{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T17:34:55Z","timestamp":1778607295899,"version":"3.51.4"},"reference-count":69,"publisher":"MDPI AG","issue":"20","license":[{"start":{"date-parts":[[2020,10,12]],"date-time":"2020-10-12T00:00:00Z","timestamp":1602460800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100009450","name":"KAUTE-S\u00e4\u00e4ti\u00f6","doi-asserted-by":"publisher","award":["-"],"award-info":[{"award-number":["-"]}],"id":[{"id":"10.13039\/100009450","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004373","name":"Tauno T\u00f6nningin S\u00e4\u00e4ti\u00f6","doi-asserted-by":"publisher","award":["-"],"award-info":[{"award-number":["-"]}],"id":[{"id":"10.13039\/501100004373","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005637","name":"Tekniikan Edist\u00e4miss\u00e4\u00e4ti\u00f6","doi-asserted-by":"publisher","award":["-"],"award-info":[{"award-number":["-"]}],"id":[{"id":"10.13039\/501100005637","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004157","name":"Maj ja Tor Nesslingin S\u00e4\u00e4ti\u00f6","doi-asserted-by":"publisher","award":["2014459"],"award-info":[{"award-number":["2014459"]}],"id":[{"id":"10.13039\/501100004157","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012683","name":"Walter Ahlstr\u00f6min S\u00e4\u00e4ti\u00f6","doi-asserted-by":"publisher","award":["-"],"award-info":[{"award-number":["-"]}],"id":[{"id":"10.13039\/501100012683","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008530","name":"European Regional Development Fund","doi-asserted-by":"publisher","award":["A32164"],"award-info":[{"award-number":["A32164"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Seventh Framework Programme","award":["PIRSES-GA-2012-317714"],"award-info":[{"award-number":["PIRSES-GA-2012-317714"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Au, Pt, and Pt-Au catalysts supported on Al2O3 and CeO2-Al2O3 were studied in the oxidation of dichloromethane (DCM, CH2Cl2). High DCM oxidation activities and HCl selectivities were seen with all the catalysts. With the addition of Au, remarkably lower light-off temperatures were observed as they were reduced by 70 and 85 degrees with the Al2O3-supported and by 35 and 40 degrees with the CeO2-Al2O3-supported catalysts. Excellent HCl selectivities close to 100% were achieved with the Au\/Al2O3 and Pt-Au\/Al2O3 catalysts. The addition of ceria on alumina decreased the total acidity of these catalysts, resulting in lower performance. The 100-h stability test showed that the Pt-Au\/Al2O3 catalyst was active and durable, but the selectivity towards the total oxidation products needs improvement. The results suggest that, with the Au-containing Al2O3-supported catalysts, DCM decomposition mainly occurs via direct DCM hydrolysis into formaldehyde and HCl followed by the oxidation of formaldehyde into CO and CO2.<\/jats:p>","DOI":"10.3390\/molecules25204644","type":"journal-article","created":{"date-parts":[[2020,10,17]],"date-time":"2020-10-17T07:23:22Z","timestamp":1602919402000},"page":"4644","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Oxidation of Dichloromethane over Au, Pt, and Pt-Au Containing Catalysts Supported on \u03b3-Al2O3 and CeO2-Al2O3"],"prefix":"10.3390","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9906-7261","authenticated-orcid":false,"given":"Tuomas K.","family":"Nevanper\u00e4","sequence":"first","affiliation":[{"name":"Faculty of Technology, Environmental and Chemical Engineering, University of Oulu, P.O. Box 4300, FI-90014 Oulu, Finland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Satu","family":"Pitk\u00e4aho","sequence":"additional","affiliation":[{"name":"Faculty of Technology, Environmental and Chemical Engineering, University of Oulu, P.O. Box 4300, FI-90014 Oulu, Finland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Satu","family":"Ojala","sequence":"additional","affiliation":[{"name":"Faculty of Technology, Environmental and Chemical Engineering, University of Oulu, P.O. Box 4300, FI-90014 Oulu, Finland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Riitta L.","family":"Keiski","sequence":"additional","affiliation":[{"name":"Faculty of Technology, Environmental and Chemical Engineering, University of Oulu, P.O. Box 4300, FI-90014 Oulu, Finland"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2020,10,12]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Marshall, K.A., and Pottenger, L.H. (2016). Chlorocarbons and Chlorohydrocarbons. Kirk-Othmer Encyclopedia of Chemical Technology, Wiley-Interscience.","DOI":"10.1002\/0471238961.1921182218050504.a01.pub3"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1169","DOI":"10.2478\/s11696-013-0505-7","article-title":"State of the art in catalytic oxidation of chlorinated volatile organic compounds","volume":"68","author":"Aranzabal","year":"2014","journal-title":"Chem. Pap."},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Seinfeld, J.H., and Pandis, S.N. (1998). Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, Wiley.","DOI":"10.1063\/1.882420"},{"key":"ref_4","unstructured":"(2019, June 14). About Chlorinated Solvents. 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