{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T04:23:46Z","timestamp":1760243026441,"version":"build-2065373602"},"reference-count":31,"publisher":"MDPI AG","issue":"8","license":[{"start":{"date-parts":[[2015,8,18]],"date-time":"2015-08-18T00:00:00Z","timestamp":1439856000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Synthetic modification of trichlorofluoromethane (CFCl3) to non-volatile and useful fluorinated precursors is a cost-effective and an environmentally benign strategy for the safe consumption\/destruction of the ozone depleting potential of the reagent. In this report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl3 for synthesis of dichlorofluoromethyl aromatic alcohols.<\/jats:p>","DOI":"10.3390\/molecules200815098","type":"journal-article","created":{"date-parts":[[2015,8,18]],"date-time":"2015-08-18T10:31:11Z","timestamp":1439893871000},"page":"15098-15107","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Addition of CFCl3 to Aromatic Aldehydes via in Situ Grignard Reaction"],"prefix":"10.3390","volume":"20","author":[{"given":"Balaka","family":"Barkakaty","sequence":"first","affiliation":[{"name":"Center for Nanophase Materials Sciences, Oak Ridge National Laboratory,  One Bethel Valley Road, Oak Ridge, TN 37831, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bandana","family":"Talukdar","sequence":"additional","affiliation":[{"name":"Independent Researcher, Juripar, Panjabari, Guwahati 781037, Assam, India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bradley","family":"Lokitz","sequence":"additional","affiliation":[{"name":"Center for Nanophase Materials Sciences, Oak Ridge National Laboratory,  One Bethel Valley Road, Oak Ridge, TN 37831, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2015,8,18]]},"reference":[{"key":"ref_1","unstructured":"Welch, C. 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