{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T18:27:54Z","timestamp":1787596074377,"version":"build-2736575974"},"reference-count":60,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2015,11,27]],"date-time":"2015-11-27T00:00:00Z","timestamp":1448582400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The synthesis and characterization of P-chiral phosphonite-, phosphonate- and thiophosphonate-Au(I) complexes are reported. These novel ligands for Au(I) are based on glycomimetic phosphorus scaffolds, obtained from the chiral pool. The catalytic activities of these complexes are shown in the cyclization of allenols and the hydroamination of 2-(2-propynyl)aniline combined with an organocatalyzed reduction to the corresponding 2-phenyl tetrahydroquinoline. All described gold complexes present excellent catalytic activities.<\/jats:p>","DOI":"10.3390\/molecules201219755","type":"journal-article","created":{"date-parts":[[2015,11,27]],"date-time":"2015-11-27T10:25:29Z","timestamp":1448619929000},"page":"21082-21093","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["When Phosphosugars Meet Gold: Synthesis and Catalytic Activities of Phostones and Polyhydroxylated Phosphonite Au(I) Complexes"],"prefix":"10.3390","volume":"20","author":[{"given":"Ga\u00eblle","family":"Malik","sequence":"first","affiliation":[{"name":"Institut de Chimie des Substances Naturelles, CNRS UPR 2301, Universit\u00e9 Paris-Sud, Universit\u00e9 Paris-Saclay, 1 Avenue de la Terrasse, 91198 Gif sur Yvette cedex, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ang\u00e9lique","family":"Ferry","sequence":"additional","affiliation":[{"name":"Institut de Chimie des Substances Naturelles, CNRS UPR 2301, Universit\u00e9 Paris-Sud, Universit\u00e9 Paris-Saclay, 1 Avenue de la Terrasse, 91198 Gif sur Yvette cedex, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2353-8236","authenticated-orcid":false,"given":"Xavier","family":"Guinchard","sequence":"additional","affiliation":[{"name":"Institut de Chimie des Substances Naturelles, CNRS UPR 2301, Universit\u00e9 Paris-Sud, Universit\u00e9 Paris-Saclay, 1 Avenue de la Terrasse, 91198 Gif sur Yvette cedex, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2015,11,27]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"5232","DOI":"10.1002\/anie.200907078","article-title":"Homogeneous gold catalysis beyond assumptions and proposals\u2014Characterized intermediates","volume":"49","author":"Hashmi","year":"2010","journal-title":"Angew. 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