{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T13:41:09Z","timestamp":1760190069682,"version":"build-2065373602"},"reference-count":59,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2019,6,22]],"date-time":"2019-06-22T00:00:00Z","timestamp":1561161600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>In this work the immobilization of hybrid polyoxometalates (POMs) onto functional polymeric surfaces is exposed and discussed. Thus, various hybrid polymer\u2012inorganic films were prepared by anchoring selected hybrid POMs onto tailored polymeric surfaces that consisted of breath figures (BFs) made of polystyrene-b-poly(acrylic acid)\/polystyrene (PS-b-PAA\/PS) blends. Functionalization of the BF films was performed by selective arrangement of acrylic acid groups of the amphiphilic block copolymer on the surface pores because of their affinition for the water condensed during breath figure formation. These carboxylic acid functional groups contained within the PAA blocks were then employed to anchor [Cu(cyclam)][{Cu(cyclam)}2(V10O28)]\u00b710H2O (1-CuV10) and [{Cu(cyclam)}(VO3)2]\u00b75H2O (1-CuV1), hybrid POMs by immersing the films into aqueous solutions of the in situ formed hybrid clusters, resulting in the hybrid films BF1 and BF2, respectively. Superficial analysis of these hybrid polymeric films was carried out by the sophisticated ion beam-based technique time-of-flight secondary ion mass spectrometry (ToF-SIMS) that was revealed to be an excellent method for the superficial compositional mapping of patterned surfaces.<\/jats:p>","DOI":"10.3390\/molecules24122313","type":"journal-article","created":{"date-parts":[[2019,6,24]],"date-time":"2019-06-24T02:37:40Z","timestamp":1561343860000},"page":"2313","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Toward Advanced Functional Systems: Honeycomb-Like Polymeric Surfaces Incorporating Polyoxovanadates with Surface-Appended Copper-Cyclam Complexes"],"prefix":"10.3390","volume":"24","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2045-008X","authenticated-orcid":false,"given":"Leire","family":"Ruiz-Rubio","sequence":"first","affiliation":[{"name":"Grupo de Qu\u00edmica Macromolecular (LABQUIMAC). Departamento de Qu\u00edmica F\u00edsica, Facultad de Ciencia y Tecnolog\u00eda, Universidad del Pa\u00eds Vasco UPV\/EHU, P.O. Box 644, 48080 Bilbao, Spain"},{"name":"BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV\/EHU Science Park, 48940 Leioa, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7373-4596","authenticated-orcid":false,"given":"Be\u00f1at","family":"Artetxe","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica, Facultad de Ciencia y Tecnolog\u00eda, Universidad del Pa\u00eds Vasco UPV\/EHU, P.O. Box 644, 48080 Bilbao, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0543-4134","authenticated-orcid":false,"given":"Leyre","family":"P\u00e9rez-\u00c1lvarez","sequence":"additional","affiliation":[{"name":"Grupo de Qu\u00edmica Macromolecular (LABQUIMAC). Departamento de Qu\u00edmica F\u00edsica, Facultad de Ciencia y Tecnolog\u00eda, Universidad del Pa\u00eds Vasco UPV\/EHU, P.O. Box 644, 48080 Bilbao, Spain"},{"name":"BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV\/EHU Science Park, 48940 Leioa, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jagoba","family":"Mart\u00edn-Caballero","sequence":"additional","affiliation":[{"name":"BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV\/EHU Science Park, 48940 Leioa, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tatsumi","family":"Ishihara","sequence":"additional","affiliation":[{"name":"International Institute for Carbon-Neutral Energy Research (I2CNER), Kyushu University, Fukuoka 819-0395, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Juan M.","family":"Guti\u00e9rrez-Zorrilla","sequence":"additional","affiliation":[{"name":"BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV\/EHU Science Park, 48940 Leioa, Spain"},{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica, Facultad de Ciencia y Tecnolog\u00eda, Universidad del Pa\u00eds Vasco UPV\/EHU, P.O. Box 644, 48080 Bilbao, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0188-4579","authenticated-orcid":false,"given":"Jos\u00e9 Luis","family":"Vilas-Vilela","sequence":"additional","affiliation":[{"name":"Grupo de Qu\u00edmica Macromolecular (LABQUIMAC). Departamento de Qu\u00edmica F\u00edsica, Facultad de Ciencia y Tecnolog\u00eda, Universidad del Pa\u00eds Vasco UPV\/EHU, P.O. Box 644, 48080 Bilbao, Spain"},{"name":"BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV\/EHU Science Park, 48940 Leioa, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2019,6,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Pope, M.T. (1983). Heteropoly and Isopoly Oxometalates, Springer.","DOI":"10.1007\/978-3-662-12004-0"},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Pope, M.T., and M\u00fcller, A. (1994). 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