{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T02:50:43Z","timestamp":1760237443159,"version":"build-2065373602"},"reference-count":77,"publisher":"MDPI AG","issue":"9","license":[{"start":{"date-parts":[[2020,5,7]],"date-time":"2020-05-07T00:00:00Z","timestamp":1588809600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21871203, 21671143"],"award-info":[{"award-number":["21871203, 21671143"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>A heterometallic metal\u2212organic framework (MOF) of [Cd6Ca4(BTB)6(HCOO)2(DEF)2(H2O)12]\u2219DEF\u2219xSol (1, H3BTB = benzene-1,3,5-tribenzoic acid; DEF = N,N\u2032-diethylformamide; xSol. = undefined solvates within the pore) was prepared by solvothermal reaction of Cd(NO3)2\u00b74H2O, CaO and H3BTB in a mixed solvent of DEF\/H2O\/HNO3. The compatibility of these two divalent cations from different blocks of the periodic table results in a solid-state structure consisting of an unusual combination of a discrete V-shaped heptanuclear cluster of [Cd2Ca]2Ca\u2032 and an infinite one-dimensional (1D) chain of [Cd2CaCa\u2032]n that are orthogonally linked via a corner-shared Ca2+ ion (denoted as Ca\u2032), giving rise to an unprecedented branched-chain secondary building unit (SBU). These SBUs propagate via tridentate BTB to yield a three-dimensional (3D) structure featuring a corner-truncated P41 helix in MOF 1. This outcome highlights the unique topologies possible via the combination of carefully chosen s- and d-block metal ions with polydentate ligands.<\/jats:p>","DOI":"10.3390\/molecules25092190","type":"journal-article","created":{"date-parts":[[2020,5,8]],"date-time":"2020-05-08T03:45:20Z","timestamp":1588909520000},"page":"2190","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["A Heterometallic Three-Dimensional Metal\u2212Organic Framework Bearing an Unprecedented One-Dimensional Branched-Chain Secondary Building Unit"],"prefix":"10.3390","volume":"25","author":[{"given":"Jing","family":"Chen","sequence":"first","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Meng-Yao","family":"Chao","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yan","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bo-Wei","family":"Xu","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9047-8881","authenticated-orcid":false,"given":"Wen-Hua","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6079-5904","authenticated-orcid":false,"given":"David J.","family":"Young","sequence":"additional","affiliation":[{"name":"College of Engineering, Information Technology &amp; Environment, Charles Darwin University, Darwin, Northern Territory 0909, Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2020,5,7]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"8129","DOI":"10.1021\/acs.chemrev.7b00091","article-title":"Metal\u2013organic frameworks for heterogeneous basic catalysis","volume":"117","author":"Zhu","year":"2017","journal-title":"Chem. 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