{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T18:06:14Z","timestamp":1774548374310,"version":"3.50.1"},"reference-count":71,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2018,5,10]],"date-time":"2018-05-10T00:00:00Z","timestamp":1525910400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21761018"],"award-info":[{"award-number":["21761018"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University","award":["201706"],"award-info":[{"award-number":["201706"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Two unprecedented homometallic CoII and ZnII coordination compounds, [M2(L)(OCH3)][M2(L)(OAc)] (MII = CoII (1) and ZnII (2)), with a novel symmetric bis(salamo)-like tetraoxime ligand H3L were synthesized and characterized by elemental analyses, infrafred (IR), ultraviolet\u2013visible spectroscopy (UV-Vis), fluorescent spectra and single-crystal X-ray diffraction analyses. The unit cell of the two coordination compounds contains two crystallographically and chemically independent dinuclear coordination compounds. In the two coordination compounds, three metal ions are five-coordinated, formed two square pyramidal and a trigonal bipyramidal geometries, and the other metal ion is a hexacoordinate octahedral configuration. In addition, the coordination compound 1 forms a 3D supramolecular structure, and the coordination compound 2 forms a 0D dimer structure by the inter-molecular hydrogen bond interactions. Meanwhile, the fluorescence spectra of the coordination compounds 1 and 2 were also measured and discussed.<\/jats:p>","DOI":"10.3390\/molecules23051141","type":"journal-article","created":{"date-parts":[[2018,5,11]],"date-time":"2018-05-11T03:42:48Z","timestamp":1526010168000},"page":"1141","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":38,"title":["Unprecedented Fluorescent Dinuclear CoII and ZnII Coordination Compounds with a Symmetric Bis(salamo)-Like Tetraoxime"],"prefix":"10.3390","volume":"23","author":[{"given":"Lin-Wei","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ling-Zhi","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fei","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1249-5808","authenticated-orcid":false,"given":"Wen-Kui","family":"Dong","sequence":"additional","affiliation":[{"name":"School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2018,5,10]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3375","DOI":"10.1007\/s11164-013-1440-5","article-title":"Synthesis, structure, antioxidation, and DNA-bindingstudies of a binuclear ytterbium(III) complex with bis(N-salicylidene)-3-oxapentane-1,5-diamine","volume":"41","author":"Wu","year":"2015","journal-title":"Res. 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