{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T03:42:22Z","timestamp":1760240542469,"version":"build-2065373602"},"reference-count":14,"publisher":"MDPI AG","issue":"14","license":[{"start":{"date-parts":[[2019,7,15]],"date-time":"2019-07-15T00:00:00Z","timestamp":1563148800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Korea Alcohol &amp; Liquor Industry Association (KALIA)","award":["2017-2371-01"],"award-info":[{"award-number":["2017-2371-01"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Herein, contaminants remaining in distillate and distillers\u2019 stillage were quantitatively measured after distillation. After rice bran powder was contaminated with 10 ppm of lead (Pb) and cadmium (Cd) or 0.02\u20131.27 ppm of five pesticides (terbufos, fenthion, iprobenfos, flutolanil, and ethoprophos) followed by fermentation, single-stage distillation was performed. In the obtained distillate, no Pb or Cd was found, as expected. However, when the pesticides were added as contaminants, trace\u20130.05 ppm of some pesticides were detected in the distillate, possibly due to the high vapor pressure (e.g., that of ethoprophos) and contamination amount (e.g., that of flutolanil, terbufos, and fenthion). In contrast, none of the contaminating pesticides were observed in the distilled spirits when a fermented liquefaction contaminated with 0.04\u20134 ppm of six pesticides (fenthion, terbufos, ethoprophos, iprobenfos, oxadiazon, and flutolanil) was distilled using a pilot-plant scale distillation column, indicating that the pesticides hardly migrate to the distilled spirits.<\/jats:p>","DOI":"10.3390\/molecules24142572","type":"journal-article","created":{"date-parts":[[2019,7,16]],"date-time":"2019-07-16T02:23:16Z","timestamp":1563243796000},"page":"2572","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Approach Study for Mass Balance of Pesticide Residues in Distillers\u2019 Stillage along with Distillate and Absence Verification of Pesticides in Distilled Spirits from Pilot-Scale of Distillation Column"],"prefix":"10.3390","volume":"24","author":[{"given":"Jung-Ah","family":"Shin","sequence":"first","affiliation":[{"name":"Department of Food Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hoonho","family":"Cho","sequence":"additional","affiliation":[{"name":"Chilseo Ethanol Factory, IL SAN Trading Co., 551 Daebu-ro, Chilseo-myeon, Haman-gun, Gyeongsangnam-do 52001, Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dong-Woo","family":"Seo","sequence":"additional","affiliation":[{"name":"Department of Food Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hee-Gon","family":"Jeong","sequence":"additional","affiliation":[{"name":"Department of Food Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sung Chul","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Bio Environmental Chemistry, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jeung-Hee","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Food and Nutrition, Daegu University, 201 Daegudae-ro, Gyeonsan-si, Gyeongsangbukdo 38453, Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Soon-Taek","family":"Hong","sequence":"additional","affiliation":[{"name":"Department of Food Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ki-Teak","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Food Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2019,7,15]]},"reference":[{"key":"ref_1","unstructured":"The Beverage Alcohol Manual (BAM) (2019, May 02). Chapter 4: Class and Type Designation, Available online: https:\/\/www.ttb.gov\/spirits\/bam.shtml."},{"key":"ref_2","unstructured":"Official Journal of the European Union law (EUR-Lex) (2019, May 02). Regulation (EC) No 110\/2008 of the European parliament and of the Council of 15 January 2008. Available online: http:\/\/data.europa.eu\/eli\/reg\/2008\/110(1)\/oj."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"12","DOI":"10.1016\/j.foodchem.2016.03.035","article-title":"Residue levels of five grain-storage-use insecticides during the production process of sorghum distilled spirits","volume":"206","author":"Han","year":"2016","journal-title":"Food Chem."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"2248","DOI":"10.1021\/jf960457l","article-title":"Pesticides in the distilled spirits of wine and its byproducts","volume":"45","author":"Cabras","year":"1997","journal-title":"J. Agric. 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National Library of Medicine, National Center for Biotechnology Information, Available online: https:\/\/pubchem.ncbi.nlm.nih.gov\/compound\/flutolanil."},{"key":"ref_12","doi-asserted-by":"crossref","unstructured":"Mendes, M.F. (2017). Distillation techniques in the fruit spirits production. Distillation\u2014Innovative Application and Modeling, IntechOpen. Available online: http:\/\/dx.doi.org\/10.5772\/66774.","DOI":"10.5772\/66774"},{"key":"ref_13","unstructured":"(2019, March 03). Analysis methods of lead (9.1.2.) and cadmium (9.1.3.) in foods, Korean Food Standards Codex, Ministry of Food and Drug Safety, Available online: https:\/\/www.foodsafetykorea.go.kr\/portal\/safefoodlife\/food\/foodRvlv\/foodRvlv.do."},{"key":"ref_14","unstructured":"(2019, March 03). Multi class pesticide multiresidue methods (7.1.2) in foods, Korean Food Standards Codex, Ministry of Food and Drug Safety, Available online: https:\/\/www.foodsafetykorea.go.kr\/portal\/safefoodlife\/food\/foodRvlv\/foodRvlv.do."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/24\/14\/2572\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T13:05:55Z","timestamp":1760187955000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/24\/14\/2572"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,7,15]]},"references-count":14,"journal-issue":{"issue":"14","published-online":{"date-parts":[[2019,7]]}},"alternative-id":["molecules24142572"],"URL":"https:\/\/doi.org\/10.3390\/molecules24142572","relation":{},"ISSN":["1420-3049"],"issn-type":[{"type":"electronic","value":"1420-3049"}],"subject":[],"published":{"date-parts":[[2019,7,15]]}}}