{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,7]],"date-time":"2026-01-07T23:30:08Z","timestamp":1767828608955,"version":"3.49.0"},"reference-count":39,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2017,12,20]],"date-time":"2017-12-20T00:00:00Z","timestamp":1513728000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The crystal structure of compound (1), [CuCl(phen)(H2NCH2COO)]\u22194H2O, reveals an unusual hydrogen-bond water cluster aggregate T6(2)6(2). Four water molecules in (1) form an isolated water cluster, [(H2O)14]n, resembling a \u201cphenanthro-[1,2]phenanthrene polymer structure shape\u201d along the ac plane. The two face-face parallel [(H2O)14]n planes are bridged by Cl atoms in [CuCl(phen) (H2NCH2COO)] with a strong O-H\u2219\u2219\u2219Cl hydrogen bond to form a water cluster conduit.<\/jats:p>","DOI":"10.3390\/molecules22122278","type":"journal-article","created":{"date-parts":[[2017,12,20]],"date-time":"2017-12-20T11:34:14Z","timestamp":1513769654000},"page":"2278","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["A Water Cluster Conduit in Crystal"],"prefix":"10.3390","volume":"22","author":[{"given":"Fangfang","family":"Jian","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471023, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"E","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471023, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jiao","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471023, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2017,12,20]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"426","DOI":"10.1039\/c39910000426","article-title":"Hydration in organic crystals: Prediction from molecular structure","volume":"6","author":"Desiraju","year":"1991","journal-title":"J. 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