocatalysis and Water Purification, Wiley-VCH.","DOI":"10.1002\/9783527645404"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"245","DOI":"10.2109\/jcersj.101.245","article-title":"Photocatalytic Property of TiO2 Anchored on Porous Alumina Ceramic Support by the Alkoxide Method","volume":"101","author":"Kato","year":"1993","journal-title":"J. Ceram. Soc. Jpn."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1006\/jcat.1994.1274","article-title":"Acetone Oxidation in a Photocatalytic Monolith Reactor","volume":"149","author":"Sauer","year":"1994","journal-title":"J. Catal."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"1223","DOI":"10.1021\/es00005a013","article-title":"TiO2 Photocatalysis for Indoor Air Applications Effects of Humidity and Trace Contaminant Levels on the Oxidation Rates of Formaldehyde, Toluene, and 1,3-Butadiene","volume":"29","author":"Obee","year":"1995","journal-title":"Environ. Sci. Technol."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"2521","DOI":"10.1039\/a803265c","article-title":"Preparation of a TiO2 based multiple layer thin film photocatalyst","volume":"8","author":"Yasumori","year":"1998","journal-title":"J. Mater. Chem."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"1253","DOI":"10.1039\/b100216n","article-title":"Photocatalytic and photoelectrochemical propertiesof TiO2-based multiple layer thin film prepared by sol\u2013gel and reactive-sputtering methods","volume":"11","author":"Yasumori","year":"2001","journal-title":"J. Mater. Chem."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"5017","DOI":"10.1021\/j100269a025","article-title":"Photoluminescence and photocatalytic activity of highly dispersed titanium oxide anchored onto porous Vycor glass","volume":"89","author":"Anpo","year":"1985","journal-title":"J. Phys. Chem."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"10707","DOI":"10.1021\/jp982835q","article-title":"Preparation of Titanium Oxide Photocatalysts Anchored on Porous Silica Glass by a Metal Ion-Implantation Method","volume":"102","author":"Yamashita","year":"1998","journal-title":"J. Phys. Chem. B"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1016\/S1010-6030(03)00009-1","article-title":"Photocatalyst TiO2 supported on glass fiber for indoor air purification effect of NO on the photodegradation of CO and NO2","volume":"156","author":"Ao","year":"2003","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"3486","DOI":"10.1021\/la047308e","article-title":"Photocatalytic TiO2\/Glass Nanoflake Array Films","volume":"21","author":"Ho","year":"2005","journal-title":"Langmuir"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"461","DOI":"10.1111\/j.1551-2916.2009.03472.x","article-title":"Structures and Photocatalytic Properties of Crystalline Titanium Oxide-Dispersed Nanoporous Glass-Ceramics","volume":"93","author":"Machida","year":"2010","journal-title":"J. Am. Ceram. Soc."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"9986","DOI":"10.1021\/j100024a047","article-title":"Effect of Inert Supports for Titanium Dioxide Loading on Enhancement of Photodecomposition Rate of Gaseous Propionaldehyde","volume":"99","author":"Takeda","year":"1995","journal-title":"J. Phys. Chem."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"153","DOI":"10.1016\/S1010-6030(96)04503-0","article-title":"Effect of Activated Carbon Content in TiO2-loaded Activated Carbon on Photodegradation Behaviors of Dichloromethane","volume":"103","author":"Torimoto","year":"1997","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1007\/s100860300013","article-title":"Photocatalytic activity of TiO2 crystallite-activated carbon composites prepared in supercritical isopropanol for the decomposition of formaldehyde","volume":"49","author":"Huang","year":"2003","journal-title":"J. Wood Sci."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1016\/S1010-6030(03)00276-4","article-title":"Combination effect of activated carbon with TiO2 for the photodegradation of binary pollutants at typical indoor air level","volume":"161","author":"Ao","year":"2004","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1016\/j.ces.2004.01.073","article-title":"Indoor air purification by photocatalyst TiO2 immobilized on an activated carbon filter installed in an air cleaner","volume":"60","author":"Ao","year":"2005","journal-title":"Chem. Eng. Sci."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"520","DOI":"10.1021\/jz900265j","article-title":"Graphene-Based Nanoarchitectures. Anchoring Semiconductor and Metal Nanoparticles on a Two-Dimensional Carbon Support","volume":"1","author":"Kamat","year":"2010","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1021\/nn901221k","article-title":"P25-Graphene Composite as a High Performance Photocatalyst","volume":"4","author":"Zhang","year":"2010","journal-title":"ACS Nano"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"7303","DOI":"10.1021\/nn1024219","article-title":"TiO2\u2212Graphene Nanocomposites for Gas-Phase Photocatalytic Degradation of Volatile Aromatic Pollutant: Is TiO2\u2212Graphene Truly Different from Other TiO2\u2212Carbon Composite Materials","volume":"4","author":"Zhang","year":"2010","journal-title":"ACS Nano"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"15049","DOI":"10.1021\/jp105526d","article-title":"Graphene Coating of TiO2 Nanoparticles Loaded on Mesoporous Silica for Enhancement of Photocatalytic Activity","volume":"114","author":"Kamegawa","year":"2011","journal-title":"J. Phys. Chem. C"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"359","DOI":"10.1246\/bcsj.61.359","article-title":"The Photocatalytic Activity of a Platinized Titanium Dioxide Catalyst Supported over Silica","volume":"61","author":"Domen","year":"1988","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"702","DOI":"10.2109\/jcersj.102.702","article-title":"Preparation of TiO2 Fine Particles Supported on Silica Gel as Photocatalyst","volume":"102","author":"Yasumori","year":"1994","journal-title":"J. Ceram. Soc. Jpn."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"9882","DOI":"10.1021\/j100024a033","article-title":"An Improved Photocatalyst of TiO2\/SiO2 Prepared by a Sol-Gel Synthesis","volume":"99","author":"Anderson","year":"1995","journal-title":"J. Phys. Chem."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"6216","DOI":"10.1021\/la000119l","article-title":"Novel Silica Gel Supported TiO2 Photocatalyst Synthesized by CVD Method","volume":"16","author":"Ding","year":"2000","journal-title":"Langmuir"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"445","DOI":"10.1016\/j.jphotochem.2004.01.017","article-title":"Sol\u2013gel synthesis of titania\u2013silica photocatalyst for cyanide photodegradation","volume":"163","author":"Ismail","year":"2004","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"1523","DOI":"10.1021\/cm049955x","article-title":"Pore-Wall Chemistry and Photocatalytic Activity of Mesoporous Titania Molecular Sieve Films","volume":"16","author":"Yu","year":"2004","journal-title":"Chem. Mater."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"4538","DOI":"10.1021\/ja069113u","article-title":"Mesoporous Au-TiO2 Nanocomposites with Enhanced Photocatalytic Activity","volume":"129","author":"Li","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"498","DOI":"10.1021\/am900726k","article-title":"Transparent, Well-Aligned TiO2 Nanotube Arrays with Controllable Dimensions on Glass Substrates for Photocatalytic Applications","volume":"2","author":"Tan","year":"2010","journal-title":"Appl. Mater. Interfaces"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"6586","DOI":"10.1021\/jp0349684","article-title":"Highly Porous (TiO2-SiO2-TeO2)\/Al2O3\/TiO2 Composite Nanostructures on Glass with Enhanced Photocatalysis Fabricated by Anodization and Sol-Gel Process","volume":"107","author":"Chu","year":"2003","journal-title":"J. Phys. Chem. B"},{"key":"ref_40","first-page":"19544","article-title":"Calcium Phosphate Coatings Incorporated in Mesoporous TiO2\/SBA-15 by a Facile Inner-pore Sol-gel Process toward Enhanced Adsorption-photocatalysis Performances","volume":"117","author":"Qian","year":"2013","journal-title":"J. Phys. Chem. C"},{"key":"ref_41","doi-asserted-by":"crossref","unstructured":"Auerbach, S.M., Carrado, K.A., and Dutta, P.K. (2003). Handbook of Zeolite Science and Technology, CRC Press.","DOI":"10.1201\/9780203911167"},{"key":"ref_42","doi-asserted-by":"crossref","unstructured":"Corma, A., and Garcia, H. (2004). Zeolite-based photocatalysts. Chem. Commun., 1443\u20131459.","DOI":"10.1039\/b400147h"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"2407","DOI":"10.1039\/C0JM02741C","article-title":"Efficient photocatalytic degradation of organics diluted in water and air using TiO2 designed with zeolites and mesoporous silica materials","volume":"21","author":"Kuwahara","year":"2011","journal-title":"J. Mater. Chem."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"189","DOI":"10.1006\/jcat.1994.1284","article-title":"Photocatalytic Degradation of Gaseous Pyridine over Zeolite-Supported Titanium Dioxide","volume":"149","author":"Sampath","year":"1994","journal-title":"J. Catal."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"1275","DOI":"10.1021\/es950483k","article-title":"Effects of Adsorbents Used as Supports for Titanium Dioxide Loading on Photocatalytic Degradation of Propyzamide","volume":"30","author":"Torimoto","year":"1996","journal-title":"Environ. Sci. Technol."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"3115","DOI":"10.1021\/jp962494l","article-title":"Photoactivity of Titanium Dioxide Supported on MCM41, Zeolite X, and Zeolite Y","volume":"101","author":"Xu","year":"1997","journal-title":"J. Phys. Chem. B"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"2937","DOI":"10.1023\/A:1016060729376","article-title":"Preparation of composite TiO2-zeolite sheets using a papermaking technique and their application to environmental improvement Part I Removal of acetaldehyde with and without UV irradiation","volume":"37","author":"Ichiura","year":"2002","journal-title":"J. Mater. Sci."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1016\/j.jcat.2006.12.010","article-title":"Photocatalytic oxidation of acetaldehyde with oxygen on TiO2\/ZSM-5 photocatalyst: Effect of hydrophobicity of zeolites","volume":"246","author":"Takeuchi","year":"2007","journal-title":"J. Catal."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"25004","DOI":"10.1039\/C4CP03897E","article-title":"Photocatalytic performance of TiO2\u2013zeolite templated carbon composites in organic contaminant degradation","volume":"16","author":"Donphai","year":"2014","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"16477","DOI":"10.3390\/molecules191016477","article-title":"Design of Composite Photocatalyst of TiO2 and Y-Zeolite for Degradation of 2-Propanol in the Gas Phase under UV and Visible Light Irradiation","volume":"19","author":"Kamegawa","year":"2014","journal-title":"Molecules"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"1611","DOI":"10.1023\/A:1023246803552","article-title":"Preparation of composite TiO2-zeolite sheets using a papermaking technique and their application to environmental improvement, Part II Effect of zeolite coexisting in the composite sheet on NOx removal","volume":"38","author":"Ichiura","year":"2003","journal-title":"J. Mater. Sci."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"1186","DOI":"10.3155\/1047-3289.59.10.1186","article-title":"Titanium Dioxide\/Zeolite Catalytic Adsorbent for the Removal of NO and Acetone Vapors","volume":"59","author":"Jan","year":"2009","journal-title":"J. Air Waste Manag. Assoc."},{"key":"ref_53","doi-asserted-by":"crossref","unstructured":"Auerbach, S.M., Carrado, K.A., and Dutta, P.K. (2003). Handbook of Zeolite Science and Technology, CRC Press.","DOI":"10.1201\/9780203911167"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"8057","DOI":"10.1021\/jp972002k","article-title":"Kinetics of Photocatalytic Reactions under Extremely Low-Intensity UV Illumination on Titanium Dioxide Thin Films","volume":"101","author":"Ohko","year":"1997","journal-title":"J. Phys. Chem. A"},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"350","DOI":"10.1016\/j.micromeso.2008.07.009","article-title":"Photocatalytic decomposition of 2-propanol in air by mechanical mixtures of TiO2 crystalline particles and silicalite adsorbent: The complete conversion of organic molecules strongly adsorbed within zeolitic channels","volume":"117","author":"Yamaguchi","year":"2009","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_56","doi-asserted-by":"crossref","unstructured":"Pichat, P. (2013). Photocatalysis and Water Purification, Wiley-VCH.","DOI":"10.1002\/9783527645404"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"3433","DOI":"10.1007\/BF00352046","article-title":"Novel alkali-resistance porous glass prepared from a mother glass based on the SiO2-B2O3-RO-ZrO2 (R=Mg, Ca, Sr, Ba and Zn) system","volume":"29","author":"Yazawa","year":"1994","journal-title":"J. Mater. Sci."},{"key":"ref_58","doi-asserted-by":"crossref","unstructured":"Auerbach, S.M., Carrado, K.A., and Dutta, P.K. (2003). Handbook of Zeolite Science and Technology, CRC Press.","DOI":"10.1201\/9780203911167"},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"603","DOI":"10.1351\/pac198557040603","article-title":"Reporting Physisorption Data for Gas\/Solid Systems with Special Reference to the Determination of Surface Area and Porosity","volume":"57","author":"Sing","year":"1986","journal-title":"Pure Appl. Chem."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"7279","DOI":"10.1039\/c3ra46987e","article-title":"Influence of charge compensating cations on propane adsorption in X zeolites: Experimental measurement and mathematical modeling","volume":"4","author":"Yang","year":"2014","journal-title":"RSC Adv."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"398","DOI":"10.1016\/0021-9517(73)90311-4","article-title":"Photoadsorption and Photocatalysis at Rutile Surfaces II. Photocatalytic Oxidation of Isopropanol","volume":"31","author":"Bickley","year":"1973","journal-title":"J. Catal."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"425","DOI":"10.1016\/j.jphotochem.2004.01.014","article-title":"Kinetic study of ketones photocatalytic oxidation in gas phase using TiO2-containing paper: Effect of water vapor","volume":"163","author":"Raillard","year":"2004","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"14480","DOI":"10.1039\/C3RA48052F","article-title":"Zeolites and related sorbents with narrow pores for CO2 separation from flue gas","volume":"4","author":"Cheung","year":"2014","journal-title":"RSC Adv."},{"key":"ref_64","unstructured":"Doremus, R.H. (1973). Glass Science, John Wiley & Sons."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"451","DOI":"10.1016\/0144-2449(87)90014-5","article-title":"Crystallization of low-silica faujasite (SiO2\/Al2O3~2.0)","volume":"7","year":"1987","journal-title":"Zeolites"}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/20\/2\/2349\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T20:42:11Z","timestamp":1760215331000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/20\/2\/2349"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,1,30]]},"references-count":65,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2015,2]]}},"alternative-id":["molecules20022349"],"URL":"https:\/\/doi.org\/10.3390\/molecules20022349","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,1,30]]}}}