{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,31]],"date-time":"2026-03-31T22:38:19Z","timestamp":1774996699224,"version":"3.50.1"},"reference-count":54,"publisher":"MDPI AG","issue":"8","license":[{"start":{"date-parts":[[2020,4,18]],"date-time":"2020-04-18T00:00:00Z","timestamp":1587168000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100009409","name":"Russian Science Support Foundation","doi-asserted-by":"publisher","award":["RSF projects 18-73-00014"],"award-info":[{"award-number":["RSF projects 18-73-00014"]}],"id":[{"id":"10.13039\/100009409","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>An efficient method for the synthesis of tetraoxathiaspiroalkanes, tetraoxathiocanes, and hexaoxathiadispiroalkanes was developed by reactions of pentaoxacanes, pentaoxaspiroalkanes, and heptaoxadispiroalkanes with hydrogen sulfide in the presence of a catalyst, Sm(NO3)3\u00b76H2O. We found that the synthesized S-containing di- and triperoxides exhibit high cytotoxic activity against Jurkat, K562, U937, and HL60 tumor cultures, and fibroblasts.<\/jats:p>","DOI":"10.3390\/molecules25081874","type":"journal-article","created":{"date-parts":[[2020,4,21]],"date-time":"2020-04-21T05:48:52Z","timestamp":1587448132000},"page":"1874","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides"],"prefix":"10.3390","volume":"25","author":[{"given":"Nataliya","family":"Makhmudiyarova","sequence":"first","affiliation":[{"name":"Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa 450075, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Irina","family":"Ishmukhametova","sequence":"additional","affiliation":[{"name":"Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa 450075, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3315-4746","authenticated-orcid":false,"given":"Lilya","family":"Dzhemileva","sequence":"additional","affiliation":[{"name":"Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa 450075, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7787-5054","authenticated-orcid":false,"given":"Vladimir","family":"D\u2019yakonov","sequence":"additional","affiliation":[{"name":"Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa 450075, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Askhat","family":"Ibragimov","sequence":"additional","affiliation":[{"name":"Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa 450075, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Usein","family":"Dzhemilev","sequence":"additional","affiliation":[{"name":"Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa 450075, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2020,4,18]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1739","DOI":"10.1248\/cpb.19.1739","article-title":"Tremorgenic toxins from Aspergillus fumigatus Fres","volume":"19","author":"Yamazaki","year":"1971","journal-title":"Chem. 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