{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,5]],"date-time":"2026-06-05T06:35:18Z","timestamp":1780641318768,"version":"3.54.1"},"reference-count":45,"publisher":"MDPI AG","issue":"7","license":[{"start":{"date-parts":[[2015,7,3]],"date-time":"2015-07-03T00:00:00Z","timestamp":1435881600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>A series of novel ferrocenyl- and aryl-phosphonofluorodithioic salts, adducts, and esters has been prepared. The reaction of 2,4-diferrocenyl-1,3,2,4-diathiadiphosphetane 2,4-disulfide {[FcP(\u03bc-S)S]2, FcLR} with dry KF or tetrabutylammonium fluoride (TBAF) led to the corresponding potassium and tetrabutylammonium salts of ferrocenyldithiofluorophosphinic acids. Treating potassium ferrocenyldithiofluorophosphinic acid with an equimolar amount of tetraphenylphosphonium chloride readily yielded the corresponding organic adducts, and with mono- and di-halogenated alkanes generated a series of the corresponding esters of ferrocenylphosphonofluoridodithioates. Similarly, using 1,3-epithionaphtho[1,8-cd][1,2,6] oxadiphosphinine 1,3-disulfide or Belleau\u2019s Reagent in place of FcLR resulted in the corresponding novel salts, adducts, and ester derivatives. All new compounds have been characterized by means of multi-NMR (1H, 13C, 31P, 19F) spectroscopy and accurate mass measurement in conjunction with single crystal X-ray crystallography of four structures.<\/jats:p>","DOI":"10.3390\/molecules200712175","type":"journal-article","created":{"date-parts":[[2015,7,3]],"date-time":"2015-07-03T16:19:37Z","timestamp":1435940377000},"page":"12175-12197","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Novel Fluorinated Phosphorus\u2013Sulfur Heteroatom Compounds: Synthesis and Characterization of Ferrocenyl- and  Aryl-Phosphonofluorodithioic Salts, Adducts, and Esters"],"prefix":"10.3390","volume":"20","author":[{"given":"Guoxiong","family":"Hua","sequence":"first","affiliation":[{"name":"EaStCHEM School of Chemistry, University of St. Andrews, St Andrews, Fife KY16 9ST, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junyi","family":"Du","sequence":"additional","affiliation":[{"name":"EaStCHEM School of Chemistry, University of St. Andrews, St Andrews, Fife KY16 9ST, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Brian","family":"Surgenor","sequence":"additional","affiliation":[{"name":"EaStCHEM School of Chemistry, University of St. Andrews, St Andrews, Fife KY16 9ST, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9527-6418","authenticated-orcid":false,"given":"Alexandra","family":"Slawin","sequence":"additional","affiliation":[{"name":"EaStCHEM School of Chemistry, University of St. Andrews, St Andrews, Fife KY16 9ST, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J.","family":"Woollins","sequence":"additional","affiliation":[{"name":"EaStCHEM School of Chemistry, University of St. Andrews, St Andrews, Fife KY16 9ST, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2015,7,3]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3194","DOI":"10.1073\/pnas.71.8.3194","article-title":"Regulation of newly synthesized acetyleholinesterase in muscle cultures treated with diisopropylfluorophosphate","volume":"71","author":"Wilson","year":"1974","journal-title":"Proc. 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